两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究          下载免费PDF全文

常俊男  田晓清  樊成奇  黄金昌  陆亚男  韩清华 《极地研究》2020,32(1):60-67

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。  相似文献   

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI     

Janaína N. vila  Trevor R. Ireland  Peter Holden  Peter Lanc  Andrew Latimore  Norm Schram  John Foster  Ian S. Williams  Liane Loiselle  Bin Fu 《Geostandards and Geoanalytical Research》2020,44(1):85-102

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.  相似文献   

地震重灾区诱发次生地质灾害风险评价研究   总被引：6，自引：4，他引：2       下载免费PDF全文

李天华  袁永博 《地震工程学报》2018,40(1):111-115

为了揭示地震重灾区与次生地质灾害的关联性,以某地震灾区为例,在分析次生地质灾害类型与危害的基础上,通过计算一次泥石流总量及流量确定其危险度,并引入易损性指数,确定各评价单元次生山地灾害的易损性大小,设置评价指标;结合研究区实际,采用层次分析法构建次生地质灾害风险评价模型,对地震重灾区诱发次生地质灾害风险进行评价。实验以次生地质灾害中的泥石流产生的灾害风险为例进行研究,结果表明,采用本文研究方法可在有效确定地震重灾区诱发次生地质灾害的位置方面具有一定优势,但在纵向地震造成次生地质灾害风险评价方面需进一步进行研究。  相似文献   

一次暴雨过程受不同系统影响的动力热力场结构特征     

任丽  关铭  李有缘  王深义 《气象科技》2019,47(6):959-968

本文使用常规观测资料、卫星云图、自动气象站降水量以及0.25°×0.25°的NCEP/NCAR再分析资料,对出现在东北地区北部受不同系统影响的连续2d暴雨过程的热力和动力场结构特征展开研究。结果表明:24日为暖锋锋生暴雨,暴雨范围大;25日为台风暴雨,暴雨出现在台风移动路径上,为狭长带状。暴雨是由MCS活动造成的,每次短时强降水均与TBB低值中心相对应,台风倒槽内的MCS强度比暖锋云系内的MCS弱,但是降水强度却更大。台风安比携带大量暖湿空气,其东侧的低空急流向北输送热量和水汽,水汽辐合集中在边界层内,台风暴雨的水汽辐合强度比暖锋暴雨更强烈,所造成的雨强更大。暖锋暴雨期间,小兴安岭迎风坡地形的辐合抬升作用明显;高层强辐散及地形辐合抬升作用对暴雨有较大贡献。台风暴雨期间,低空辐合,特别是水汽辐合作用对暴雨有较大贡献;辐合区位于台风倒槽附近,倒槽表现为冷锋性质。  相似文献   

软岩隧道中双层初期支护的应力情况分析          下载免费PDF全文

姚正源 《探矿工程》2018,45(7):73-76

两水隧道穿越的地层主要岩性为炭质千枚岩,地质情况较差,围岩破碎度高,节理发育。自2009年两水隧道开工建设以来,隧道工程问题层出不穷,出现了初期支护开裂、破坏,甚至出现二衬开裂、掉块,仰拱隆起等严重的隧道结构破坏现象,施工进度缓慢。在进口桩号为DK359+712～ DK359+742段采用双层初期支护和单层二次衬砌的支护方式,取得了良好的效果。通过应力情况分析为炭质千枚岩隧道的支护选型提供了依据。  相似文献   

Paleoearthquakes in the Uimon basin (Gorny Altai)     

E.V. Deev  I.D. Zol’nikov  I.V. Turova  G.G. Rusanov  Yu.M. Ryapolova  N.N. Nevedrova  S.A. Kotler 《Russian Geology and Geophysics》2018,59(4):351-362

Paleoseismological studies confirm that the Uimon basin is thrust by its northern mountain border along the active South Terekta fault. The latest motion along the fault in the 7-8th centuries AD induced an earthquake with a magnitude of M_w= 7.4-7.7 and a shaking intensity of I = 9-11 on the MSK-64 scale. The same fault generated another event (M > 7, I = 9-10), possibly, about 16 kyr ago, which triggered gravity sliding. The rockslide dammed the Uimon valley and produced a lake, where lacustrine deposition began about 14 ± 1 kyr ago, and a later M > 7 (I = 9-10) earthquake at ~ 6 ka caused the dam collapse and the lake drainage. Traces of much older earthquakes that occurred within the Uimon basin are detectable from secondary deformation structures (seismites) in soft sediments deposited during the drainage of a Late Pleistocene ice-dammed lake between 100 and 90 ka and in ~ 77 ka alluvium. The magnitude and intensity of these paleoearthquakes were at least M > 5.0-5.5 and I > 6-7.  相似文献   

Anatomical Study of Cretaceous, Permineralized, Bennettitalean Fossils from Heilongjiang Province, NE China     

LIU Fengxiang  YANG Xiaonan  CHENG Yeming 《《地质学报》英文版》2022,96(5):1495-1501

Well-preserved Cretaceous trunk fragments of Cycadeoidea (Cycadeoidaceae) were recently found in Keshan County, Heilongjiang Province, Northeast China. These fossils represent important evidence of the distribution of this group of plants in East Asia. In these trunk fragments, the stem cortices and leaf bases with cones are preserved. The leaf bases are rhombic with cones infrequently distributed among leaf bases. The cortex is broad and consists of fundamental parenchyma cells, numerous secretory ducts and C-shaped leaf traces with adaxial secondary xylem and abaxial secondary phloem. The genus Cycadeoidea, which is widely distributed in the Cretaceous deposits of East Asia, North America and Western Europe, was an important component of Cretaceous floras. Bennettitalean trunk fossils with well-preserved anatomical structures are rarely known from China. These fossils are important for studies of the evolution of genus Cycadeoidea and for stratigraphic correlation.  相似文献   

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis     

Alicja Wudarska  Ewa S&#x;aby  Michael Wiedenbeck  Jaime D. Barnes  Magali Bonifacie  Neil C. Sturchio  Grard Bardoux  Frdric Couffignal  Johannes Glodny  Linnea Heraty  Timm John  Christof Kusebauch  Sathish Mayanna  Franziska D. H. Wilke  Ewa Deput 《Geostandards and Geoanalytical Research》2021,45(1):121-142

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.  相似文献   

渤海湾盆地黄骅坳陷石炭系—二叠系烃源岩生烃演化及与中—新生代构造演化的响应关系     

马妍  孙永河  柳少波  马钰凯  刘海涛  赵长毅 《地质论评》2023,69(2):496-512

渤海湾盆地石炭系—二叠系为烃源岩的古生界潜山内幕型原生油气藏认识程度低,勘探难度大,明确石炭系—二叠系烃源岩生烃演化过程及与中—新生代构造演化的响应关系对内幕型原生油气藏勘探具有重要意义。笔者等基于三维地震资料、典型井实测镜质体反射率、流体包裹体等数据资料,进一步采用构造解析、潜山埋藏史分析以及盆地生烃模拟等技术手段,探讨了渤海湾盆地黄骅坳陷中—新生代构造运动及对石炭系—二叠系烃源岩生烃演化的控制作用,明确了生烃时期及有利生烃范围。研究表明,黄骅坳陷中—新生代构造活动经历了“两期裂陷,两期抬升”的四个演化阶段,形成多种类型的埋藏史,构造运动引起的古地温变化使南北地区烃源岩进行差异了生烃演化,裂陷建造作用促进地温上升,有利于有机质生烃,挤压改造作用抑制地温上升,有机质生烃中止。乌马营潜山及歧北潜山具有3次生烃阶段,生烃期为早—中三叠纪、早白垩纪、古近纪,港北潜山具有两次生烃阶段,生烃期为早—中三叠纪、古近纪。黄骅坳陷内早期(即早—中三叠纪)生烃范围局限,晚期(即古近纪)生烃最有利,乌马营地区及歧北地区为原生油气藏有利勘探区。  相似文献