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1.
Sb, As, Cu, and Zn toxicity and contamination have become a growing concern in recent years. Phytoremediation, a plant based and cost effective technology, may be an effective approach in the cleanup of water contaminated by these metals. In this study, the aquatic macrophyte Eleocharis acicularis was used in laboratory and field experiments to assess its capability to accumulate Sb, As, Cu, and Zn, and thereby investigate its potential application in phytoremediation. The results showed that E. acicularis adapted well to water contaminated by these metals. The removal rates of Sb, As, Cu, and Zn in the laboratory experiment were 3.04, 2.75, 0.417, and 1.49 μg/L/day, respectively. The highest concentrations of these metals accumulated in E. acicularis after 10 days of the laboratory experiment were 6.29, 6.44, 20.5, and 73.5 mg/kg dry weight, respectively. Only 8% of As, 12% of Sb, 87% of Cu and 93% of Zn removed from the water were used by E. acicularis. The highest concentrations of Sb, As, Cu, and Zn accumulated in E. acicularis after 10 wk of the field experiment were 76.0, 22.4, 33.9, and 266 mg/kg dry weight, respectively. The results indicate that E. acicularis has the ability to accumulate Sb, As, Cu, and Zn from contaminated water.  相似文献   

2.
Green-lipped mussels, Perna viridis, and Manila clams, Ruditapes philippinarum were sourced from “clean” sites in the Hong Kong region, depurated in a laboratory using uncontaminated filtered seawater for 8 days, and transplanted to a suspected gradient of chemically polluted sites in Hong Kong. After 14- and 28-days of field exposure, several antioxidant parameters including glutathione S transferase (GST), catalase (CAT), glutathione peroxidase (GPx), and glutathione (GSH) were quantified in gill and hepatopancreas tissues. Whole body tissue concentrations of polycyclic aromatic hydrocarbons (PAHs), petroleum hydrocarbons (PHCs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCs) were determined in pooled site samples. Chemical analyses indicated that: (a) clams had higher levels of PAHs, PHCs, DDTs and PCBs, whereas mussels had higher hexachlorocyclohexane (HCHs) and there was no difference between species for dieldrin and remaining OCs; (b) Kat O should not be continued as a “clean” reference site for Hong Kong, because of the levels of contaminants measured and (c) PAH concentrations in the current survey were similar to those previously measured. Toxicological conclusions were: (a) antioxidant responses were different between species; (b) CAT and GST have highest utility in clams for field use in Hong Kong, whereas CAT in both gill and hepatopancreas tissue showed most potential in mussels; (c) significant induction of antioxidant responses over day 0 (excluding GPx in both tissues, and GST in mussel hepatic tissue); (d) groups of contaminants do not consistently induce antioxidant responses and (e) organochlorines and PCBs correlated significantly with CAT and GST in clam hepatopancreas and with CAT in mussel gill and hepatic tissue. Multivariate statistical techniques indicated little relationship between the site patterns for antioxidant responses and the contaminant gradients identified in body burden analysis.  相似文献   

3.
Accurate determination of the tufa growth rate (TGR) is required to answer the fundamental geomorphological question of tufa evolution. The TGR has been measured by various direct and indirect methods. One of the most popular direct methods uses modified micro-erosion meter (MEM), which has several drawbacks. Here, we present for the first time a coordinate measuring macro-photogrammetry device (CMD) for monitoring the TGR in a contactless manner. The CMD was applied on 28 limestone plates at 14 locations within the Skradinski buk area, Croatia, and measurements were performed in the laboratory. The TGR was derived from digital tufa high-resolution models (DTHRMs). The accuracy of the device was evaluated using state-of-the-art three-dimensional (3D) scanners and error calculation at checkpoints. Moreover, the precision was evaluated with the split test (n = 5). A total of 74 DTHRMs with a spatial resolution of 0.0236 mm were created. The TGR ranged from 0.327 to 19.302 mm a−1, with an average of 5.771 mm a−1. A higher TGR was observed on the limestone plates near mosses, located in fast and turbulent water rather than in stagnant water. We found that specific micro-environmental factors (e.g. proximity to moss) positively affected tufa growth. Erosion events were observed, as well as the presence of aquatic insect larvae (Simuliidae and Chironomidae), which positively affected tufa growth. The CMD is a precise and accurate device that does not suffer from the drawbacks of the MEM method and has many other advantages. It has a high capability of tufa erosion detection, enables the identification of macroinvertebrates, and multispectral or hyperspectral cameras can be mounted on the device for spectral reflectance analysis of the tufa surface. The CMD can be applied in any study requiring a sub-millimetre data quality and involving the comparison of consecutive 3D models and derivation of various parameters of smaller objects. © 2020 John Wiley & Sons, Ltd.  相似文献   

4.
In this study, the distribution and partition of polybrominateddiphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in water from the Pearl River Estuary were investigated. A seasonal dependence for dissolved and particle phase PCB and PBDE levels was observed. A high dissolved phase level occurred in the dry season. The positive correlation between POC content in the particles and phase distribution coefficients (Kp) suggested that POC may play an important role in determining the partition of PBDEs and PCBs. A linear correlation between the observed log KOC and log KOW for PBDEs and PCBs was found with slopes less than one. The observed log KOC values were lower than the predicted log KOC values for PBDEs (except for BDE28). The log KOC values were higher than the predicted values for PCBs. A combination of sorption to colloids (10-98% for PBDEs and less than 25% for PCBs) and adsorption to BC was responsible for this observation.  相似文献   

5.
目的:探讨CT淋巴管造影对淋巴管肌瘤病乳糜胸的诊断价值。方法:回顾性分析2009至2014年我院38例临床或病理证实的LAM患者及172例非LAM乳糜胸患者的临床及影像学资料,所有患者均接受淋巴管造影(DLG)及淋巴管造影后CT检查,由2名医师对CT淋巴管造影(CTL)显示乳糜胸的发生部位、分布类型及胸导管梗阻情况进行分析。结果:CTL显示36例LAM合并乳糜胸。单侧积液23例(右侧11例,左侧12例),双侧积液13例;脏层胸膜型3例,壁层胸膜型7例,混合型4例,未显示型22例。172例非LAM乳糜胸(原发性乳糜胸118例,继发性乳糜胸54例)。118例原发性乳糜胸中,右侧积液26例,左侧积液27例,双侧积液65例;脏层型60例,壁层型15例,混合型23例,未显示型20例。54例继发性乳糜胸中,右侧积液13例,左侧积液3例,双侧积液38例;脏层型43例,壁层型2例,混合型6例,未显示型3例。LAM乳糜胸与原发性乳糜胸的发生部位不存在差异,LAM乳糜胸与继发性乳糜胸的发生部位存在差异。LAM乳糜胸的发生侧别几乎没有差别,继发性乳糜胸常见为双侧。LAM乳糜胸与原发性乳糜胸和继发性乳糜胸在胸膜类型上存在差异,LAM乳糜胸以未显示型最常见,而原发性和继发性乳糜胸以脏层型最常见。结论:CTL可显示LAM乳糜胸的发生类型,提示胸导管梗阻或者腹腔淋巴管压力增高可能是LAM乳糜胸的致病原因,为临床手术治疗LAM乳糜胸提供影像学依据。   相似文献   

6.
探地雷达三维高阶时域有限差分法模拟研究   总被引：11，自引：7，他引：4       下载免费PDF全文
探地雷达数值模拟中,时域有限差分法在时间和空间上一般采用二阶精度的中心差分近似(FDTD(2,2)),其形式简单,但数值色散误差较大,在复杂模型模拟时不能很好地反映模型的精细变化.高阶时域有限差分法能很好地改善数值色散带来的误差,提高模拟精度.本文基于三维高阶时域有限差分法的基本原理实现了探地雷达正演模拟,采用单轴各向异性完全匹配层(UPML)作为吸收边界条件,可以有效地吸收外向传播的电磁波,在大大地提高计算效率的同时,也能很好地改善边界的吸收效果.分析对比正演模拟结果,通过三维高阶时域有限差分正演能获得目标体准确电磁响应信息,并能很好的提高模拟精度.  相似文献   

7.
Snow is an important component of the Earth's climate system and is particularly vulnerable to global warming. It has been suggested that warmer temperatures may cause significant declines in snow water content and snow cover duration. In this study, snowfall and snowmelt were projected by means of a regional climate model that was coupled to a physically based snow model over Shasta Dam watershed to assess changes in snow water content and snow cover duration during the 21st century. This physically based snow model requires both physical data and future climate projections. These physical data include topography, soils, vegetation, and land use/land cover, which were collected from associated organizations. The future climate projections were dynamically downscaled by means of the regional climate model under 4 emission scenarios simulated by 2 general circulation models (fifth‐generation of the ECHAM general circulation model and the third‐generation atmospheric general circulation model). The downscaled future projections were bias corrected before projecting snowfall and snowmelt processes over Shasta Dam watershed during 2010–2099. This study's results agree with those of previous studies that projected snow water equivalent is decreasing by 50–80% whereas the fraction of precipitation falling as snowfall is decreasing by 15% to 20%. The obtained projection results show that future snow water content will change in both time and space. Furthermore, the results confirm that physical data such as topography, land cover, and atmospheric–hydrologic data are instrumental in the studies on the impact of climate change on the water resources of a region.  相似文献   

8.
A comprehensive study aimed at evaluating the occurrence, significance of concentrations and spatial distribution of priority pollutants (PPs) along the Comunidad Valenciana coastal waters (Spain) was carried out in order to fulfil the European Water Framework Directive (WFD). Additionally, PP concentrations were also analysed in the effluent of 28 WWTPs distributed along the studied area. In coastal waters 36 organic pollutants of the 71 analysed, including 26 PPs were detected although many of them with low frequency of occurrence. Only 13 compounds, which belong to four different classes (VOCs, organochlorinated pesticides, phthalates and tributyltin compounds (TBT)) showed a frequency of occurrence above 20% in coastal waters. In the results obtained until now, octylphenol, pentachlorobenzene, DEHP and TBT exceeded the annual average concentration (EQS-AAC), and only TBT surpassed the maximum allowable concentration (EQS-MAC). The most frequent contaminants determined in coastal waters were also present in WWTP effluents.  相似文献   

9.
There is a lack of information on monitoring neurotoxicity in offshore commercial species. To help fill this gap, we sampled hake (Merluccius merluccius) and Norway lobster (Nephrops norvegicus) in fishing grounds off the coast of l’Ametlla de Mar (NW Mediterranean) in June 2005 at a depth of 100 m and 400 m. Additionally, at 400 m depth, two other fish species, Micromesistius poutassou and Phycis blennoides were included. Neurotoxicity markers such as Colinesterases (ChEs), namely acethyl- (AChE), butyryl- (BChE), propionyl- (PrChE) and carboxilesterase (CbE) were measured in muscle. Lipid peroxidation (LP), a marker of oxidative damage, was also included. The results are discussed in relation to the animal’s sex, size and fishing depth. A comparison of esterases and LP levels between muscle and liver of hake and between muscle and hepatopancreas of Norway Lobster was made.

AChE was dominant in muscle and CbE in hepatopancreas. No differences between fish species were seen for AChE. However, N. norvegicus, presented lower levels of ChEs and LP. A size-dependence in ChEs was seen for M. merluccius, with larger animals showing significantly lower activities (p < 0.05). Sex-dependence was seen in N. norvegicus for most esterases, except AChE, with males displaying higher activities (p < 0.05). A sampling-depth effect was also seen in the crustacea, with animals from 100 m generally presenting lower esterase activities and higher LP levels.  相似文献   


10.
《国际泥沙研究》2020,35(4):355-364
The scour and deposition pattern around an abutment under constant discharge condition is calculated using a three dimensional (3D) Computational Fluid Dynamics (CFD) model. The Reynolds-Averaged Navier Stokes (RANS) equations are solved in three dimensions using a CFD model. The Level Set Method (LSM) is used for calculation of both free surface and bed topography. The two-equation turbulence model (k-ε and k-ω) is used to calculate the eddy viscosity in the RANS equations. The pressure term in the RANS equations on a staggered grid is modeled using the Chorin's projection method. The 5th order Weighted Essentially Non-Oscillatory (WENO) scheme discretizes the convective term of the RANS equations. The Kovacs and Parker and Dey formulations are used for the reduction in bed shear stress on the sloping bed. The model also used the sandslide algorithm which limits bed shear stress reduction during the erosion process. The numerical model solution is validated against experimental results collected at the Politecnico di Milano, Milan, Italy. Further, the numerical model is tested for performance by varying the grid sizes and key parameters like the space and time discretization schemes. The effect of varying bed porosity has been evaluated. Overall, the free surface is well represented in a realistic manner and bed topography is well predicted using the Level Set Method (LSM).  相似文献   

11.
The Joint FAO/WHO/IOC ad hoc Expert Consultation on Biotoxins in Molluscan Bivalves performed risk assessments for a number of biotoxins present in bivalve molluscs. For performing risk assessments, the Expert Consultation categorized the biotoxins into eight distinct groups based on chemical structure. The Expert Consultation established LOAELs for the azaspiracid (AZA), okadaic acid (OA), saxitoxin (STX), and domoic acid (DA) toxin groups. The derived provisional acute RfDs for the AZA, OA, STX, and DA toxin groups were 0.04 μg/kg bw, 0.33 μg/kg bw, 0.7 μg/kg bw, and 100 μg/kg bw, respectively. For the yessotoxin (YTX) group, a NOAEL was established, based on animal studies. Applying a safety factor of 100, a provisional acute RfD of 50 μg/kg bw was suggested for the YTX group. The Expert Consultation considered that the database for cyclic imines, brevetoxins, and pectenotoxins was insufficient to establish provisional acute RfDs for these three toxin groups.  相似文献   

12.
ABSTRACT

Karst aquifers and springs are important with respect to their potential for supplying drinking water in regions suffering from water scarcity in Iran. Accordingly, it is essential to determine the recharge potential of the catchment and the regions with higher obtainability potential. This study provides a road map for the Sheshpeer catchment in southern Iran. A recharge potential (RP) map was produced from which a recharge index (RI) was computed for several selected springs in the catchment. Furthermore, the unit discharge (q) – defined as the average annual discharge for a given catchment area and unit rainfall depth for each spring – was calculated. The plot of q versus RI for the springs showed a linear positive relationship between the two variables (R 2 = 0.9). Applying the trend equation of this plot to the whole Sheshpeer karstic catchment reveals that its long-term recharge coefficient is 0.74.  相似文献   

13.
This paper describes the results of a preliminary study to determine the effective heating and cooling time constants of ionospheric currents in a simulated modulated HF heating, ‘beam painting’ configuration. It has been found that even and odd harmonics of the fundamental ELF wave used to amplitude modulate the HF heater are sourced from different regions of the ionosphere which support significantly different heating and cooling time constants. The fundamental frequency and its odd harmonics are sourced in a region of the ionosphere where the heating and cooling time constants are about equal. The even harmonics on the other hand are sourced from regions of the ionosphere characterised by ratios of cooling to heating time constant greater than ten. It is thought that the even harmonics are sourced in the lower ionosphere (around 65 km) where the currents are much smaller than at the higher altitudes around 78 km where the currents at the fundamental frequency and odd harmonics maximise.  相似文献   

14.
ABSTRACT

Ten notable meteorological drought indices were compared on tracking the effect of drought on streamflow. A 730-month dataset of precipitation, temperature and evapotranspiration for 88 catchments in Oregon, USA, representing pristine conditions, was used to compute the drought indices. These indices were correlated with the monthly streamflow datasets of the minimum, maximum and mean discharge, and the discharge monthly fluctuation; it was revealed that the 3-month Z-score drought index (Z3) has the best association with the four streamflow variables. The Mann-Kendall trend detection test applied to the latter index time series mainly highlighted a downward trend in the autumn and winter drought magnitude (DM) and an upward trend in the spring and summer DM (p = 0.05). Finally, the Pettitt test indicated an abrupt decline in the annual and autumn DM, which began in 1984 and 1986, respectively.  相似文献   

15.
大地电磁二维陡边界反演应用效果分析   总被引：2，自引：0，他引：2       下载免费PDF全文
针对石油勘探中常常遇到大块具有均匀电导率的地质单元被高陡边界分割的情况,传统的光滑反演各具特色但均有边界位置模糊的缺点,而陡边界反演方法可以有效地克服这种缺点.本文从应用的角度出发,对陡边界反演方法的原理作了详细的介绍,并应用该反演方法对两个块状结构模型的合成数据进行了反演,反演结果的拟合差分别为rms=1.66和rms=1.27,表明该方法反演结果能准确地恢复到真实模型附近;通过对比该方法与快速松弛法在实测数据中的应用,表明该方法有助于提高MT反演分辨率.但是该方法对模型参数设置和所知道的地质信息的准确性要求较高.  相似文献   

16.
本文分析了腹部平片,静脉肾盂造影,B 超及CT 对肾脏疾病的诊断价值。CT 的组织分辨力为普通X 线的十倍,并能提供二维图象,对肾囊肿,结石等疾病可作出定性及定量诊断。静脉肾盂造影有禁忌症限制。B 超受到肠道积气及脂肪影响。4cm 以上肿块行B 超导引穿刺,而深部小于4cm 病灶应行CT 导引下穿刺。  相似文献   

17.
The statistical characteristics of precipitation on the daily resolution play an important role not only in the risk assessment of floods and droughts but also in the land use management. In this study, spatial and temporal patterns of the precipitation concentration in the Yangtze River Basin are investigated by using three indices, i.e. precipitation concentration index (CI), precipitation concentration degree (PCD) and precipitation concentration period (PCP). Based on meteorological data of 147 stations for the period of 1960–2008, non‐parametric trend analysis and wavelet transformation analysis are employed to detect the temporal variation of these indices. Spatial variability of precipitation concentration indices and their trends are analysed and demonstrated with the help of GIS tools. The results indicate the following: (i) The high precipitation CI values mainly distribute in the middle region of the Yangtze River Basin, whereas the lower and lowest CI values are found in the lower and upper regions, respectively. A roughly east–west gradient for PCD value and PCP value varies from 0.26 to 0.77 and from 123 to 197, respectively. (ii) The analysis results of precipitation CI trends for different periods (i.e. recent 40, 30 and 20 years) show that the middle region of the Yangtze River Basin experienced a transition from decreasing precipitation CI to increasing precipitation CI during the last two decades, although the decreasing long‐term trends in the precipitation CI are not significant in most areas during the period of 1960–2008. (iii) The upper basin, middle basin and lower basin are, respectively, dominated by the significant decreasing, increasing and no significant trends in PCD. A dominance of insignificant PCP trends is observed in the entire basin during 1960–2008 despite that a few areas in the upper region are characterized by significant decreasing trends. (iv) Interdecadal oscillations can be found for three precipitation indices, but with no constant periodicity. Furthermore, good positive correlations have been detected between precipitation CI and PCD, whereas insignificant correlation coefficients of PCP with precipitation are common in the basin. The results can provide beneficial reference to water resource and eco‐environment and mitigation to flood or drought hazards in the Yangtze River Basin for policymakers and stakeholders. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

18.
Asian dust storm (ADS) samples were collected on March 20,2002 in Beijing,China. High-resolution field emission scanning electron microscopy with energy dispersive X-ray detector (FESEM-EDX) and X-ray diffraction (XRD) were used to study the morphology,chemical compositions,number-size dis-tributions and mineralogical compositions of ADS particles. The mineral particles were major compo-nents in the ADS samples,accounting for 94% by number. The XRD analysis indicated that the dust particles were dominated by clay (40.3%),and quartz (19.5%),followed by plagioclase (8.4%),calcite (7.5%),K-feldspar (1.5%),hematite (0.9%),pyrite (0.9%),hornblende (0.4%) and gypsum (0.3%),with a certain amount of noncrystalline materials (20.3%). Clay minerals were mainly illite/smectite mixed lay-ers (78%),followed by illite (9%),kaolinite (6%),and chlorite (7%). In addition to these main minerals,FESEM-EDX also detected some trace minerals,such as dolomite,pyrite,thenardite,as well as heavy minerals represented by rutile,ilmenite and apatite. The mineralogical compositions of the 2002-03-20 Asian dust storm and the Saharan dust plumes were similar but the clay mineralogy showed a great distinction,with the illite/smectite mixed layers being common in the Asian dust storm but illite being common in the Saharan dust plumes.  相似文献   

19.
Daily values of the ionospheric characteristics foF2 and M(3000)F2 for a given hour and month are correlated with the corresponding daily values of sunspot number using measured data collected at seven European locations. The significance of applying different-order polynomials is considered and the times are confirmed when the higher-order terms are important. Mean correlation coefficients for combined data sets over all hours, months and stations are determined, together with the standard errors of estimates. Comparisons are made with corresponding figures for monthly median values derived from the same data sets.  相似文献   

20.
基于Maxwell型阻尼器的多重调谐质量阻尼器性能评价   总被引：1，自引：0，他引：1  
研究了基于Maxwell型阻尼器的多重调谐质量阻尼器(MTD—MTMD)在控制结构地震反应方面的最优动力特性。利用建立的设置MTD-MTMD时结构的传递函数,定义了设置MTD—MTMD时结构的动力放大系数(DMF)。将MTD-MTMD的优化准则定义为结构最大动力放大系数的最小值的最小化(Min．Min．Max．DMF)。利用定义的优化准则,评价了Maxwell型阻尼器的松弛时间系数(RTC)对MTD—MTMD最优参数和有效性的影响。利用最大的MTD—MTMD动力放大系数(DMF),评价了RTC对MTD-MTMD冲程的影响。  相似文献   

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