Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   

桂西北林旺金矿床构造控矿规律及成矿模式探讨     

张知春 《地质与勘探》2020,56(2):277-287

桂西北林旺金矿是近年来右江盆地新发现的卡林型金矿,位于乐业碳酸盐台地边缘乐业-浪全同生断裂带上。通过对矿区进行野外调查、岩矿鉴定并结合勘探成果进行综合研究,发现I号矿体群与断裂、褶皱的时空联系具有构造分带的特征,以F1断层为界,上盘褶皱鞍部发育石英杂砂岩夹粉砂质泥岩矿体,矿体近F1断层破碎带部位发育破碎的硅化构造岩带,F1下盘近破碎带部位发育强烈劈理化、炭化粉砂质泥岩带,指示矿区在印支期挤压过程中,石英杂砂岩顺着先存构造薄弱面以泥岩层为滑动系统,往上部逆冲并逐渐发生褶皱,产生许多张裂隙,成为成矿流体富集的场所。林旺金矿床是层滑-褶皱构造体系与成矿流体耦合作用的产物,分析了矿床构造成矿规律,提出了以层滑-褶皱运动机制为基础的成矿模式以及成矿远景。  相似文献   

北京区域成矿规律综述   总被引：1，自引：0，他引：1  

方同明  高学泉  刘林生  刘旭东  李莉  程新彬  何付兵  张晓亮  董静  林天懿  郭高轩 《地质学报》2020,94(1):36-49

2013～2019年开展的"中国矿产地质志·北京卷"项目是全面总结北京地区现代地质矿产工作,特别是新中国成立以来北京地区矿产勘查与研究成果,旨在全面反映北京市矿产全貌及重要成矿规律。本文是对该项工作部分成果的概括总结。系统收集了北京市铁、金、煤、石灰岩等各类矿产资料,划分了矿种矿床类型,重点对铁、金、煤、石灰岩等矿种成矿地质特征进行了阐述。在全国Ⅰ-Ⅲ级成矿区带划分基础上,结合北京市地质构造演化和成矿特点,提出北京市区域成矿区带划分方案,划分了怀柔北金萤石成矿区、八达岭金铜钼铅锌成矿区、京西煤石灰岩成矿区、密云-怀柔铁金成矿区、密云-平谷金石灰岩成矿区5个Ⅴ级成矿区,总结了不同区带各矿种规律特征。从矿产时空演化、岩浆岩控矿、构造控矿角度进行了区域成矿规律总结,提升了北京地区矿产地质研究水平,填补了北京区域成矿规律多矿种综合性研究的空白。  相似文献   

内蒙古呼伦西白地区铌稀土多金属矿成矿特征及找矿标志     

胡二红  贺中银  张善明  吕新彪  阮班晓  赵鹏彬  孙浩  纪鹏飞  何世明  苏波  刘婷 《中国地质》2020,47(2):300-314

北山成矿带东缘的内蒙古呼伦西白地区近年来发现了多处铌稀土矿床(点),矿床(点)产于二叠纪二长花岗岩外接触带上,矿体赋存于滨浅海相碳酸盐岩-变碎屑岩内,其形态、产状、规模受构造-岩浆活动控制,并与磁异常对应,其中灰石山东北铌稀土矿区Nb2O5品位0.02%～0.56%、平均0.11%,REO品位0.13%～2.63%,平均0.93%,辉森乌拉西铌金矿区Nb2O5品位0.01%～0.1%,与白云鄂博Nb-REE-Fe超大型矿床特征类似,成矿潜力巨大。结合区域地质背景及铌稀土多金属矿成矿特征,初步认为区内该类型矿床的找矿标志为:二叠系滨浅海相碳酸盐岩-变碎屑岩地层、构造挤压形成的虚脱空间或韧-脆性转换部位、二叠纪二长花岗岩外接触带、放射性异常梯度带-磁异常位置、岩石蚀变(褐铁矿化、硅化、碳酸盐化等)和石英细网脉发育地段。对该地区铌稀土多金属矿成矿特征和找矿标志的研究有利于拓展北山地区三稀矿产的找矿思路,也可为此类矿产的找矿方向提供借鉴。  相似文献   

Mesocosm experiments identifying hotspots of groundwater upwelling in a water column by fibre optic distributed temperature sensing          下载免费PDF全文

Amaya Irene Marruedo Arricibita  Stefan Krause  Jesus Gomez‐Velez  David M. Hannah  Jörg Lewandowski 《水文研究》2018,32(2):185-199

Lacustrine groundwater discharge (LGD) can substantially impact ecosystem characteristics and functions. Fibre optic distributed temperature sensing (FO‐DTS) has been successfully used to locate groundwater discharge into lakes and rivers at the sediment–water interface, but locating groundwater discharge would be easier if it could be detected from the more accessible water surface. So far, it is not clear if how and under which conditions the LGD signal propagates through the water column to the water surface–atmosphere interface, and what perturbations and signal losses occur along this pathway. In the present study, LGD was simulated in a mesocosm experiment. Under winter conditions, water with temperatures of 14 to 16 °C was discharged at the bottom of a 10 × 2.8‐m mesocosm. Water within this mesocosm ranged from 4.0 to 7.4 °C. Four layers (20, 40, 60, and 80 cm above the sediment) of the 82 cm deep mesocosm were equipped with FO‐DTS for tracing thermal patterns in the mesocosm. Aims are (a) to test whether the positive buoyancy of relatively warm groundwater imported by LGD into shallow water bodies allows detection of LGD at the lake's water surface–atmosphere interface by FO‐DTS, (b) to analyse the propagation of the temperature signal from the sediment‐water interface through the water column, and (c) to learn more about detectability of the signal under different discharge rates and weather conditions. The experiments supported the benchmarking of scale dependencies and robustness of FO‐DTS applications for measuring upwelling into aquatic environments and revealed that weather conditions can have important impacts on the detection of upwelling at water surface–atmosphere interfaces at larger scales.  相似文献   

鲁西潘店地区矽卡岩型铁矿成矿规律初探   总被引：1，自引：0，他引：1       下载免费PDF全文

郝兴中  刘伟  臧凯  张学松 《山东国土资源》2018,34(7)

近年来,在鲁中隆起区西北部潘店地区的铁矿勘查工作取得了重大进展。该区发育有明显的航磁异常及航空重力异常,且具有"重磁同源性"特征;通过对航磁异常的分析,可分为李屯、潘店、大张和薛官屯4个次级磁异常。勘查工作表明,区内巨厚新生界覆盖层下发育有矽卡岩型铁矿床,总体表现为"地层、岩体和构造"联合控矿的特征,即铁矿体受控于奥陶纪马家沟群碳酸盐地层、中生代燕山晚期闪长岩体、以及地层与岩体接触处形成的各种类型(构造)接触带。区内铁矿体赋存位置多样,主要为接触带赋存式、断裂充填式、层间充填式、裂隙贯入式、捕虏体构造式等;其成矿时代为早白垩世(130~131Ma),与济南、莱芜、金岭地区矽卡岩型铁矿形成时代基本一致;铁矿物质主要来源于中—基性侵入岩体。在整体表现为具有(剩余)重力异常高值处、(化极)磁异常明显部位,以及高—低电阻率转换带的地段进行铁矿勘查工作较为有利。  相似文献   

水动力条件对沉积物-水界面氧通量的影响   总被引：2，自引：0，他引：2  

郑阳华  邹浩东  何强  李宏  张青  陈德敏  艾海男 《湖泊科学》2018,30(6):1552-1559

氧环境决定了水体沉积物中各种生命所需元素的最终归趋，沉积物-水界面是水相与沉积物相氧传递的重要场所，而水动力条件是影响沉积物-水界面氧传递的重要因素.选择三峡库区一级支流御临河为研究对象，根据长年监测数据建立实验室模型，采用声学多普勒流速测试仪及微电极测试系统构建了非侵入式涡度相关测试系统，探究了不同水动力条件对沉积物-水界面氧通量的影响.结果表明：水体静止状态下沉积物-水界面溶解氧浓度随时间的增加而减少，非静止状态下随时间的增加而增加；沉积物-水界面氧通量随水体流速的增加而增加.根据氧通量求解对应流速下垂直涡动扩散系数并进行线性拟合，当水体流速为0.01~0.14 m/s时，垂直涡动扩散系数与水体流速的相关性最好，此时沉积物-水界面氧通量的传递以涡动扩散为主导.  相似文献   

辽阳灯塔M_S5.1地震震源深度分析     

谢弘臻  王九洋 《中国地震》2018,34(4):704-712

对不同震中距台站的记录采用入射角法、s PL-Pg等震相到时差,对辽宁地震台网记录采用单纯形法研究了辽阳灯塔5.1级地震的震源深度。结果表明,该地震震源深度应为14km,略大于目录给出的10km。利用四川松潘台、青海湟源台的远台记录也得到同样的结果。通过对辽宁1970年以来5.0级以上地震进行分析发现,辽宁地震的震源分布存在东西两侧偏深、中部偏浅、中部地区南浅北深的统计规律,灯塔地震震源深度符合该统计规律。  相似文献   

筋土界面特性宏细观分析试验仪器研制与应用     

易富  杜常博  王政宇  于犇 《煤田地质与勘探》2020,48(1):174-182

为了更全面地分析筋土界面相互作用特性，改制了一台可视加筋土界面特性宏细观分析的试验仪器，可开展不同土工合成材料与填料的直剪和拉拔试验；该仪器改进了试验箱的尺寸，可方便两种试验的对比分析，增加了图像摄录系统，可进行试验过程的细观分析。使用新研制仪器分别进行了土工合成材料（土工格栅和土工布）加筋尾矿砂的直剪和拉拔试验，试验结果表明:两种试验条件下，土工格栅与尾矿的界面参数（似黏聚力和似摩擦角）及似摩擦系数均比土工布与尾矿的界面参数和似摩擦系数大；直剪试验下筋材网孔的有无对筋-尾矿界面参数均有较大影响，拉拔试验下筋材网孔有无对筋-尾矿界面参数似黏聚力的影响较为显著，对似摩擦角的影响较小。随着宏观变量法向应力的增加，细观参数孔隙率减小，平均接触数增加，反映在宏观上的现象就是填料颗粒被压密，筋材需要克服的阻力增大。该试验仪器能够较好地分析筋土界面宏细观特性，获得关键技术指标以用于加筋结构的设计。   相似文献   

老挝帕莱通铁矿床西矿段磁铁矿地球化学特征及其成矿意义     

孙策  彭惠娟  熊富浩  侯林 《矿床地质》2020,39(3):523-546

帕莱通铁矿床是老挝万象—呵叻中新生代盆地中最大规模的铁矿床,分为东、西2个矿段,西矿段为豆状、块状富磁铁矿矿体,东部则主要发育角砾状贫赤铁矿矿体。其中,西矿段主要产于新生代富铁质玄武岩中。文章对西矿段中豆状、块状磁铁矿进行了详细的野外地质调查和显微结构分析,发现块状磁铁矿具有细粒他形结构特征,豆状磁铁矿具有球粒同心圆状结构特征。对较为新鲜的磁铁矿进行电子探针(EPMA)以及激光剥蚀电感耦合等离子质谱(LA-ICP-MS)分析显示:帕莱通铁矿床磁铁矿TiO_2-Al_2O_3-MgO三角图落入岩浆岩区域;微量元素富集V、Ti、Cr、Co、Ni及Ga等元素,亏损Sr、Ba及Mg等不相容元素;w(Co)和w(Ni)较高,且较高的Ni/Co比值可以反映成因与深源物质;w(Ti)较高且Ni/Cr比值≤1,在Ti-Ni/Cr图中落入了热液型磁铁矿的范围;Ga-Sn图解表明磁铁矿属于斑岩型热液成因;(Ca+Al+Mn)-(Ti+V)或Ni/(Cr+Mn)-(Ti+V)成因判别图显示该矿床兼具Kiruna型和斑岩型矿床的特征;w(V)表明磁铁矿在较低氧化环境中形成;(Al+Mn)-(Ti+V)形成温度判别图表明磁铁矿形成温度处于300～500℃范围内。文章认为帕莱通铁矿床成矿物质主要源于岩浆演化作用形成的富铁流体,后期由于岩浆热液流体的交代作用,使得磁铁矿具有了热液成因的特征。岩浆型矿床类型在老挝及邻区分布较为广泛,研究帕莱通铁矿的成因,对于总结区域成矿规律,指导同类型矿床找矿预测具有重要意义。  相似文献