Laboratory studies of the interaction of carbon monoxide with water ice     

M.P. Collings  J.W. Dever  H.J. Fraser  M.R.S. McCoustra 《Astrophysics and Space Science》2003,285(3-4):633-659

The interaction of carbon monoxide (CO) with vapour-deposited water(H₂O) ices has been studied using temperature programmed desorption (TPD) and Fourier transform reflection-absorption infrared spectroscopy (FT-RAIRS) over a range of astrophysically relevant temperatures. Such measurements have shown that CO desorption from amorphous H₂Oices is a much more complex process than current astrochemical models suggest. Re-visiting previously reported laboratory experiments (Collings et al., 2003), a rate model has been constructed to explain, in a phenomenological manner, the desorption of CO over astronomically relevant time scales. The model presented here can be widely applied to a range of astronomical environments where depletion of CO from the gas phase is relevant. The model accounts for the two competing processes of CO desorption and migration, and also enables the entrapment of some of the CO in the ice matrix and its subsequent release as the water ice crystallises and then desorbs. The astronomical implications of this model are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Origins of high pH mineral waters from ultramafic rocks, Central Portugal     

Jos M. Marques  Paula M. Carreira  Maria Rosrio Carvalho  Maria J. Matias  Fraser E. Goff  Maria J. Basto  Rui C. Graa  Luís Aires-Barros  Luís Rocha 《Applied Geochemistry》2008,23(12):3278-3289

This paper reviews the geochemical, isotopic (²H, ¹⁸O, ¹³C, ³H and ¹⁴C) and numerical modelling approaches to evaluate possible geological sources of the high pH (11.5)/Na–Cl/Ca–OH mineral waters from the Cabeço de Vide region (Central-Portugal). Water–rock interaction studies have greatly contributed to a conceptual hydrogeological circulation model of the Cabeço de Vide mineral waters, which was corroborated by numerical modelling approaches. The local shallow groundwaters belong to the Mg–HCO₃ type, and are derived by interaction with the local serpentinized rocks. At depth, these type waters evolve into the high pH/Na–Cl/Ca–OH mineral waters of Cabeço de Vide spas, issuing from the intrusive contact between mafic/ultramafic rocks and an older carbonate sequence. The Cabeço de Vide mineral waters are supersaturated with respect to serpentine indicating that they may cause serpentinization. Magnesium silicate phases (brucite and serpentine) seem to control Mg concentrations in Cabeço de Vide mineral waters. Similar δ²H and δ¹⁸O suggest a common meteoric origin and that the Mg–HCO₃ type waters have evolved towards Cabeço de Vide mineral waters. The reaction path simulations show that the progressive evolution of the Ca–HCO₃ to Mg–HCO₃ waters can be attributed to the interaction of meteoric waters with serpentinites. The sequential dissolution at CO₂ (g) closed system conditions leads to the precipitation of calcite, magnesite, amorphous silica, chrysotile and brucite, indicating that the waters would be responsible for the serpentinization of fresh ultramafic rocks (dunites) present at depth. The apparent age of Cabeço de Vide mineral waters was determined as 2790 ± 40 a BP, on the basis of ¹⁴C and ¹³C values, which is in agreement with the ³H concentrations being below the detection limit.  相似文献   

Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA     

Mark A. Engle  Fraser Goff  David G. Jewett  Gregory J. Reller  Joel B. Bauman 《Hydrogeology Journal》2008,16(3):559-573

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

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Ruminations of a Dyspeptic Ex-Editor*   总被引：1，自引：0，他引：1  

John Fraser Hart 《The Professional geographer》1976,28(3):225-232

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Quality Assessment Of Digital Surface Models Generated From IKONOS Imagery     

Joanne  Poon  Clive S.  Fraser  Zhang  Chunsun  Zhang  Li  Armin  Gruen 《The Photogrammetric Record》2005,20(110):162-171

The growing applications of digital surface models (DSMs) for object detection, segmentation and representation of terrestrial landscapes have provided impetus for further automation of 3D spatial information extraction processes. While new technologies such as lidar are available for almost instant DSM generation, the use of stereoscopic high-resolution satellite imagery (HRSI), coupled with image matching, affords cost-effective measurement of surface topography over large coverage areas. This investigation explores the potential of IKONOS Geo stereo imagery for producing DSMs using an alternative sensor orientation model, namely bias-corrected rational polynomial coefficients (RPCs), and a hybrid image-matching algorithm. To serve both as a reference surface and a basis for comparison, a lidar DSM was employed in the Hobart testfield, a region of differing terrain types and slope. In order to take topographic variation within the modelled surface into account, the lidar strip was divided into separate sub-areas representing differing land cover types. It is shown that over topographically diverse areas, heighting accuracy to better than 3 pixels can be readily achieved. Results improve markedly in feature-rich open and relatively flat terrain, with sub-pixel accuracy being achieved at check points surveyed using the global positioning system (GPS). This assessment demonstrates that the outlook for DSM generation from HRSI is very promising.  相似文献   

Hyper Redundancy for Accuracy Enhancement in Automated Close Range Photogrammetry   总被引：1，自引：0，他引：1  

Clive S.  Fraser  Alex  Woods  Danny  Brizzi 《The Photogrammetric Record》2005,20(111):205-217

A generic network design in close range photogrammetry is one where optimal multi-ray intersection geometry is obtained with as few camera stations as practicable. Hyper redundancy is a concept whereby, once the generic network is in place, many additional images are recorded, with the beneficial impact upon object point precision being equivalent to the presence of multiple exposures at each camera position within the generic network. The effective number of images per station within a hyper redundant network might well be in the range of 10 to 20 or more. As is apparent when it is considered that a hyper redundant network may comprise hundreds of images, the concept is only applicable in practice to fully automatic vision metrology systems, where it proves to be a very effective means of enhancing measurement accuracy at the cost of minimal additional work in the image recording phase. This paper briefly reviews the network design and accuracy aspects of hyper redundancy and illustrates the technique by way of the photogrammetric measurement of surface deformation of a radio telescope of 26 m diameter. This project required an object point measurement accuracy of σ  = 0·065 mm, or 1/400 000 of the diameter of the reflector.  相似文献   

The molecular universe     

Helen J Fraser  Martin R S McCoustra  David A Williams 《Astronomy& Geophysics》2002,43(2):2.10-2.18

Helen J Fraser , Martin R S McCoustra and David A Williams present a simple guide to astrochemistry.
Molecules play a fundamental role in many regions of our universe. The science where chemistry and astronomy overlap is known as astrochemistry, a branch of astronomy that has risen in importance over recent years. In this article we review the significance of chemistry in several astronomical years. IN this article we review the significance of chemistry in several astronomical environments including the early universe, interstellar clouds, starforming regions and protoplanetary disks. We discuss theoretical models, laboratory experiments and observational data, and present several recent and exciting results that challenge our perception of the "molecular universe".  相似文献   

Atmospheric Methyl Iodide at Cape Grim, Tasmania, from AGAGE Observations     

D. S. Cohan  G. A. Sturrock  A. P. Biazar  P. J. Fraser 《Journal of Atmospheric Chemistry》2003,44(2):131-150

Atmospheric mixing ratios of methyl iodide (CH₃I) and other methyl halides have been measured at Cape Grim, Tasmania (41°S, 145°E), since early 1998 as part of the Advanced Global Atmospheric Gases Experiment (AGAGE). This paper analyses about 1700 ambient air CH₃I measurements from the 14-month period (March 1998–April 1999). Mixing ratios peaked during the summer, despite faster photolytic loss, suggesting local oceanic emissions were about 2.2–3.6 times stronger in summer than in winter. Back trajectories show that CH₃I levels are strongly dependent on air mass origin, with highest mixing ratios in air from the Tasman Sea/Bass Strait region and lowest levels in air originating from the Southern Ocean at higher latitudes. CH₃I mixing ratios were not well correlated with other methyl halides in unpolluted marine air. The large variations with season and air mass origin suggest that high frequency, continuous data from key locations will make a significant contribution to the understanding of sources and sinks of this important short-lived atmospheric species.  相似文献   

Innovations in Automation for Vision Metrology Systems   总被引：1，自引：0，他引：1  

C. S. Fraser 《The Photogrammetric Record》1997,15(90):901-911

The advantages of vision metrology (VM) systems over their film-based counterparts, in terms of the degree of automation within the measurement process, were initially confined to the image mensuration stage. Of late, however, the potential of significantly raising the level of automation of offline and real time VM systems has been more fully exploited, to the point where full automation of the offline procedure has been realized. Innovative features such as automatic image point identification via coded targets, exterior orientation through automatically recognizable "control" groupings of target points, determination of image point correspondences within unlabelled point clouds, and real time tracking of multipoint, handheld measurement probes are now incorporated in industrial VM systems. Another significant innovation is the development of "smart" cameras with incorporated image processing and measurement capabilities which remove the necessity for transmitting image data to the host computer. This paper reviews recent innovations in automation and discusses their operational impact on practical VM applications. The concepts discussed are illustrated through reference to a modern VM system which supports offline and real time measurement.  相似文献   

The making of Stars 'R' Us!     

Serena Viti  Wendy Brown  Martin McCoustra  Helen Fraser  Nigel Mason  Robert Massey 《Astronomy& Geophysics》2004,45(6):6.22-6.24

The team behind a successful project to broaden the understanding of astrochemistry – Serena Viti, Wendy Brown, Martin McCoustra, Helen Fraser, Nigel Mason and Robert Massey – recount how they went about it and what benefits resulted.  相似文献