On the relevance of iron adsorption to container materials in small-volume experiments on iron marine chemistry: Fe-aided assessment of capacity, affinity and kinetics     

A.C. Fischer  J.J. Kroon  T.G. Verburg  T. Teunissen  H.Th. Wolterbeek 《Marine Chemistry》2007,107(4):533-546

Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron ⁵⁵Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10^− 9 mol/m² or 1.7 × 10^− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log K_Fe'W = 11.0 ± 0.3 m²/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 ⁻⁴–10^− 5 L/s and rate constants for association in the order of 10⁸ L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry.  相似文献   

Integer aperture bootstrapping: a new GNSS ambiguity estimator with controllable fail-rate   总被引：1，自引：0，他引：1  

P.J.G. Teunissen 《Journal of Geodesy》2005,79(6-7):389-397

In this contribution, we introduce a new bootstrap-based method for Global Navigation Satellite System (GNSS) carrier-phase ambiguity resolution. Integer bootstrapping is known to be one of the simplest methods for integer ambiguity estimation with close-to-optimal performance. Its outcome is easy to compute due to the absence of an integer search, and its performance is close to optimal if the decorrelating Z-transformation of the LAMBDA method is used. Moreover, the bootstrapped estimator is presently the only integer estimator for which an exact and easy-to-compute expression of its fail-rate can be given. A possible disadvantage is, however, that the user has only a limited control over the fail-rate. Once the underlying mathematical model is given, the user has no freedom left in changing the value of the fail-rate. Here, we present an ambiguity estimator for which the user is given additional freedom. For this purpose, use is made of the class of integer aperture estimators as introduced in Teunissen (2003). This class is larger than the class of integer estimators. Integer aperture estimators are of a hybrid nature and can have integer outcomes as well as non-integer outcomes. The new estimator is referred to as integer aperture bootstrapping. This new estimator has all the advantages known from integer bootstrapping with the additional advantage that its fail-rate can be controlled by the user. This is made possible by giving the user the freedom over the aperture of the pull-in region. We also give an exact and easy-to-compute expression for its controllable fail-rate.  相似文献   

A canonical theory for short GPS baselines. Part II: the ambiguity precision and correlation   总被引：1，自引：0，他引：1  

P. J. G. Teunissen 《Journal of Geodesy》1997,71(7):389-401

The present contribution is the second of four parts. It considers the precision and correlation of the least-squares estimators of the carrier phase ambiguities. It is shown how the precision and correlation of the double-differenced ambiguities as well as of the widelane ambiguities are effected by the observation weights, by the number of satellites tracked, by the number of observation epochs used, and by the change over time of the relative receiver-satellite geometry. Also the ability of the widelane transformation to decorrelate and to improve the precision is investigated. Received: 16 July 1996 / Accepted: 14 November 1996  相似文献   

A canonical theory for short GPS baselines. Part IV: precision versus reliability     

P. J. G. Teunissen 《Journal of Geodesy》1997,71(9):513-525

This contribution is the last of four parts and deals with the link between baseline precision and ambiguity reliability. It is shown analytically how and to what extent the baseline-ambiguity correlation is related to the gain in baseline precision, to the volume of the ambiguity search space, and to the impact of potential integer ambiguity biases. Also, an ambiguity DOP measure is introduced together with its closed-form formulae for the three different single-baseline models. Received: 16 July 1996 / Accepted: 14 November 1996  相似文献   

GPS Ambiguity Resolution: Impact of Time Correlation,Cross-Correlation and Satellite Elevation Dependence     

Teunissen  P.J.G. 《Studia Geophysica et Geodaetica》1997,41(2):181-195

In this contribution we discuss the geometry-free GPS single baseline model and show how the least-squares ambiguities are affected by changes in the stochastic model. We particularly pay attention to the effect of time correlation, cross-correlation and satellite elevation dependence. We also differentiate between the impact on the location of the ambiguity search space and the impact on the size and shape of the search space. The analysis is carried out for both the model in which the ionospheric delays are assumed absent, and for the model in which they are assumed present. The former model is applicable to short baselines only.  相似文献   

PPP-RTK and inter-system biases: the ISB look-up table as a means to support multi-system PPP-RTK     

A. Khodabandeh  P. J. G. Teunissen 《Journal of Geodesy》2016,90(9):837-851

  相似文献   

First and second moments of non-linear least-squares estimators   总被引：1，自引：1，他引：1  

Peter J. G. Teunissen 《Journal of Geodesy》1989,63(3):253-262

The first two moments of non-linear and least-squares estimators are studied. Approximate expressions for the moments are derived and discussed. The results are compared with those ofJeudy [1988].  相似文献   

The Askervein Hill Project: Wind-tunnel simulations at three length scales   总被引：1，自引：1，他引：1  

H. W. Teunissen  M. E. Shokr  A. J. Bowen  C. J. Wood  D. W. R. Green 《Boundary-Layer Meteorology》1987,40(1-2):1-29

Wind-tunnel simulations of neutrally-stable atmospheric boundary-layer flow over an isolated, low hill (Askervein) have been carried out at three different length scales in two wind-tunnel facilities. The objectives of these simulations were to assess the reliability with which changes in mean wind and turbulence structure induced by the prototype hill on boundary-layer flow can be reproduced in the wind tunnel, and to determine the relative impact of certain modelling approaches (surface roughness, model scale, measurement techniques, etc.) on the quality of the simulations. The wind-tunnel results are compared with each other and with full-scale data and are shown in general to model the prototype flow very well. The effects of relaxing the criterion of aerodynamic roughness of the model surface were limited to certain regions in the lee of the hill and were linked to separation phenomena.  相似文献   

Integer estimation in the presence of biases     

P. J. G. Teunissen 《Journal of Geodesy》2001,75(7-8):399-407

 Carrier phase ambiguity resolution is the key to fast and high-precision GNSS (Global Navigation Satellite System) kinematic positioning. Critical in the application of ambiguity resolution is the quality of the computed integer ambiguities. Unsuccessful ambiguity resolution, when passed unnoticed, will too often lead to unacceptable errors in the positioning results. Very high success rates are therefore required for ambiguity resolution to be reliable. Biases which are unaccounted for will lower the success rate and thus increase the chance of unsuccessful ambiguity resolution. The performance of integer ambiguity estimation in the presence of such biases is studied. Particular attention is given to integer rounding, integer bootstrapping and integer least squares. Lower and upper bounds, as well as an exact and easy-to-compute formula for the bias-affected success rate, are presented. These results will enable the evaluation of the bias robustness of ambiguity resolution. Received: 28 September 2000 / Accepted: 29 March 2001  相似文献   

The least-squares ambiguity decorrelation adjustment: a method for fast GPS integer ambiguity estimation   总被引：71，自引：26，他引：71  

P. J. G. Teunissen 《Journal of Geodesy》1995,70(1-2):65-82

The GPS double difference carrier phase measurements are ambiguous by an unknown integer number of cycles. High precision relative GPS positioning based on short observational timespan data, is possible, when reliable estimates of the integer double difference ambiguities can be determined in an efficient manner. In this contribution a new method is introduced that enables very fast integer least-squares estimation of the ambiguities. The method makes use of an ambiguity transformation that allows one to reformulate the original ambiguity estimation problem as a new problem that is much easier to solve. The transformation aims at decorrelating the least-squares ambiguities and is based on an integer approximation of the conditional least-squares transformation. This least-squares ambiguity decorrelation approach, flattens the typical discontinuity in the GPS-spectrum of ambiguity conditional variances and returns new ambiguities that show a dramatic improvement in correlation and precision. As a result, the search for the transformed integer least-squares ambiguities can be performed in a highly efficient manner.  相似文献