Diamond in metasedimentary crustal rocks from Pohorje,Eastern Alps: a window to deep continental subduction          下载免费PDF全文

M. Janák  N. Froitzheim  K. Yoshida  V. Sasinková  M. Nosko  T. Kobayashi  T. Hirajima  M. Vrabec 《Journal of Metamorphic Geology》2015,33(5):495-512

We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp³‐bonded carbon, in most cases centred between 1332 and 1330 cm^?1, with a full width at half maximum between 3 and 5 cm^?1. Several spectra show Raman bands typical for disordered graphitic (sp²‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO₂ and CH₄ in polyphase inclusions_. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units.  相似文献   

Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China          下载免费PDF全文

S.‐J. Wang  L. Wang  M. Brown  P. M. Piccoli  T. E. Johnson  P. Feng  H. Deng  K. Kitajima  Y. Huang 《Journal of Metamorphic Geology》2017,35(6):601-629

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.  相似文献   

大别山早白垩世变质核杂岩的结构与演化   总被引：7，自引：0，他引：7       下载免费PDF全文

冀文斌  林伟  石永红  王清晨  褚杨 《地质科学》2011,46(1):161-180

大别山中部混合岩-片麻岩穹隆的构造属性认识方面一直众说纷纭.通过对中大别杂岩及其边界剪切带或断裂带的构造解析,并结合对前人相关研究的总结,我们将中大别杂岩厘定为早白垩世的变质核杂岩,其中商麻断裂与晓天-磨子潭断裂和水吼-五河剪切带构成了一个完整的拆离断层带,并将变质核杂岩的形成时间限定在145～120 Ma.中大别杂岩...  相似文献   

大陆俯冲带流体活动:超高压变质岩矿物水含量和稳定同位素制约     

陈仁旭  郑永飞  龚冰 《岩石学报》2011,27(2):451-468

对超高压变质岩中含水矿物和名义上无水矿物的地球化学研究,极大地深化了我们对大陆碰撞带地壳俯冲和折返过程中流体体制的认识。就流体体制和化学地球动力学来说,有关研究在大别-苏鲁造山带进行的最为详细,因此已经成为研究大陆俯冲带变质的典型地区。本文以大别-苏鲁造山带为对象,从矿物水含量的角度,结合稳定同位素论述了大陆俯冲带流体活动。超高压变质岩中名义上无水矿物含有大量的水,以结构羟基和分子水形式存在。名义上无水矿物中结构羟基和分子水出溶与含水矿物分解共同构成了折返过程中退变质流体的主要来源。名义上无水矿物所释放的水以富集轻的氢氧同位素为特征,而含水矿物分解则提供了富集D的流体来源。折返过程中,名义上无水矿物降压脱水存在亏损D的分子水的优先丢失和不同形式水之间的相互转化。不同岩性的水含量差异导致了它们在折返过程中不同的流体活动行为。大陆板块俯冲和折返过程中,在不同矿物、不同岩性以及板片不同部位之间存在水的再分配;板片的一部分作为富水流体的源,而另一部分可能作为汇。  相似文献   

北大别的高温超高压变质作用与多阶段折返     

刘贻灿  古晓锋  邓亮鹏 《岩石学报》2011,27(2):589-600

近期的变质岩石学、地球化学及同位素年代学研究表明,北大别整体经历了高温超高压变质作用和多阶段折返历史,因而表现为广泛发育的多期减压结构和极少保留早期的超高压变质记录。北大别榴辉岩以高温变质作用以及折返期间因麻粒岩相和角闪岩相退变质变质作用而形成的多期后成合晶为显著特征。石榴子石中伴有放射状胀裂纹的单晶和多晶石英包体指示早期柯石英的转变结果,这已被锆石中发现的柯石英残晶所证实。结合北大别北部榴辉岩和片麻岩中发现的金刚石等超高压证据以及三叠纪变质记录,由此证明北大别整体经历过深俯冲和印支期超高压变质作用。北大别榴辉岩的多阶段高温条件主要来自石榴子石-绿辉石矿物对温度计、单斜辉石中紫苏辉石+石英针状矿物出熔体以及金红石中较高的Zr含量和变质锆石中较高的Ti含量等得出的温度证据。此外,多期后成合晶以及石榴子石和单斜辉石等矿物中成分分带的存在,证明该区榴辉岩经历了一个多阶段、快速折返过程;而不同变质阶段的温度、压力和形成时代,却反映该区榴辉岩经历了长时间的高温变质演化与缓慢冷却过程。长时间的高温变质作用与缓慢冷却过程也许正是北大别长期难以发现柯石英和有关超高压记录的重要原因。因此,这些成果为大别山三个不同超高压岩片的差异折返模型的建立提供了新的证据。  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987114001121   总被引：1，自引：0，他引：1  

Mark Scheltens  Lifei Zhang  Wenjiao Xiao  Jinjiang Zhang 《地学前缘(英文版)》2015,6(2):191-209

The Chinese Tianshan belt of the southern Altaids has undergone a complicated geological evolution.Different theories have been proposed to explain its evolution and these are still hotly debated.The major subduction polarity and the way of accretion are the main problems.Southward,northward subduction and multiple subduction models have been proposed.This study focuses on the structural geology of two of the main faults in the region,the South Tianshan Fault and the Nikolaev Line.The dip direction in the Muzhaerte valley is southward and lineations all point towards the NW.Two shear sense motions have been observed within both of these fault zones,a sinistral one,and a dextral one,the latter with an age of 236-251 Ma.Structural analyses on the fault zones show that subduction has been northward rather than southward.The two shear sense directions indicate that the Yili block was first dragged along towards the east due to the clockwise rotation of the Tarim block.After the Tarim block stopped rotating,the Yili block still kept going eastward,inducing the dextral shear senses within the fault zones.  相似文献   

从西南天山超高压变质带多期构造变形看天山古生代构造演化   总被引：2，自引：1，他引：1  

林伟  黎乐  张仲培  石永红  李秋立  薛振华  王非  吴林 《岩石学报》2015,31(8):2115-2128

通过对西南天山阿克雅孜和木扎尔特地区高压-超高压变质带构造几何学和岩石变形相关运动学的详细剖析,厘定出高压-超高压变质岩石及其相关围岩的构造单元。详细研究表明,研究区可划分为三个构造单元:北部单元、中部单元和南部单元。确定了每个构造单元的构造几何学特征及各个构造单元之间的相互关系。通过分析岩石变形特征和叠加关系,确定了岩石所记录多期变形的运动学特征。根据研究区的多期构造变形特点,建立了阿克雅孜和木扎尔特河地区构造演化序列。共划分出四期构造可识别的事件(E1-E4),分别代表了E1:高压-超高压岩石折返过程;E2:高压-超高压岩石造山带的早期改造过程;E3:北部构造事件对高压-超高压造山带影响;E4:走滑构造对高压-超高压造山带的叠加。沿造山带系列构造分析表明,西南天山高压-超高压带中发育的四期构造事件沿中天山北缘具有很好的一致性,各期构造事件也有一定的横向可对比性。在此基础上通过对多期变形事件的构造背景的探讨,建立了整个天山在古生代的构造拼合过程,揭示我国西部洋壳相关的深俯冲造山带形成过程和参与深俯冲作用(超)高压变质岩的变形变质历史。  相似文献   

Constraining peak P–T conditions in UHP eclogites: calculated phase equilibria in kyanite‐ and phengite‐bearing eclogite of the Tromsø Nappe,Norway     

M. JANÁK  E. J. K. RAVNA  K. KULLERUD 《Journal of Metamorphic Geology》2012,30(4):377-396

Kyanite‐ and phengite‐bearing eclogites have better potential to constrain the peak metamorphic P–T conditions from phase equilibria between garnet + omphacite + kyanite + phengite + quartz/coesite than common, mostly bimineralic (garnet + omphacite) eclogites, as exemplified by this study. Textural relationships, conventional geothermobarometry and thermodynamic modelling have been used to constrain the metamorphic evolution of the Tromsdalstind eclogite from the Tromsø Nappe, one of the biggest exposures of eclogite in the Scandinavian Caledonides. The phase relationships demonstrate that the rock progressively dehydrated, resulting in breakdown of amphibole and zoisite at increasing pressure. The peak‐pressure mineral assemblage was garnet + omphacite + kyanite + phengite + coesite, inferred from polycrystalline quartz included in radially fractured omphacite. This omphacite, with up to 37 mol.% of jadeite and 3% of the Ca‐Eskola component, contains oriented rods of silica composition. Garnet shows higher grossular (X_Grs = 0.25–0.29), but lower pyrope‐content (X_Prp = 0. 37–0.39) in the core than the rim, while phengite contains up to 3.5 Si pfu. The compositional isopleths for garnet core, phengite and omphacite constrain the P–T conditions to 3.2–3.5 GPa and 720–800 °C, in good agreement with the results obtained from conventional geothermobarometry (3.2–3.5 GPa & 730–780 °C). Peak‐pressure assemblage is variably overprinted by symplectites of diopside + plagioclase after omphacite, biotite and plagioclase after phengite, and sapphirine + spinel + corundum + plagioclase after kyanite. Exhumation from ultrahigh‐pressure (UHP) conditions to 1.3–1.5 GPa at 740–770 °C is constrained by the garnet rim (X_Ca^Grt = 0.18–0.21) and symplectite clinopyroxene (X_Na^Cpx = 0.13–0.21), and to 0.5–0.7 GPa at 700–800 °C by sapphirine (X_Mg = 0.86–0.87) and spinel (X_Mg = 0.60–0.62) compositional isopleths. UHP metamorphism in the Tromsø Nappe is more widespread than previously known. Available data suggest that UHP eclogites were uplifted to lower crustal levels rapidly, within a short time interval (452–449 Ma) prior to the Scandian collision between Laurentia and Baltica. The Tromsø Nappe as the highest tectonic unit of the North Norwegian Caledonides is considered to be of Laurentian origin and UHP metamorphism could have resulted from subduction along the Laurentian continental margin. An alternative is that the Tromsø Nappe belonged to a continental margin of Baltica, which had already been subducted before the terminal Scandian collision, and was emplaced as an out‐of‐sequence thrust during the Scandian lateral transport of nappes.  相似文献   

Element mobility during continental collision: insights from polymineralic metamorphic vein within UHP eclogite in the Dabie orogen     

Y.‐M. SHENG  Y‐F. ZHENG  S‐N. LI  Z. HU 《Journal of Metamorphic Geology》2013,31(2):221-241

Metamorphic dehydration and partial melting are two important processes during continental collision. They have significant bearing on element transport at the slab interface under subduction‐zone P–T conditions. Petrological and geochemical insights into the two processes are provided by a comprehensive study of leucocratic veins in ultrahigh‐pressure (UHP) metamorphic rocks. This is exemplified by this study of a polymineralic vein within phengite‐bearing UHP eclogite in the Dabie orogen. The vein is primarily composed of quartz, kyanite, epidote and phengite, with minor accessory minerals such as garnet, rutile and zircon. Primary multiphase solid inclusions occur in garnet and epidote from the both vein and host eclogite. They are composed of quartz ± K‐feldspar ± plagioclase ± K‐bearing glass and exhibit irregular to negative crystal shapes that are surrounded by weak radial cracks. This suggests their precipitation from solute‐rich metamorphic fluid/melt that involved the reaction of phengite breakdown. Zircon U–Pb dating for the vein gave two groups of concordant ages at 217 ± 2 and 210 ± 2 Ma, indicating two episodes of zircon growth in the Late Triassic. The same minerals from the two rocks give consistent δ¹⁸O and δD values, suggesting that the vein‐forming fluid was directly derived from the host UHP eclogite. The vein is much richer in phengite and epidote than the host eclogite, suggesting that the fluid is associated with remarkable concentration of such water‐soluble elements as LILE and LREE migration. Garnet and rutile in the vein exhibit much higher contents of HREE (2.2–5.7 times) and Nb–Ta (1.8–2.0 times) than those in the eclogite, indicating that these normally water‐insoluble elements became mobile and then were sunken in the vein minerals. Thus, the vein‐forming agent would be primarily composed of the UHP aqueous fluid with minor amounts of the hydrous melt, which may even become a supercritical fluid to have a capacity to transport not only LILE and LREE but also HREE and HFSE at subduction‐zone metamorphic conditions. Taken together, significant amounts of trace elements were transported by the vein‐forming fluid due to the phengite breakdown inside the UHP eclogite during exhumation of the deeply subducted continental crust.  相似文献   

西藏松多榴辉岩变质作用研究   总被引：5，自引：0，他引：5       下载免费PDF全文

张丁丁  张立飞  赵志丹 《地学前缘》2011,18(2):116-126

西藏拉萨地块松多附近新发现一条榴辉岩带,长约100 km,宽约2~3 km。松多榴辉岩主要经历了进变质的绿帘石榴辉岩相-峰期的榴辉岩相-退变质的角闪岩相3个阶段。岩石学研究表明,峰期的特征矿物组合是石榴子石绿辉石多硅白云母金红石,峰期温压条件是760~800 ℃,33~39 GPa。这表明松多地区可能曾经历超高压变质作用,之后快速返回,p T轨迹呈“发卡”状,后期退变质经历了角闪石榴辉岩相阶段。研究松多榴辉岩表明,拉萨地块内部有一条新的缝合带,这对于了解拉萨地块和古特提斯洋的演化有重要意义。  相似文献