Long-term hydrology and aquatic biogeochemistry data from H. J. Andrews Experimental Forest,Cascade Mountains,Oregon     

Sherri L. Johnson  Don Henshaw  Greg Downing  Steve Wondzell  Mark Schulze  Adam Kennedy  Greg Cohn  Stephanie A. Schmidt  Julia A. Jones 《水文研究》2021,35(5):e14187

The H. J. Andrews Experimental Forest (HJA) encompasses the 6400 ha Lookout Creek watershed in western Oregon, USA. Hydrologic, chemistry and precipitation data have been collected, curated, and archived for up to 70 years. The HJA was established in 1948 to study the effects of harvest of old-growth conifer forest and logging-road construction on water quality, quantity and vegetation succession. Over time, research questions have expanded to include terrestrial and aquatic species, communities and ecosystem dynamics. There are nine small experimental watersheds and 10 gaging stations in the HJA, including both reference and experimentally treated watersheds. Gaged watershed areas range from 8.5 to 6242 ha. All gaging stations record stage height, water conductivity, water temperature and above-stream air temperature. At nine of the gage sites, flow-proportional water samples are collected and composited over 3-week intervals for chemical analysis. Analysis of stream and precipitation chemistry began in 1968. Analytes include dissolved and particulate species of nitrogen and phosphorus, dissolved organic carbon, pH, specific conductance, suspended sediment, alkalinity, and major cations and anions. Supporting climate measurements began in the 1950s in association with the first small watershed experiments. Over time, and following the initiation of the Long Term Ecological Research (LTER) grant in 1980, infrastructure expanded to include a set of benchmark and secondary meteorological stations located in clearings spanning the elevation range within the Lookout Creek watershed, as well as a large number of forest understory temperature stations. Extensive metadata on sensor configurations, changes in methods over time, sensor accuracy and precision, and data quality control flags are associated with the HJA data.  相似文献   

Spatial and Temporal Distribution of Dust‐Bound Trace Metal Elements around Kuhdasht Watershed Area in Iran     

Hamid Alipour  Ahmad Jalalian  Naser Honarjoo  Norair Tommanian  Fereidoon Sarmadian 《洁净——土壤、空气、水》2019,47(10)

Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km²), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg^?1), Pb (46.352.9 mg kg^?1), and Cd (2.443.30 mg kg^?1) are obtained in winter, of Ni (98110 mg kg^?1) and Cu in autumn (16.053.5 mg kg^?1), and of Mn in summer (385505 mg kg^?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.  相似文献   

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素     

王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   

Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

Multimodal water age distributions and the challenge of complex hydrological landscapes     

Nicolas B. Rodriguez  Paolo Benettin  Julian Klaus 《水文研究》2020,34(12):2707-2724

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Riparian land use and stream habitat regulate water quality     

《Limnologica》2020

Riparian land use is a key driver of stream ecosystem processes but its effects on water quality are still a matter of debate when proposing measures to improve freshwater quality. The aim of this study was to examine the influence of riparian land use on stream habitat and water chemistry, and to assess in what extent stream habitat also affects water quality. To that end, we selected eight reaches in the Ave River basin (northwestern Portugal) and compared longitudinal variations in water chemistry and stream habitat between reaches with different land use (urban, agricultural and natural), and between reaches with natural riparian areas and different habitats. Stream habitat was assessed using the Fluvial Functional Index, the HABSCORE, and the Riparian Forest Quality Index. Longitudinal variations in water chemistry were determined measuring differences in concentrations of ammonium, nitrate, phosphate and oxygen, and conductivity, pH and temperature between the downstream and the upstream ends of each reach. Nitrate concentration tended to decrease along reaches with more natural riparian areas and to increase along reaches with more urban and agricultural land uses. Longitudinal variations in water chemistry also differed between reaches with natural riparian areas, suggesting that water quality also depends on stream habitat. Moreover, longitudinal variation in water chemistry was proven a simple, useful and low-cost approach to assess the influence of land cover and stream habitat on water quality. Overall results demonstrated that both riparian land use and stream habitat influence water quality and that riparian forests are essential to reduce nutrient export to downstream ecosystems.  相似文献   

Spatial variability in specific discharge and streamwater chemistry during low flows: Results from snapshot sampling campaigns in eleven Swiss catchments     

Marius G. Floriancic  Benjamin M. C. Fischer  Peter Molnar  James W. Kirchner  Ilja H.J. van Meerveld 《水文研究》2019,33(22):2847-2866

Catchments consist of distinct landforms that affect the storage and release of subsurface water. Certain landforms may be the main contributors to streamflow during extended dry periods, and these may vary for different catchments in a given region. We present a unique dataset from snapshot field campaigns during low‐flow conditions in 11 catchments across Switzerland to illustrate this. The catchments differed in size (10 to 110 km²), varied from predominantly agricultural lowlands to Alpine areas, and covered a range of physical characteristics. During each snapshot campaign, we jointly measured streamflow and collected water samples for the analysis of major ions and stable water isotopes. For every sampling location (basin), we determined several landscape characteristics from national geo‐datasets, including drainage area, elevation, slope, flowpath length, dominant land use, and geological and geomorphological characteristics, such as the lithology and fraction of quaternary deposits. The results demonstrate very large spatial variability in specific low‐flow discharge and water chemistry: Neighboring sampling locations could differ significantly in their specific discharge, isotopic composition, and ion concentrations, indicating that different sources contribute to streamflow during extended dry periods. However, none of the landscape characteristics that we analysed could explain the spatial variability in specific discharge or streamwater chemistry in multiple catchments. This suggests that local features determine the spatial differences in discharge and water chemistry during low‐flow conditions and that this variability cannot be assessed a priori from available geodata and statistical relations to landscape characteristics. The results furthermore suggest that measurements at the catchment outlet during low‐flow conditions do not reflect the heterogeneity of the different source areas in the catchment that contribute to streamflow.  相似文献   

Kainsaz(CO3)陨石中两个富Al球粒的氧同位素组成特征与形成演化     

戴德求  包海梅  刘爽  尹锋 《岩石学报》2020,36(6):1850-1856

富Al球粒是原始球粒陨石中一种矿物岩石学特征介于富钙铝包体(CAIs)和镁铁质硅酸盐球粒之间的特殊集合体,所以常常认为富Al球粒在认识CAIs和镁铁质硅酸盐球粒形成演化过程中的相互联系具有特殊意义。然而,对富Al球粒的初始物质组成以及形成演化过程一直存在较多争议,而氧同位素组成研究能够对球粒演化和早期星云环境等提供重要的信息。在本文中我们报导了来自Kainsaz(1937年降落于俄罗斯,CO3型)碳质球粒陨石中的2个富Al球粒(编号K1-CH1和K2-CH2)的矿物岩石学和氧同位素组成特征。K1-CH1的矿物组成主要为橄榄石、低钙辉石和富钙长石,K2-CH2为橄榄石和富钙长石。2个球粒中的矿物均具有贫~(16)O同位素组成特征。K1-CH1中矿物的△~(17)O组成基本上位于2个区间:-11.1‰～-8.7‰和-3.9‰～0.4‰;而K2-CH2的△~(17)O介于-6.6‰～-0.6‰之间,且具有从中部至边部升高的趋势。矿物岩石学和氧同位素特征表明,这2个富Al球粒的初始物质组成为富CAIs和镁铁质硅酸盐。在球粒熔融结晶过程中,与贫~(16)O同位素组成(△~(17)O:-8.7‰～-7.8‰)的星云发生了氧同位素交换。球粒形成后,发生迁移进入陨石母体,在相对更贫~(16)O同位素组成(△~(17)O:-0.6‰～0.4‰)的母体中(流体参与)发生变质作用,并再次发生了氧同位素交换。  相似文献   

再探温跃层有孔虫B/Ca与温度和[CO₃^2-]的依赖性及其在24 ka以来热带西太平洋次表层碳酸盐系统重建中的应用     

郭景腾  李铁刚  熊志方  仇晓华  常凤鸣 《海洋学报(英文版)》2019,38(9):71-86

The B/Ca ratio of planktonic foraminifer shells has been used as a proxy for reconstructing past ocean carbonate chemistry. However, recent studies have revealed significant uncertainties associated with this proxy, such as whether seawater temperature or [ CO_3~(2-)] is the dominant control on the partition coefficient(K_D) of planktonic foraminiferal B/Ca. To address these uncertainties and thus improve our understanding of the planktonic foraminiferal B/Ca proxy, we analysed B/Ca ratios in the tests of Neogloboquadrina dutertrei(300–355 μm) and Pulleniatina obliquiloculata(355–400 μm) in surface sediment samples from the tropical western Pacific and South China Sea. The relationship between these B/Ca ratios and bottom water calcite saturation states(Δ[ CO_3~(2-)]) is weak, thus suggesting only a small dissolution effect on the B/Ca of the two species. The correlation coefficients(R~2) between the B/Ca ratios of N. dutertrei and P. obliquiloculata and environmental parameters(e.g., temperature, salinity, phosphate, DIC and ALK) in the tropical western Pacific and South China Sea are not high enough to justify using B/Ca ratios as a palaeoenvironmental proxy in the study areas. The significant correlation between K_D values of N. dutertrei and P. obliquiloculata and carbonate system parameters(e.g.,[ CO_3~(2-)], DIC, ALK, pH and [ HCO_3~-]) in the study area reflect chemical links between the K_D denominator and these variables. Based on our surface sediment calibration, an empirical relationship between the K_D of N.dutertrei and temperature is proposed in the tropical western Pacific. We also generated a record of B/Ca ratios in N. dutertrei(300–355 μm) from Core MD06-3052 in the tropical western Pacific over the past 24 ka to evaluate the application of the revised B/Ca proxy method. Based on the reconstructed empirical relationship for B/Ca and subsurface seawater ALK, we estimated subsurface seawater carbonate system parameters in the tropical western Pacific since 24 ka. In general, the estimated subsurface seawater pH and [ CO_3~(2-)] show an increase with time, and the record of subsurface seawater pCO_2 shows a decrease with time, in the tropical western Pacific over the past 24 ka. The consistent trends in subsurface seawater pCO_2 and opal flux during deglaciation may imply that the reported increase in subsurface water pCO_2 in the study area was promoted by enhanced upwelling in the Southern Ocean.  相似文献   

Long-term hydrological,biogeochemical, and climatological data from Walker Branch Watershed,East Tennessee,USA     

Natalie A. Griffiths  Patrick J. Mulholland 《水文研究》2021,35(3):e14110

In 1967, the original Walker Branch Watershed (WBW) project was established to study elemental cycling and mass balances in a relatively unimpacted watershed. Over the next 50+ years, findings from additional experimental studies and long-term observations on WBW advanced understanding of catchment hydrology, biogeochemistry, and ecology and established WBW as a seminal site for catchment science. The 97.5-ha WBW is located in East Tennessee, USA, on the U.S. Department of Energy's Oak Ridge Reservation. Vegetation on the watershed is characteristic of an eastern deciduous, second-growth forest. The watershed is divided into two subcatchments: the West Fork (38.4 ha) and the East Fork (59.1 ha). Headwater streams draining these subcatchments are fed by multiple springs, and thus flow is perennial. Stream water is high in base cations due to weathering of dolomite bedrock and nutrient concentrations are low. Long-term observations of climate, hydrology, and biogeochemistry include daily (1969–2014) and 15-min (1994–2014) stream discharge and annual runoff (1969–2014); hourly, daily, and annual rainfall (1969–2012); daily climate and soil temperature (1993–2010); and weekly stream water chemistry (1989–2013). These long-term datasets are publicly available on the WBW website (https://walkerbranch.ornl.gov/long-term-data/ ). While collection of these data has ceased, related long-term measurements continue through the National Ecological Observatory Network (NEON), where WBW is the core terrestrial and aquatic site in the Appalachian and Cumberland Plateau region (NEON's Domain 7) of the United States. These long-term datasets have been and will continue to be important in evaluating the influence of climatic and environmental drivers on catchment processes.  相似文献