两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究          下载免费PDF全文

常俊男  田晓清  樊成奇  黄金昌  陆亚男  韩清华 《极地研究》2020,32(1):60-67

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。  相似文献   

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI     

Janaína N. vila  Trevor R. Ireland  Peter Holden  Peter Lanc  Andrew Latimore  Norm Schram  John Foster  Ian S. Williams  Liane Loiselle  Bin Fu 《Geostandards and Geoanalytical Research》2020,44(1):85-102

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.  相似文献   

地震重灾区诱发次生地质灾害风险评价研究   总被引：6，自引：4，他引：2       下载免费PDF全文

李天华  袁永博 《地震工程学报》2018,40(1):111-115

为了揭示地震重灾区与次生地质灾害的关联性,以某地震灾区为例,在分析次生地质灾害类型与危害的基础上,通过计算一次泥石流总量及流量确定其危险度,并引入易损性指数,确定各评价单元次生山地灾害的易损性大小,设置评价指标;结合研究区实际,采用层次分析法构建次生地质灾害风险评价模型,对地震重灾区诱发次生地质灾害风险进行评价。实验以次生地质灾害中的泥石流产生的灾害风险为例进行研究,结果表明,采用本文研究方法可在有效确定地震重灾区诱发次生地质灾害的位置方面具有一定优势,但在纵向地震造成次生地质灾害风险评价方面需进一步进行研究。  相似文献   

一次暴雨过程受不同系统影响的动力热力场结构特征     

任丽  关铭  李有缘  王深义 《气象科技》2019,47(6):959-968

本文使用常规观测资料、卫星云图、自动气象站降水量以及0.25°×0.25°的NCEP/NCAR再分析资料,对出现在东北地区北部受不同系统影响的连续2d暴雨过程的热力和动力场结构特征展开研究。结果表明:24日为暖锋锋生暴雨,暴雨范围大;25日为台风暴雨,暴雨出现在台风移动路径上,为狭长带状。暴雨是由MCS活动造成的,每次短时强降水均与TBB低值中心相对应,台风倒槽内的MCS强度比暖锋云系内的MCS弱,但是降水强度却更大。台风安比携带大量暖湿空气,其东侧的低空急流向北输送热量和水汽,水汽辐合集中在边界层内,台风暴雨的水汽辐合强度比暖锋暴雨更强烈,所造成的雨强更大。暖锋暴雨期间,小兴安岭迎风坡地形的辐合抬升作用明显;高层强辐散及地形辐合抬升作用对暴雨有较大贡献。台风暴雨期间,低空辐合,特别是水汽辐合作用对暴雨有较大贡献;辐合区位于台风倒槽附近,倒槽表现为冷锋性质。  相似文献   

红河油田低压易漏地层水平段固井技术          下载免费PDF全文

闫吉曾 《探矿工程》2018,45(5):40-45

为提高红河油田水平井固井质量,满足后期分段压裂需求,对红河油田水平井固井技术进行了研究。针对红河油田水平段固井技术难点,通过室内和现场试验,优选出了GSJ水泥浆体系,基于实测地层压力与地层破裂压力,进行平衡压力固井设计确定了环空浆体结构,为提高顶替效率,优化了扶正器类型与加放位置,专业软件模拟表明套管居中度＞73%,良好的井眼准备和套管漂浮措施确保了管柱的顺利下入;加长胶塞、树脂滚轮刚性旋流扶正器和关井阀等附件的使用,保证了固井质量。现场应用53口水平井,水泥浆全部返至地面,CBL测井结果表明,固井优良率达81.13%。该固井技术成功应用于红河油田水平井中,保证了固井质量,满足了后期分段压裂的需要。  相似文献   

软岩隧道中双层初期支护的应力情况分析          下载免费PDF全文

姚正源 《探矿工程》2018,45(7):73-76

两水隧道穿越的地层主要岩性为炭质千枚岩,地质情况较差,围岩破碎度高,节理发育。自2009年两水隧道开工建设以来,隧道工程问题层出不穷,出现了初期支护开裂、破坏,甚至出现二衬开裂、掉块,仰拱隆起等严重的隧道结构破坏现象,施工进度缓慢。在进口桩号为DK359+712～ DK359+742段采用双层初期支护和单层二次衬砌的支护方式,取得了良好的效果。通过应力情况分析为炭质千枚岩隧道的支护选型提供了依据。  相似文献   

Paleoearthquakes in the Uimon basin (Gorny Altai)     

E.V. Deev  I.D. Zol’nikov  I.V. Turova  G.G. Rusanov  Yu.M. Ryapolova  N.N. Nevedrova  S.A. Kotler 《Russian Geology and Geophysics》2018,59(4):351-362

Paleoseismological studies confirm that the Uimon basin is thrust by its northern mountain border along the active South Terekta fault. The latest motion along the fault in the 7-8th centuries AD induced an earthquake with a magnitude of M_w= 7.4-7.7 and a shaking intensity of I = 9-11 on the MSK-64 scale. The same fault generated another event (M > 7, I = 9-10), possibly, about 16 kyr ago, which triggered gravity sliding. The rockslide dammed the Uimon valley and produced a lake, where lacustrine deposition began about 14 ± 1 kyr ago, and a later M > 7 (I = 9-10) earthquake at ~ 6 ka caused the dam collapse and the lake drainage. Traces of much older earthquakes that occurred within the Uimon basin are detectable from secondary deformation structures (seismites) in soft sediments deposited during the drainage of a Late Pleistocene ice-dammed lake between 100 and 90 ka and in ~ 77 ka alluvium. The magnitude and intensity of these paleoearthquakes were at least M > 5.0-5.5 and I > 6-7.  相似文献   

温敏堵漏水泥浆体系研究与应用          下载免费PDF全文

刘学鹏 《探矿工程》2022,49(2):110-116

温敏形状记忆聚合物是形状记忆材料的一种,其结构中存在记忆起始形状的固定相和随温度变化能可逆地固化和软化的可逆相。本文将这种材料性能应用于石油工程的固井领域,利用温敏聚合物温敏形变的特点,在井下温度升高时激发粒子形变形成大形变体,为封堵漏失层提供架桥结构,解决固井水泥浆防漏堵漏效果差、水泥车不能泵送较大尺寸颗粒的难题。研制的温敏堵漏材料初始粒径1 mm,达到温敏点后体积形变膨胀,应用温度60~140 ℃,加量0~2% BWOC;据此构建的温敏堵漏水泥浆体系,能有效封堵2 mm的缝隙板,承压7 MPa。温敏堵漏水泥浆先后在东北分公司北209井、北8井、北213-1井等的尾管或油层固井中进行了现场应用,尤其在北213-1井的固井堵漏过程中有效解决了固井漏失难题。  相似文献   

Anatomical Study of Cretaceous, Permineralized, Bennettitalean Fossils from Heilongjiang Province, NE China     

LIU Fengxiang  YANG Xiaonan  CHENG Yeming 《《地质学报》英文版》2022,96(5):1495-1501

Well-preserved Cretaceous trunk fragments of Cycadeoidea (Cycadeoidaceae) were recently found in Keshan County, Heilongjiang Province, Northeast China. These fossils represent important evidence of the distribution of this group of plants in East Asia. In these trunk fragments, the stem cortices and leaf bases with cones are preserved. The leaf bases are rhombic with cones infrequently distributed among leaf bases. The cortex is broad and consists of fundamental parenchyma cells, numerous secretory ducts and C-shaped leaf traces with adaxial secondary xylem and abaxial secondary phloem. The genus Cycadeoidea, which is widely distributed in the Cretaceous deposits of East Asia, North America and Western Europe, was an important component of Cretaceous floras. Bennettitalean trunk fossils with well-preserved anatomical structures are rarely known from China. These fossils are important for studies of the evolution of genus Cycadeoidea and for stratigraphic correlation.  相似文献