Rainfall intensity affects runoff responses in a semi-arid catchment     

Ze Tao  Min Li  Bingcheng Si  Dyan Pratt 《水文研究》2021,35(4):e14100

The source and hydrochemical makeup of a stream reflects the connectivity between rainfall, groundwater, the stream, and is reflected to water quantity and quality of the catchment. However, in a semi-arid, thick, loess covered catchment, temporal variation of stream source and event associated behaviours are lesser known. Thus, the isotopic and chemical hydrographs in a widely distributed, deep loess, semi-arid catchment of the northern Chinese Loess Plateau were characterized to determine the source and hydrochemical behaviours of the stream during intra-rainfall events. Rainfall and streamflow were sampled during six hydrologic events coupled with measurements of stream baseflow and groundwater. The deuterium isotope (²H), major ions (Cl⁻, SO₄²⁻, NO₃⁻, Ca²⁺, K⁺, Mg²⁺, and Na⁺) were evaluated in water samples obtained during rainfall events. Temporal variation of ²H and Cl⁻ measured in the groundwater and stream baseflow prior to rainfall was similar; however, the isotope compositions of the streamflow fluctuated significantly and responded quickly to rainfall events, likely due to an infiltration excess, overland dominated surface runoff during torrential rainfall events. Time source separation using ²H demonstrated greater than 72% on average, the stream composition was event water during torrential rainfall events, with the proportion increasing with rainfall intensity. Solutes concentrations in the stream had loglinear relationships with stream discharge, with an outling anomaly with an example of an intra-rainfall event on Oct. 24, 2015. Stream Cl⁻ behaved nonconservative during rainfall events, temporal variation of Cl⁻ indicated a flush and washout at the onset of small rainfall events, a dilution but still high concentration pattern in high discharge and old water dominated in regression flow period. This study indicates rainfall intensity affects runoff responses in a semi-arid catchment, and the stored water in the thick, loess covered areas was less connected with stream runoff. Solute transport may threaten water quality in the area, requiring further analysis of the performance of the eco-restoration project.  相似文献   

Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream     

Sam J. Leuthold  Stephanie A. Ewing  Robert A. Payn  Florence R. Miller  Stephan G. Custer 《水文研究》2021,35(2):e14029

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   

鄂尔多斯地块周缘垂直形变场负位错反演与应变积累研究     

张希  刘立炜  郝明  白卓立 《大地测量与地球动力学》2019,39(6):551-556

利用鄂尔多斯地块及其周缘1970～2014年的垂直形变速率场资料，借助负位错反演研究该区域长期应变积累。结果表明，地块东北缘山西断陷带中北段年均能量积累增量、剪应力强度都较高，西南缘六盘山断裂与渭河断裂西段次之；山西断陷带中南段至晋陕交界处年均剪应力强度较高且显示一定程度的能量积累；西秦岭构造区尤其西秦岭北缘断裂西段、晋冀蒙交界区也反映一定程度的能量积累特性。  相似文献   

南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

沉积物中硬质粘土层的研究进展          下载免费PDF全文

孔凡彪  徐树建  贾广菊 《山东国土资源》2018,34(3)

大量的钻孔资料表明,平原地区及其海域沉积物中普遍有硬质粘土层的存在。硬质粘土层在工程地质、地理学研究等方面具有重要的价值,它不仅是高层建筑的持力层,而且是研究全球环境变化事件、古气候演变的良好载体。该文阐述了硬质粘土层的一般特征、成因以及在粒度、地球化学元素、年代学、沉积环境等方面的研究进展,并展望了硬质粘土层在年代、物质来源和沉积环境等方面的研究方向,认为黄河三角洲硬质粘土层研究较少,需要开展大范围的、系统深入的、多学科的宏观和微观综合分析,挖掘硬质粘土层蕴含的古环境意义和应用价值。  相似文献   

新疆库车县盐水沟北铜矿床地质特征及成因探讨          下载免费PDF全文

刘传朋 《山东国土资源》2018,34(4)

盐水沟北铜矿区位于新疆库车县北部,其大地构造位置处于塔吉克-塔里木陆块区、塔里木陆块、塔里木北缘隆起、库车前陆盆地,区内构造活动强烈。铜矿床赋存于新近纪中新统康村组第一岩性段,矿体呈层状,严格受地层控制。区内共圈定10个铜矿体,矿石矿物主要为孔雀石、赤铜矿、水胆矾、自然铜等,矿体内无夹石,顶、底板围岩均为褐红色及浅红色粉质泥岩。该矿床为砂岩型铜矿床。  相似文献   

Petrochronology of oxidized granulites from southern Peru     

Chris Yakymchuk  Adrian Rehm  Zhuoheng Liao  John M. Cottle 《Journal of Metamorphic Geology》2019,37(6):839-862

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.  相似文献   

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N   总被引：1，自引：0，他引：1  

荣坤波  曾志刚  殷学博  陈帅  王晓媛  齐海燕  马瑶 《海洋学报(英文版)》2018,37(9):67-81

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.  相似文献   

基于TPB拓展模型游艇旅游行为意向影响机制研究     

刘佳  贾楠 《海洋通报》2018,(4):378-388

在改进计划行为理论(TPB)模型基础上,引入人口特征和游艇文化变量,构建游艇旅游行为意向的影响机制模型,以实地调研和问卷调查作为数据来源,运用结构方程模型(SEM)实证检验影响旅游者参与游艇旅游行为意向的主要因素及其作用机制。研究表明:当前我国旅游者参与游艇旅游的意向较高;旅游者的行为态度、主观规范、感知行为控制和游艇文化是影响其选择游艇旅游活动的重要因素;旅游者的行为态度、游艇文化2个变量对游艇旅游行为意向具有显著的正向影响;主观规范和感知行为控制均通过行为态度这一中介变量间接影响游艇旅游行为意向。  相似文献   

利用短期静态PPP结果反演海潮负荷位移     

魏国光  王琪洁  彭葳  郭良琦 《大地测量与地球动力学》2019,39(6):607-612

采用香港11个GPS测站的观测资料进行1 h、2 h、3 h和4h静态PPP解算，获得4组PPP坐标序列，利用调和分析求取11个测站处8个主要分潮的负荷位移参数（振幅和相位），将其与海潮模型计算的负荷位移参数进行对比，并比较分析PPP反演值与海潮模型值改正海潮负荷信号的效果。结果表明，垂直和水平方向上，不同PPP结果反演8个分潮的负荷位移分别具有约5 mm和7 mm的差异；PPP反演8个分潮垂向负荷位移优于全球海潮模型，但水平方向上的反演效果稍弱。  相似文献