Palaeomagnetism of the Tudor gabbro, Ontario: evidence for divergence between Grenvillia and interior Laurentia     

David J. Dunlop  Hironobu Hyodo  Todd Knight  Alan G. Steele 《Geophysical Journal International》1985,83(3):699-720

Summary. After thermal and alternating field (AF) cleaning, the characteristic high blocking temperature A component of natural remanent magnetization (NRM) of the Tudor gabbro of southern Ontario has a mean direction D = 326°, I =–46° ( k = 132, α₉₅= 4.8°, N = 8 sites). The corresponding palaeopole, 133°E, 12°N ( dp = 4°, dm = 6°), confirms the palaeopole 137°E, 17°N (α₉₅= 8.4°) reported earlier by Palmer & Carmichael, based on AF cleaning only. The A NRM has unblocking temperatures > 515–525°C which exceed the estimated 500°C peak temperature reached locally during ∼ 1050 Ma Grenvillian regional metamorphism. The A NRM therefore predates metamorphism and is probably a primary thermoremanence (TRM). The age of the Tudor NRM has previously been taken to be about 675 Ma, but recent ⁴⁰Ar/³⁹Ar dating by Baksi has shown that this is the time of post-metamorphic cooling to 200–250°C. Hornblendes record initial cooling of the intrusion to 590±20°C at 1110 Ma and this is the best estimate of the age of the A remanence. Successful Thellier-type palaeointensity determinations on 11 Tudor samples confirm that the A NRM is a TRM and indicate a palaeofield at this time of 18–27 μT, about 50–70 per cent of the present field intensity at 27° magnetic latitude. The anomalous Tudor A palaeopole, which lies well to the west of both 1000–800 Ma Grenvillian palaeopoles and 1100–1050 Ma poles from Interior Laurentia, is interpreted as recording divergence between Grenvillia and Interior Laurentia just before the Grenvillian orogeny, rather than a post-metamorphic extension of the apparent polar wander path as previously assumed.  相似文献   

The spectra and light curves of two gamma-ray bursts     

F. K. Knight  J. L. Matteson  L. E. Peterson 《Astrophysics and Space Science》1981,75(1):21-30

During the last half of 1977 the UCSD/MIT Hard X-Ray and Low Energy Gamma-Ray Experiment of HEAO-1 observed two of the three gamma-ray bursts detected by at least three satellites. The first of these bursts (20 October, 1977) had a fluence of (3.1±0.5)×10^–5 erg cm^–2 integrated over the energy range 0.135–2.05 MeV and over its duration of 38.7 s, placing it among the largest bursts observed. The second (10 November, 1977) had a fluence of (2.1±0.8)×10^–5 erg cm^–2 integrated over the energy range 0.125–3 MeV and over its duration of 2.8 s. The light curves of both bursts exhibit time fluctuations down to the limiting time resolution of the detectors (0.1 s). The spectrum of the 20 October, 1977 burst can be fitted with a power law (index –1.93±0.16), which is harder than other reported gamma-ray burst spectral fits. This burst was detected up to 2.05 MeV, and approximately half of its energy was emitted at photon energies above 0.5 MeV. The spectrum of the 10 November, 1977 burst is softer (index –2.4±0.7) and is similar to the spectrum of the 27 April, 1972 burst.Paper presented at the Symposium on Cosmic Gamma-Ray Bursts held at Toulouse, France, 26–29 November, 1979.  相似文献   

Compositional variation in Hg-bearing sphalerite from the polymetallic Eskay Creek deposit, British Columbia, Canada   总被引：1，自引：0，他引：1  

Tassos A. Grammatikopoulos  Oleg Valeyev  Tina Roth 《Chemie der Erde / Geochemistry》2006,66(4):307-314

The Eskay Creek, British Columbia, Canada, is a polymetallic, gold- and silver-rich, volcanic-hosted, massive sulfide deposit. The ore in the deposit is divided into subzones distinguished by mineralogy, texture, grade and metallurgical characteristics. This study presents the results of a mineralogical examination of three composite field samples, with emphasis on the chemistry of sphalerite. Sphalerite is associated with variable amounts of Hg-tetrahedrite and cinnabar, and an array of sulfides, sulphosalts and non-opaque minerals. Electron micro probe analyses of sphalerite in the three composite samples reveal wide variations in compositions. The Hg content in sphalerite in the three samples varies between 0.08 and 16.35 wt%, whereas the Fe content ranges from 0.33 to 2.29 wt%. The chemical formula of the sphalerite shows the compositional range (Zn_0.89–0.98Hg_0.01–0.09.Fe_0.005–0.02)S. Sphalerite exhibits an almost perfect substitution of Hg and Zn, as shown by the negative covariance between them. Sphalerite with the highest Hg contents tends to have the lowest Fe concentrations. The highest Hg contents in sphalerite are recorded in the samples with the highest bulk Hg concentrations and with the highest cinnabar contents.

The compositional variations of sphalerite are important because they can be used in mapping ore forming fluids and indicate possible temporal variations. Second, determination of the compositional variation of the sphalerite in the mine has metallurgical implications because the mineral is an important Zn source. The mineralogical data indicate that non-physical processes (e.g. pyrometallurgy) must be used to separate Hg from Zn concentrates, with direct environmental implications, that is, release of metals, such as Hg, into the environment during mining and processing.  相似文献   

Thermal expansion and crystal structure of FeSi between 4 and 1173 K determined by time-of-flight neutron powder diffraction     

L. Vočadlo  K. S. Knight  G. D. Price  I. G. Wood 《Physics and Chemistry of Minerals》2002,29(2):132-139

The thermal expansion and crystal structure of FeSi has been determined by neutron powder diffraction between 4 and 1173?K. No evidence was seen of any structural or magnetic transitions at low temperatures. The average volumetric thermal expansion coefficient above room temperature was found to be 4.85(5)?×?10^?5?K^?1. The cell volume was fitted over the complete temperature range using Grüneisen approximations to the zero pressure equation of state, with the internal energy calculated via a Debye model; a Grüneisen second-order approximation gave the following parameters: θ_D=445(11)?K, V ₀=89.596(8)?ų, K ₀′=4.4(4) and γ′=2.33(3), where θ_D is the Debye temperature, V ₀ is V at T=0?K, K ₀′ is the first derivative with respect to pressure of the incompressibility and γ′ is a Grüneisen parameter. The thermodynamic Grüneisen parameter, γ_th, has been calculated from experimental data in the range 4–400?K. The crystal structure was found to be almost invariant with temperature. The thermal vibrations of the Fe atoms are almost isotropic at all temperatures; those of the Si atoms become more anisotropic as the temperature increases.  相似文献   

Drought in Bulgaria and atmospheric synoptic conditions over Europe   总被引：1，自引：0，他引：1  

Liem Tran  C. Gregory Knight  Victoria Wesner 《GeoJournal》2002,57(3):149-157

Drought in Bulgaria is analyzed from the multiple viewpoints of statistical occurrence, spatial patterns, and synoptic conditions. A new index of drought, the SD (spatial-dryness) index, characterizes drought by both intensity and spatial extent. The occurrence of the SD index is analyzed using global gridded data sets. Examination of transitional probabilities of multiple months and years with drought occurrence suggests persistence is sufficiently frequent to be important for climate-related environmental planning. Finally, it is shown that specific seasonal synoptic patterns are associated with wet and dry conditions in Bulgaria. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Recent ventifact development on the central Oregon coast,western USA     

Jasper Knight  Helene Burningham 《地球表面变化过程与地形》2003,28(1):87-98

The unusual location of ventifacts, on a boulder‐built jetty at the mouth of the Siuslaw River, Oregon coast, western USA, allows ventifact age and wind abrasion rates to be estimated with some precision. The jetty was built mainly between 1892–1901 and extended throughout the twentieth century. Consideration of historical shoreline position and the history of jetty construction and repair suggests the ventifacts have formed since about 1930. Morphologically the ventifacts are aligned south‐to‐north reflecting winter winds and sediment transport from the adjacent beach. Wind‐parallel grooves and ridges with sharp, sinuous crests are developed on inclined boulder surfaces on top of the jetty and reflect suspended sand transport in wind vortices. Deeply pitted surfaces on steep boulder surfaces nearest the beach reflect impact by saltating sand grains. Based on present wind regimes (1992–2000) from three regional weather stations, southerly winds above the sand transport threshold occur for 21·9–29·6 per cent of the time. Based on estimated depth of loss from boulder surfaces, wind abrasion rates are calculated to be on the order of 0·24–1·63 mm a^?1. This is the first well‐constrained field estimate of ventifact age and ventifaction rate from a modern coastal environment. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Lower crustal melting and the role of open-system processes in the genesis of syn-orogenic quartz diorite–granite–leucogranite associations: constraints from Sr–Nd–O isotopes from the Bandombaai Complex, Namibia     

Tina van de Flierdt  Stephan Hoernes  Stefan Jung  Peter Masberg  Edgar Hoffer  Urs Schaltegger  Hans Friedrichsen 《Lithos》2003,67(3-4):205-226

The Bandombaai Complex (southern Kaoko Belt, Namibia) consists of three main intrusive rock types including metaluminous hornblende- and sphene-bearing quartz diorites, allanite-bearing granodiorites and granites, and peraluminous garnet- and muscovite-bearing leucogranites. Intrusion of the quartz diorites is constrained by a U–Pb zircon age of 540±3 Ma.

Quartz diorites, granodiorites and granites display heterogeneous initial Nd- and O isotope compositions (_{Nd (540 Ma)}=−6.3 to −19.8; δ¹⁸O=9.0–11.6‰) but rather low and uniform initial Sr isotope compositions (⁸⁷Sr/⁸⁶Sr_initial=0.70794–0.70982). Two leucogranites and one aplite have higher initial ⁸⁷Sr/⁸⁶Sr ratios (0.70828–0.71559), but similar initial _Nd (−11.9 to −15.8) and oxygen isotope values (10.5–12.9‰). The geochemical and isotopic characteristics of the Bandombaai Complex are distinct from other granitoids of the Kaoko Belt and the Central Zone of the Damara orogen. Our study suggests that the quartz diorites of the Bandombaai Complex are generated by melting of heterogeneous mafic lower crust. Based on a comparison with results from amphibolite-dehydration melting experiments, a lower crustal garnet- and amphibole-bearing metabasalt, probably enriched in K₂O, is a likely source rock for the quartz diorites. The granodiorites/granites show low Rb/Sr (<0.6) ratios and are probably generated by partial melting of meta-igneous (intermediate) lower crustal sources by amphibole-dehydration melting. Most of the leucogranites display higher Rb/Sr ratios (>1) and are most likely generated by biotite-dehydration melting of heterogeneous felsic lower crust. All segments of the lower crust underwent partial melting during the Pan-African orogeny at a time (540 Ma) when the middle crust of the central Damara orogen also underwent high T, medium P regional metamorphism and melting. Geochemical and isotope data from the Bandombaai Complex suggest that the Pan-African orogeny in this part of the orogen was not a major crust-forming episode. Instead, even the most primitive rock types of the region, the quartz diorites, represent recycled lower crustal material.  相似文献   

Adsorption of copper (II) on mesoporous silica: the effect of nano-scale confinement     

Andrew W. Knight  Austen B. Tigges  Anastasia G. Ilgen 《Geochemical transactions》2018,19(1):13

Nano-scale spatial confinement can alter chemistry at mineral–water interfaces. These nano-scale confinement effects can lead to anomalous fate and transport behavior of aqueous metal species. When a fluid resides in a nanoporous environments (pore size under 100 nm), the observed density, surface tension, and dielectric constant diverge from those measured in the bulk. To evaluate the impact of nano-scale confinement on the adsorption of copper (Cu²⁺), we performed batch adsorption studies using mesoporous silica. Mesoporous silica with the narrow distribution of pore diameters (SBA-15; 8, 6, and 4 nm pore diameters) was chosen since the silanol functional groups are typical to surface environments. Batch adsorption isotherms were fit with adsorption models (Langmuir, Freundlich, and Dubinin–Radushkevich) and adsorption kinetic data were fit to a pseudo-first-order reaction model. We found that with decreasing pore size, the maximum surface area-normalized uptake of Cu²⁺ increased. The pseudo-first-order kinetic model demonstrates that the adsorption is faster as the pore size decreases from 8 to 4 nm. We attribute these effects to the deviations in fundamental water properties as pore diameter decreases. In particular, these effects are most notable in SBA-15 with a 4-nm pore where the changes in water properties may be responsible for the enhanced Cu mobility, and therefore, faster Cu adsorption kinetics.  相似文献   

Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration     

Tina Sanders  Andreas Schöl  Kirstin Dähnke 《Estuaries and Coasts》2018,41(1):128-138

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.  相似文献   

The Coolgardie Goldfied,Western Australia: district-scale controls on an Archaean gold camp in an amphibolite facies terrane     

J. T. Knight  D. I. Groves  J. R. Ridley 《Mineralium Deposita》1993,28(6):436-456

Archaean lode gold deposits in the Coolgardie Goldfield, Western Australia, occur in mafic and ultramafic rocks which have been metamorphosed to the amphibolite facies. Mineralisation was broadly synchronous with peak metamorphism, the main phase of granitoid emplacement, and regional deformation. Several different structural styles are represented by the deposits of the Coolgardie Goldfield. Mineralisation occurs along sheared felsic porphyry-ultramafic rock contacts, in gabbro-hosted quartz-vein sets, in fault-bounded quartzvein sets, and in laminated quartz reefs sited in brittleductile shear zones. The structures hosting mineralisation formed in response to a progressive deformation event, related to granitoid emplacement in an east-west compressional far-field stress régime, but with local heterogeneous stress orientations. This occurred after an earlier period of thrust-stacking, with probable north-south directed tectonic transport. Two contrasting styles of goldrelated wallrock alteration are associated with the auriferous lodes of the Coolgardie Goldfield. A high-temperature assemblage (formation temperature >500°C), characterised by the proximal alteration assemblage garnet+ hornblende + plagioclase + pyrrhotite, contrasts with a medium-temperature assemblage (formation temperature <500°C), consisting of calcic amphibole + biotite + plagioclase + calcite + arsenopyrite + pyrrhotite. The distribution of the two styles of gold-related alteration is controlled by distance from voluminous syntectonic granitoids located to the west of the Coolgardie Goldfield, with the high-temperature style of alteration more proximal to the granitoid-greenstone contact than the medium-temperature style. The occurrence of gold deposits that formed under amphibolite facies conditions throughout the Coolgardie Goldfield supports a crustal continuum model for Archaean lode-gold deposits, which proposes that gold is deposited in metamorphic environments that range from the sub-greenschist to granulite facies. In addition, the data from Coolgardie suggest that syntectonic, synmineralisation granitic plutons may play a significant role in controlling the style of gold associated wallrock-alteration at deep crustal levels.  相似文献