A modified numerical model for moisture-salt transport in unsaturated sandy soil under evaporation     

Wei Wen  YuanMing Lai  ZheMin You 《寒旱区科学》2020,12(3):125-133

Soil salinization, caused by salt migration and accumulation underneath the soil surface, will corrode structures. To analyze the moisture-salt migration and salt precipitation in soil under evaporation conditions, a mathematical model consisting of a series of theoretical equations is briefly presented. The filling effect of precipitated salts on tortuosity factor and evaporation rate are taken into account in relevant equations. Besides, a transition equation to link the solute transport equation before and after salt precipitation is proposed. Meanwhile, a new relative humidity equation deduced from Pitzer ions model is used to modify the vapor transport flux equation. The results show that the calculated values are in good agreement with the published experimental data, especially for the simulation of volume water content and evaporation rate of Toyoura sand, which confirm the reliability and applicability of the proposed model.  相似文献   

Lead isotope evolution of the Central European upper mantle:Constraints from the Bohemian Massif     

《地学前缘(英文版)》2020,11(3):925-942

The Pb isotope composition of the upper mantle beneath Central Europe is heterogeneous due to the subduction of regionally contrasting material during the Variscan and Alpine orogenies.Late Variscan to Cenozoic mantlederived melts allow mapping this heterogeneity on a regional scale for the last ca.340 Myr.Late Cretaceous and Cenozoic anorogenic magmatic rocks of the Bohemian Massif(lamprophyres,volcanic rocks of basanite/tephrite and trachyte/phonolite series) concentrate mostly in the Eger Rift.Cretaceous ultramafic lamprophyres yielded the most radiogenic Pb isotope signatures reflecting a maximum contribution from metasomatised lithospheric mantle,whereas Tertiary alkaline lamprophyres originated from mantle with less radiogenic ~(206)Pb/~(204)b ratios suggesting a more substantial modification of lithospheric source by interaction with asthenosphericderived melts.Cenozoic volcanic rocks of the basanite/tephrite and trachyte/phonolite series define a linear mixing trend between these components,indicating dilution of the initial lithospheric mantle signature by upwelling asthenosphere during rifting.The Pb isotope composition of Late Cretaceous and Cenozoic magmatic rocks of the Bohemian Massif follows the same Pb growth curve as Variscan orogenic lamprophyres and lamproites that formed during the collision between Laurussia,Gondwana,and associated terranes.This implies that the crustal Pb signature in the post-Variscan mantle is repeatedly sampled by younger anorogenic melts.Most Cenozoic mantle-derived rocks of Central Europe show similar Pb isotope ranges as the Bohemian Massif.  相似文献   

Ressi experimental catchment: Ecohydrological research in the Italian pre-Alps     

Giulia Zuecco  Chiara Marchina  Ylenia Gelmini  Anam Amin  H. J. van Meerveld  Daniele Penna  Marco Borga 《水文研究》2021,35(3):e14095

Ressi is a small (2.4 ha) forested catchment located in the Italian pre-Alps. The site became an experimental catchment to investigate the water fluxes in the soil–plant–atmosphere continuum and the impact of vegetation on runoff generation in 2012. The elevation of the catchment ranges from 598 to 721 m a.s.l. and the climate is humid temperate. The bedrock consists of rhyolites and dacites; the soil is a Cambisol. The catchment is covered by a dense forest, dominated by beech, chestnut, maple, and hazel trees. The field set up includes measurements of the rainfall in an open area, streamflow at the outlet, soil moisture at various depths and locations, and depth to water table in six piezometers at a 5- or 10-min interval. Samples of precipitation, stream water, shallow groundwater and soil water are collected monthly for tracer analysis (stable isotopes (²H and ¹⁸O), electrical conductivity and major ions), and during selected rainfall–runoff events to determine the contribution of the various sources to runoff. Since 2017, soil and plant water samples have been collected to determine the sources of tree transpiration. Data collected in the period 2012–2016 are publicly available. Data collection is ongoing, and the data set is expected to be updated on an annual basis to include the most recent measurements.  相似文献   

DFT对Rb⁺水合团簇及其相关性质的分析          下载免费PDF全文

张文倩  葛蒲  房春晖  周永全  朱发岩  刘红艳  李武 《盐湖研究》2019,27(3):81-92

运用密度泛函理论(DFT)在ωB97XD/gen (O、H元素Aug-cc-PVDZ; Rb元素Lanl2DZ)基组水平上研究了[Rb(H_2O)_n]~+(n=1～12)水合团簇的结构和光谱学性质。研究结果表明,通过分析气相和液相中的稳定能以及水合团簇可知,稳定构型出现在8配位的团簇中。第一配位层水分子数为8时形成Rb~+第一近似饱和水合层。此外,拉曼光谱显示[Rb(H_2O)_n]~+(n=1～12)水合团簇中O-H伸缩振动峰随着水分子数增加发生移动和加宽,Rb~+发生水合时,O-H对称和非对称伸缩振动发生红移,随着水合数的增多,频率蓝移。此外,文中对拉曼光谱中O-H振动的频率位置结合团簇结构进行了说明。  相似文献   

不同氧化还原条件下铅锌矿尾砂中重金属元素活化迁移规律     

李晓艳  张青伟  洪松涛  袁雨婷  余金燕  潘俐傧  刘莹红 《吉林大学学报(地球科学版)》2022,52(2):434-441

以广西大厂镇鲁塘铅锌矿尾砂为研究对象,通过淋滤实验研究了不同氧化还原条件下尾砂中Cu、Cd、Zn、Pb和As等元素的活化和迁移规律。结果表明：经高浓度氧化、高浓度还原条件处理的尾矿表现为pH<7的酸性环境,经低浓度氧化环境条件处理的尾砂呈现pH>7的弱酸性至弱碱性环境;尾砂中Cu、Cd元素活化迁移受pH值的影响明显,即高浓度还原和高浓度氧化条件可以促进Cu和Cd元素的迁移,酸性条件对Cu和Cd元素的迁移起到促进作用;Zn与Cd元素存在竞争吸附关系,但二者仍有明显差别;Pb和As元素受到还原条件的影响,能有效促进Pb和As元素的释放迁移。在淋滤实验前期,铅锌矿的表面阻力较小,由于环境酸碱性的改变,初始尾砂对重金属元素的吸附位能发生变化,重金属元素初期迁移能力得到加强;淋滤后期,矿物颗粒表面由于发生氧化还原反应,促使颗粒表面的阻力增加,重金属元素的溶出量减少,迁移能力受到抑制。  相似文献   

Sources of Inaccuracy in Boron Isotope Measurement Using LA-MC-ICP-MS     

Jan Fietzke  Eleni Anagnostou 《Geostandards and Geoanalytical Research》2023,47(3):481-492

Laser ablation multi-collector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) has become a valuable tool for the in situ measurement of the boron isotope composition of geological samples at high (tens to hundreds of μm) spatial resolution. That said, this application suffers from significant analytical challenges. We focus in this study on the underlying processes of two of the main causes for inaccuracies using this technique. We provide empirical evidence that not only Ca ions (Sadekov et al. 2019, Standish et al. 2019, Evans et al. 2021) but also Ar ions, that are reflected within the flight tube of the mass spectrometer, are the source for previously reported issues with spectral baselines. We also address the impact of plasma conditions on the instrumental mass fractionation as a source for matrix- and mass-load-related analytical biases. Comparing experimental data with the results of a dedicated release and diffusion model (RDM) we estimate that a close to complete (~ 97%) release of boron from the sample aerosol is needed to allow for consistently accurate LA boron isotope measurement results without the need for corrections.  相似文献   

短脉冲激光在实验室天体物理方面的研究进展     

孙嘉宁  袁大伟  王菲鹿 《天文研究与技术》2021,(2):248-254

随着啁啾脉冲放大技术(Chirped Pulse Amplification,CPA)的飞速发展,激光功率密度实现了飞跃式的提升,利用短脉冲激光开展实验室天体物理研究的条件日趋成熟。短脉冲激光与靶相互作用可以产生相对论粒子(正负电子、质子、中子等)和高能电磁辐射(X射线、γ射线),这些粒子和辐射的产生过程与天体中的某些物理现象相对应。介绍了利用短脉冲激光开展实验室天体物理的研究进展,重点介绍了核天体物理、空心离子光谱学、相对论无碰撞冲击波以及等离子体状态诊断等。  相似文献   

Role of Layered Double Hydroxide in Improving the Stability of Aerobic Granular Sludge     

《洁净——土壤、空气、水》2017,45(4)

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Rhizofiltration of a Heavy Metal (Lead) Containing Wastewater Using the Wetland Plant Carex pendula     

Brijesh K. Yadav  Maarten A. Siebel  Johan J. A. van Bruggen 《洁净——土壤、空气、水》2011,39(5):467-474

Rhizofiltration is a subset technique of phytoremediation which refers to the approach of using plant biomass for removing contaminants, primarily toxic metals, from polluted water. The effective implementation of this in situ remediation technology requires experimental as well as conceptual insight of plant–water interactions that control the extraction of targeted metal from polluted water resources. Therefore, pot and simulation experiments are used in this study to investigate the rhizofiltration of a lead containing wastewater using plants of Carex pendula, a common wetland plant found in Europe. The metal contaminant extraction along with plant growth and water uptake rates from a wastewater having varying Pb concentration is studied experimentally for 2 wk. The temporal distribution of the metal concentration in the wastewater and the accumulated metal in different compartments of C. pendula at the end are analyzed using atomic absorption spectrometry. Parameters of the metal uptake kinetics are deduced experimentally for predicting the metal removal by root biomass. Further, mass balance equations coupled with the characterized metal uptake kinetics are used for simulating the metal partitioning from the wastewater to its accumulation in the plant biomass. The simulated metal content in wastewater and plant biomass is compared with the observed data showing a good agreement with the later. Results show that C. pendula accumulates considerable amounts of lead, particularly in root biomass, and can be considered for the cleanup of lead contaminated wastewaters in combination with proper biomass disposal alternatives. Also, the findings can be used for performing further non‐hydroponics experiment to mimic the real wetland conditions more closely.  相似文献   

广东龙门上仓铅锌矿成矿特征及成矿规律研究          下载免费PDF全文

古志宏 《江苏地质》2011,35(2):130-133

龙门上仓铅锌矿是广东省上仓式沉积改造型铅锌矿的典型矿床。通过对龙门上仓铅锌矿的矿床特征进行研究,综合前人的研究成果,归纳总结出该矿床的成矿要素,并且对矿床的成矿模式进行了初步探讨。研究表明,由大赛坝组构成槽部的开阔向斜以及南西翼帽子峰组层间破碎带构成的控矿构造是该矿的必要成矿要素。矿床成因属于岩浆热液—沉积改造型。  相似文献