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1.
大同地区早中生代煌斑岩—碳酸岩岩墙群 总被引：13，自引：7，他引：13
大同地区密集分布的岩墙群由基性－超基性煌斑岩和碳酸岩组成，侵入石炭－二叠纪煤层中。与地层的接触关系和Rb-Sr,K-Ar同位素年代学数据表明墙群的侵位于晚三叠世。Sr,Nd同位素比值显示，碳酸岩和煌斑岩都来源于壳幔混合型岩浆源区。稳定元素比值和相容，不相容元素同等富集则表明是碳酸岩和硅酸盐混合的原始母岩浆液态不混熔的产物。 岩墙群形成的地质条件和构造背景表明，它们是在伸展构造背景下，受到不同级别的构造控制，大同岩墙群的研究对进一步认识华北早中生代岩石圈演化有重要的意义。 相似文献
2.
甘肃礼县新生代火山喷发碳酸岩的发现及意义 总被引：7，自引：8，他引：7
甘肃礼县新生代钾霞橄黄长岩中有大量火山喷发碳酸岩出露，本文对该区各种碳酸岩的地质产状，岩石特征，全岩化学及稀土，微量和C、O同位素地球化学进行了研究，结果表明本区碳酸岩属于一种高CaO低碱（Na2O K2O)的火成碳酸岩，其化学成分与东非裂谷乌干达FortPortal地区的碳酸岩相似，其中碳酸岩的火山砾岩和凝灰岩具有高的SiO2和Mg/Ca比值，化学成分显示了硅酸盐和碳酸盐混合的特征，可能代表直接由地幔部分熔融形成的原生碳酸盐岩浆。其它类型碳酸岩的成因与原生碳酸盐岩浆或原生钾霞橄黄长岩浆的液态不混溶作用和／或结晶分异作用有关。碳酸岩及共生的高钾火山岩不是典型的大陆裂谷岩浆作用的产物，其起源和成因与软流圈的上涌有关。碳酸岩的发现为查明本区地幔的组成和性质提供了新的岩石学证据。 相似文献
3.
山东西部莱芜－淄博地区的中生代雪野碳酸岩中发育有大量罕见的反环带云母，云母的电子探针分析表明，云母斑晶的核心为黑云母，过渡带和边缘是金云母，基质中云母为金云母，核心黑云母与过渡带的金云母界限清晰，成分突变以及核心黑云母的溶蚀结构表明，核心黑云母和过渡带与边缘带金云母不是同一岩浆体系结晶的产物，核心黑云母可能是碳酸岩岩浆捕获的外来黑云母，过渡带与边缘带金云母同基质中金云母具有相似的化学成分，从过渡带到边缘带，金云母的Mg(Mg Fe)逐渐降低，反映了碳酸岩岩浆的不断结晶演化过程，TiO2的不断降低，一方面是由于岩浆的分异结晶，另一方面则是岩浆上升期间去气作用导致岩浆内CO2／H2O值降低所致。云母斑晶从过渡带向边缘带Al2O3含量逐渐减少，表明碳酸岩浆自过渡带云母结晶后没有富Al的圈岩物质加入。 相似文献
4.
Torngat ultramafic lamprophyres and their relation to the North Atlantic Alkaline Province 总被引：3，自引：0，他引：3
Sebastian Tappe George A. Jenner Stephen F. Foley Larry Heaman Dean Besserer Bruce A. Kjarsgaard Bruce Ryan 《Lithos》2004,76(1-4):491-518
Geological mapping and diamond exploration in northern Quebec and Labrador has revealed an undeformed ultramafic dyke swarm in the northern Torngat Mountains. The dyke rocks are dominated by an olivine-phlogopite mineralogy and contain varying amounts of primary carbonate. Their mineralogy, mineral compositional trends and the presence of typomorphic minerals (e.g. kimzeyitic garnet), indicate that these dykes comprise an ultramafic lamprophyre suite grading into carbonatite. Recognized rock varieties are aillikite, mela-aillikite and subordinate carbonatite. Carbonatite and aillikite have in common high carbonate content and a lack of clinopyroxene. In contrast, mela-aillikites are richer in mafic silicate minerals, in particular clinopyroxene and amphibole, and contain only small amounts of primary carbonate. The modal mineralogy and textures of the dyke varieties are gradational, indicating that they represent end-members in a compositional continuum.
The Torngat ultramafic lamprophyres are characterized by high but variable MgO (10–25 wt.%), CaO (5–20 wt.%), TiO2 (3–10 wt.%) and K2O (1–4 wt.%), but low SiO2 (22–37 wt.%) and Al2O3 (2–6 wt.%). Higher SiO2, Al2O3, Na2O and lower CO2 content distinguish the mela-aillikites from the aillikites. Whereas the bulk rock major and trace element concentrations of the aillikites and mela-aillikites overlap, there is no fractional crystallization relation between them. The major and trace element characteristics imply related parental magmas, with minor olivine and Cr-spinel fractionation accounting for intra-group variation.
The Torngat ultramafic lamprophyres have a Neoproterozoic age and are spatially and compositionally closely related with the Neoproterozoic ultramafic lamprophyres from central West Greenland. Ultramafic potassic-to-carbonatitic magmatism occurred in both eastern Laurentia and western Baltica during the Late Neoproterozoic. It can be inferred from the emplacement ages of the alkaline complexes and timing of Late Proterozoic processes in the North Atlantic region that this volatile-rich, deep-seated igneous activity was a distal effect of the breakup of Rodinia. This occurred during and/or after the rift-to-drift transition that led to the opening of the Iapetus Ocean. 相似文献
5.
The concept of compositional bimodality in carbonatites has become widely accepted and has been used to impose restrictions on the composition of carbonatite magmas. We agree that mineralogical bimodality exists in carbonatites (most are either calcitic or dolomitic/ankeritic), but we argue that there is no compositional bimodality. The idea of bimodality is based on the interpretation of a variety of element distribution diagrams which were compiled only from chemical analyses in which SiO2 is < 10 wt.%. All others were rejected. Even with such a restricted data set the case for compositional bimodality is extremely weak, but the inclusion of analyses with higher SiO2 content destroys it completely. Yet these more siliceous compositions must be included, for many carbonatites contain substantial amounts of Fe–Mg silicates which are an essential part of the magmatic mineralogy of the rocks. They account for much of the Mg in carbonatites that are otherwise calcitic. Many such carbonatites contain well in excess of 10 wt.% SiO2. Supporters of the bimodality concept argue that liquids having compositions between calcite and dolomite can precipitate neither calcite nor dolomite because the minimum on the solid solution loops in the system calcite–dolomite permits only a carbonate of intermediate composition. Therefore, it is argued, liquids of such intermediate composition cannot be parental to calcitic and dolomitic carbonatites; their parent magmas must be calcitic and dolomitic. This deduction is incorrect. It is well established that dolomitic liquids have calcite as the liquidus phase over substantial temperature intervals, and that this is followed by dolomite precipitation. Mixed calcite–dolomite carbonatites are explicable in this way. Therefore, dolomitic liquids can be parental to calcitic carbonatites. However, dolomitic carbonatites cannot crystallize from a calcitic liquid. We suggest that intermediate composition carbonatite magmas are probably common. Bimodality in carbonatites is solely mineralogical, not compositional. 相似文献
6.
白云鄂博碳酸岩墙的稀土和微量元素地球化学及对其成因的启示 总被引：11，自引：1，他引：11
根据矿物组成白云鄂博矿区的碳酸岩岩可墙可分为白云石型、白云石－方解石共存型和方解石型三种类型。REE和微量元素地球化学表明，这三类碳酸岩岩墙为碳酸岩浆演化不同阶段的产物，白云石型和白云石－方解石共存型对应于早期岩浆阶段，其（La/Nd)n、(La/Yb)n比值随稀土总量的增加而增大，方解石型则对应于碳酸岩浆演化的晚期热液阶段，其稀土总量明显富集，但其（La/Nd)n、(La/Y)n和（La/Yb)n比值随稀土总量的增加却有减小的趋势，热液阶段也是白云鄂博稀土矿化的主要阶段。 相似文献
7.
P. N. Shukla N. Bhandari Anirban Das A. D. Shukla J. S. Ray 《Journal of Earth System Science》2001,110(2):103-110
We report here an unusually high concentration of iridium in some alkali basalts and alkaline rocks of Deccan region having
an age of about 65Ma, similar to the age of the Cretaceous-Tertiary boundary. The alkali basalts of Anjar, in the western
periphery of Deccan province, have iridium concentration as high as 178pg/g whereas the alkaline rocks and basalts associated
with the Amba Dongar carbonatite complex have concentrations ranging between 8 and 80 pg/g. Some of these values are more
than an order of magnitude higher than the concentration in the tholeiitic basalts of Deccan, indicating the significance
of alkaline magmatism in the iridium inventory at the Cretaceous-Tertiary boundary. Despite higher concentration, their contribution
to the global inventory of iridium in the Cretaceous-Tertiary boundary clays remains small. The concentration of iridium in
fluorites from Amba Dongar was found to be <30 pg/g indicating that iridium is not incorporated during their formation in
hydrothermal activity. 相似文献
8.
F. Stoppa 《Bulletin of Volcanology》1996,57(7):563-577
The late Pleistocene San Venanzo maar and nearby Pian di Celle tuff ring in the San Venanzo area of Umbria, central Italy, appear to represent different aspects of an eruptive cycle accompanied by diatreme formation. Approximately 6x106 m3 of mostly lapillisized, juvenile ejecta with lesser amounts of lithics and 1x106 m3 of lava were erupted. The stratigraphy indicates intense explosive activity followed by lava flows and subvolcanic intrusions. The pyroclastic material includes lithic breccia derived from vent and diatreme wall erosion, roughly stratified lapilli tuff deposited by concentrated pyroclastic surge, chaotic scoriaceous pyroclastic flow and inverse graded grain-flow deposits. The key feature of the pyroclastics is the presence of concentric-shelled lapilli generated by accretion around the lithics during magma ascent in the diatreme conduits. The rock types range from kalsilite leucite olivine melilitite lavas and subvolcanic intrusions to carbonatite, phonolite and calcitic melilitite pyroclasts. Juvenile ejecta contain essential calcite whose composition and texture indicate a magmatic origin. Pyroclastic carbonatite activity is also indicated by the presence of carbonatite ash beds. The San Venanzo maar-forming event is believed to have been trigered by fluid-rich carbonatite-phonolite magma. The eruptive centre the moved to the Pian di Celle tuff ring, where the eruption of degassed olivine melilititic magma and late intrusions ended magmatic activity in the area. In both volcanoes the absence of phreatomagmatic features together with the presence of large amounts of primary calcite suggests carbonatite segregation and violent exsolution of CO2 which, flowing through the diatremes, produced the peculiar intrusive pyroclastic facies and triggered explosions. 相似文献
9.
We report here, for the first time, on the new finding of extrusive calciocarbonatite (alvikite) rocks from the Pleistocene Mt. Vulture volcano (southern Italy). These volcanic rocks, which represent an outstanding occurrence in the wider scenario of the Italian potassic magmatism, form lavas, pyroclastic deposits, and feeder dikes exposed on the northern slope of the volcano. The petrography, mineralogy and whole-rock chemistry attest the genuine carbonatitic nature of these rocks, that are characterized by high to very high contents of Sr, Ba, U, LREE, Nb, P, F, Th, high Nb/Ta and LREE/HREE ratios, and low contents of Ti, Zr, K, Rb, Na and Cs. The O–C isotope compositions are close to the “primary igneous carbonatite” field and, thus, are compatible with an ultimate mantle origin for these rocks. The Sr–Nd–Pb–B isotope compositions, measured both in the alvikites and in the silicate volcanic rocks, indicate a close genetic relationship between the alvikites and the associated melilitite/nephelinite rocks. Furthermore, these latter products are geochemically distinct from the main foiditic-phonolitic association of Mt. Vulture. We propose a petrogenetic/geodynamic interpretation which has important implications for understanding the relationships between carbonatites and orogenic activity. In particular, we propose that the studied alvikites are generated through liquid unmixing at crustal levels, starting from nephelinitic or melilititic parent liquids. These latter were produced in a hybrid mantle resulting from the interaction through a vertical slab window, between a metasomatized mantle wedge, moving eastward from the Tyrrhenian/Campanian region, and the local Adriatic mantle. The occurrence of carbonatite rocks at Mt. Vulture, that lies on the leading edge of the Southern Apennines accretionary prism, is taken as an evidence for the carbonatation of the mantle sources of this volcano. We speculate that mantle carbonatation is related to the introduction of sedimentary carbon from the Adriatic lithosphere during Tertiary subduction. 相似文献
10.
克拉玛依侏罗纪橄榄玄武岩中菱铁矿的成因 总被引：2，自引：5，他引：2
克拉玛依市西盆山交界处发育体罗纪杏仁玄武岩-橄榄玄武岩-含菱铁矿橄榄玄武岩组合,主要由橄榄石、单斜辉石、斜长石(中长石—拉长石为主)、钛铁矿、玄武玻璃及少量磷灰石组成,含菱铁矿橄榄玄武岩中存在原生菱铁矿(≈10%)和少量碱性长石。橄榄石及单斜辉石的Mg~#为≈70,单斜辉石属于富Ti普通辉石。含菱铁矿橄榄玄武岩中的菱铁矿常常包裹浑圆状斜长石,且与斜长石呈锯齿状接触。本文提供的岩相学观察表明,菱铁矿与玄武玻璃、斜长石、单斜辉石和钛铁矿呈明显的共生关系。在有些情况下观察到玄武玻璃与菱铁矿充填在斜长石格架的现象。含菱铁矿橄榄玄武岩玻璃中FeO含量最高至29.2%,CaO含量<1.5%,即熔体具有富Fe贫Ca的特点。早结晶的碳酸盐矿物是以菱铁矿为主的菱铁矿-白云石固溶体(另含少量菱锰矿)。斜长石大量结晶促使熔体不断亏损CaO,并导致较晚结晶的碳酸盐矿物向菱铁矿端元演化。菱铁矿发育有明显的成分梯变带(FeO和CaO含量表现出突变)。玄武玻璃的Mg~#普遍较低且变化范围大,橄榄玄武岩中玻璃的Mg~#值最高为64,含菱铁矿橄榄玄武岩中玻璃的Mg~#值最低至≈23。依据地质温压计,克拉玛依侏罗纪玄武岩浆的形成温度为1300℃～1340℃,压力为3.0～4.0GPa。基于本文的研究,我们认为克拉玛依侏罗纪含菱铁矿橄榄玄武岩岩浆由含CO_2,橄榄岩在软流圈中经极低程度部分熔融形成,该岩浆在快速上升过程中通过结晶分异作用形成了菱铁矿。 相似文献