Experimental partitioning of trace elements into schreibersite with applications to IIG iron meteorites     

Nancy L. Chabot  Rachel H. Cueva  Andrew W. Beck  Richard D. Ash 《Meteoritics & planetary science》2020,55(4):726-743

Some of the defining characteristics of the IIG iron meteorite group are their high bulk P contents and massive, coarse schreibersite, which have been calculated to make up roughly 11–14 wt% of each specimen. In this study, we produced two data sets to investigate the formation of schreibersites in IIG irons: measurements of trace elements in the IIG iron meteorite Twannberg and experimental determinations of trace element partitioning into schreibersite. The schreibersite‐bearing experiments were conducted with schreibersite in equilibrium with a P‐rich melt and with bulk Ni contents ranging from 0 to 40 wt%. The partitioning behavior for the 20 elements measured in this study did not vary with Ni content. Comparison of the Twannberg measurements with the experimental results required a correction factor to account for the fact that the experiments were conducted in a simplified system that did not contain a solid metal phase. Previously determined solid metal/P‐rich melt partition coefficients were applied to infer schreibersite/solid metal partitioning behavior from the experiments, and once this correction was applied, the two data sets showed broad similarities between the schreibersite/solid metal distribution of elements. However, there were also differences noted, in particular between the Ni and P contents of the solid metal relative to the schreibersite inferred from the experiments compared to that measured in the Twannberg sample. These differences support previous interpretations that subsolidus schreibersite evolution has strongly influenced the Ni and P content now present in the solid metal phase of IIG irons. Quantitative attempts to match the IIG solid metal composition to that of late‐stage IIAB irons through subsolidus schreibersite growth were not successful, but qualitatively, this study corroborates the striking similarities between the IIAB and IIG groups, which are highly suggestive of a possible genetic link between the groups as has been previously proposed.  相似文献   

Revisiting the existence of an effective stress for wet granular soils with micromechanics          下载免费PDF全文

Jérôme Duriez  Richard Wan  Mehdi Pouragha  Félix Darve 《国际地质力学数值与分析法杂志》2018,42(8):959-978

A possible effective stress variable for wet granular materials is numerically investigated based on an adapted discrete element method (DEM) model for an ideal three‐phase system. The DEM simulations consider granular materials made of nearly monodisperse spherical particles, in the pendular regime with the pore fluid mixture consisting of distinct water menisci bridging particle pairs. The contact force‐related stress contribution to the total stresses is isolated and tested as the effective stress candidate for dense or loose systems. It is first recalled that this contact stress tensor is indeed an adequate effective stress that describes stress limit states of wet samples with the same Mohr‐Coulomb criterion associated with their dry counterparts. As for constitutive relationships, it is demonstrated that the contact stress tensor used in conjunction with dry constitutive relations does describe the strains of wet samples during an initial strain regime but not beyond. Outside this so‐called quasi‐static strain regime, whose extent is much greater for dense than loose materials, dramatic changes in the contact network prevent macroscale contact stress‐strain relationships to apply in the same manner to dry and unsaturated conditions. The presented numerical results also reveal unexpected constitutive bifurcations for the loose material, related to stick‐slip macrobehavior.  相似文献   

THE NEW INTERNATIONAL DIVISION OF LABOR AND DEBT CRISIS IN THE THIRD WORLD     

Richard Peet 《The Professional geographer》1987,39(2):172-178

The advanced capitalist ccuntries are undergoing an industrial devolution as remarkable as the industrial revolution of the nineteenth century. The removal of high-paying jobs through automation and geographical migration destroys the main market of the center and precipitates debt crises in newly industrialized countries of the periphery which have followed export-oriented growth policies. This results in a new, internationalized form of the crises of iate capitalism and provides a new institutional foucs for crisis in the international banks. The paper examines this global process from the perspective of the geography of class struggle.  相似文献   

Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites     

Milton BLANDER  Arthur D. PELTON  In‐Ho JUNG  Richard WEBER 《Meteoritics & planetary science》2004,39(12):1897-1910

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.  相似文献   

The discovery of new galaxy members in the NGC 5044 and 1052 groups     

N. P. F. MKay  C. G. Mundell †  S. Brough  Duncan A. Forbes  D. G. Barnes  P. A. James  P. Goudfrooij  V. Kozhurina-Platais  R. Whitaker 《Monthly notices of the Royal Astronomical Society》2004,352(4):1121-1134

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Polar shapelets     

Richard Massey  Alexandre Refregier 《Monthly notices of the Royal Astronomical Society》2005,363(1):197-210

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Acceptance of the 2003 Distinguished Service Award     

Hubert L Barnes 《Geochimica et cosmochimica acta》2004,68(9):1969

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Physical parameters of near-Earth asteroid 1982 DV     

Faith Vilas  David J. Tholen  Larry A. Lebofsky  Humberto Campins  Glenn J. Veeder  Richard P. Binzel  Alan T. Tokunaga 《Icarus》1985,63(2):201-205

Visual and infrared observations were made of Amor asteroid 1982 DV during its discovery apparition. Broadband visual and near-infrared photometry shows that it is an S-class asteroid. Narrowband spectrophotometry shows an absorption feature due to olivine or pyroxene or both centered at 0.93 μm. Applying a nonrotating thermal model to 10-μm photometry, the geometric albedo is calculated to be approximately 0.27. The geometric albedo for a slowly rotating, rocky surface was calculated for 1 night to be 0.15, consistent with S-class asteroid albedos. Thus, 1982 DV is either one of the most reflective S-class asteroids known, or a significant amount of bare rock is exposed on the asteroid's surface. For the nonrotating model, ellipsoidal dimensions for 1982 DV are 3.5 × 1.4 × 1.4 km.  相似文献   

GEOGRAPHY ON THE PLANETS: GIFT OF REMOTE SENSING*     

Richard J. Pike 《The Professional geographer》1987,39(2):131-145

Extraterrestrial geography has become a reality, as we move from Earth's moon to the planets. A broad-scale regional physiography is being established on twenty planets and satellites through remote sensing techniques. Spacecraft images yield most of the information on Solar System landscapes. Topographic measurements are extracted by monoscopic image-processing, stereophotogrammetry, and radar analysis. Invisible parts of the spectrum furnish non-topographic data.  相似文献   

Tektite research 1936–1990*     

Virgil E. Barnes 《Meteoritics & planetary science》1990,25(3):149-159

Abstract— Fifty-odd years of tektite research are reviewed, proceeding from the discovery of the first North American tektites in 1936. This included the early recognition that tektites were terrestrial objects rather than meteorites and that the glassy particles in tektites were fused quartz (lechatelierite). Later, during National Science Foundation-supported research, it was found that some tektites appeared to have formed as puddles of melt, that the content and character of bubbles in lechatelierite can be used as a relative temperature scale, that rayed bubbles in tektites formed from hydrous minerals, that bubbles in tektites formed chiefly from water which was absorbed into the walls of the bubbles leaving vacuums, and that “fingers” in the surficial part of some tektites may have formed by differential volatilization. Some unpublished observations and adventures are briefly reported.  相似文献