Rutile R632 – A New Natural Reference Material for U‐Pb and Zr Determination          下载免费PDF全文

Emelie Axelsson  Jonas Pape  Jasper Berndt  Fernando Corfu  Klaus Mezger  Michael M. Raith 《Geostandards and Geoanalytical Research》2018,42(3):319-338

A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g^?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g^?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations.  相似文献   

Adsorption of copper (II) on mesoporous silica: the effect of nano-scale confinement     

Andrew W. Knight  Austen B. Tigges  Anastasia G. Ilgen 《Geochemical transactions》2018,19(1):13

Nano-scale spatial confinement can alter chemistry at mineral–water interfaces. These nano-scale confinement effects can lead to anomalous fate and transport behavior of aqueous metal species. When a fluid resides in a nanoporous environments (pore size under 100 nm), the observed density, surface tension, and dielectric constant diverge from those measured in the bulk. To evaluate the impact of nano-scale confinement on the adsorption of copper (Cu²⁺), we performed batch adsorption studies using mesoporous silica. Mesoporous silica with the narrow distribution of pore diameters (SBA-15; 8, 6, and 4 nm pore diameters) was chosen since the silanol functional groups are typical to surface environments. Batch adsorption isotherms were fit with adsorption models (Langmuir, Freundlich, and Dubinin–Radushkevich) and adsorption kinetic data were fit to a pseudo-first-order reaction model. We found that with decreasing pore size, the maximum surface area-normalized uptake of Cu²⁺ increased. The pseudo-first-order kinetic model demonstrates that the adsorption is faster as the pore size decreases from 8 to 4 nm. We attribute these effects to the deviations in fundamental water properties as pore diameter decreases. In particular, these effects are most notable in SBA-15 with a 4-nm pore where the changes in water properties may be responsible for the enhanced Cu mobility, and therefore, faster Cu adsorption kinetics.  相似文献   

Evaluating geological heritage: correspondence on Ruban, D.A. ‘Quantification of geodiversity and its loss’ (PGA, 2010, 121(3): 326-333)     

Jasper Knight 《Proceedings of the Geologists' Association. Geologists' Association》2011,122(3):508-510

This article comments on the recent paper in this journal by Ruban (2010) which presented a simple quantitative scheme for the calculation of landscape geodiversity and its application to evaluating geodiversity between different locations. This comment article highlights some conceptual and methodological issues in the set-up and application of Ruban's scheme, and suggests that geodiversity as a measure can only be meaningful if it is set within a wider context of landscape and geological conservation and management. Some examples of conservation strategies in Great Britain are described in order to illustrate this wider context.  相似文献   

Response to comment by Keith Beven on “Equifinality of formal (DREAM) and informal (GLUE) Bayesian approaches in hydrologic modeling?”     

Jasper A. Vrugt  Cajo J. F. ter Braak  Hoshin V. Gupta  Bruce A. Robinson 《Stochastic Environmental Research and Risk Assessment (SERRA)》2009,23(7):1061-1062

In recent years, a strong debate has emerged in the hydrologic literature regarding what constitutes an appropriate framework for uncertainty estimation. Particularly, there is strong disagreement whether an uncertainty framework should have its roots within a proper statistical (Bayesian) context, or whether such a framework should be based on a different philosophy and implement informal measures and weaker inference to summarize parameter and predictive distributions. In this paper, we compare a formal Bayesian approach using Markov Chain Monte Carlo (MCMC) with generalized likelihood uncertainty estimation (GLUE) for assessing uncertainty in conceptual watershed modeling. Our formal Bayesian approach is implemented using the recently developed differential evolution adaptive metropolis (DREAM) MCMC scheme with a likelihood function that explicitly considers model structural, input and parameter uncertainty. Our results demonstrate that DREAM and GLUE can generate very similar estimates of total streamflow uncertainty. This suggests that formal and informal Bayesian approaches have more common ground than the hydrologic literature and ongoing debate might suggest. The main advantage of formal approaches is, however, that they attempt to disentangle the effect of forcing, parameter and model structural error on total predictive uncertainty. This is key to improving hydrologic theory and to better understand and predict the flow of water through catchments.  相似文献   

Using a groundwater quality negotiation support system to change land-use management near a drinking-water abstraction in the Netherlands     

Cors van den Brink  Willem Jan Zaadnoordijk  Bas van der Grift  Peter C. de Ruiter  Jasper Griffioen 《Journal of Hydrology》2008,350(3-4):339-356

A negotiation support system (NSS) was developed to solve groundwater conflicts that arose during land-use management. It was set up in cooperation with the stakeholders involved to provide information on the impact of land use, e.g., agriculture, nature (forested areas), recreation, and urban areas, on the quality of both infiltrating and abstracted groundwater. This NSS combined simulation programs that calculate (1) the concentrations of nitrate in shallow groundwater for each land-use area and (2) the transport of nitrate in the groundwater-saturated zone. The user interface of the NSS enabled scenario analyses. The NSS was validated at a drinking-water abstraction near Holten (the Netherlands) using a spatial planning process aimed at sustainable land-use and groundwater-resource management. Two land-use scenarios were considered: a base scenario reflecting the autonomous development and an adapted land-use scenario. The calculated results for shallow groundwater provided an explicit spatial overview of the impact of historical land use and N application on the quality of abstracted groundwater as well as insight into the impact of changes in land use and N application. Visualization of the conflicting interests of agriculture and the drinking-water abstraction helped all stakeholders accept the necessary changes in land use identified by the adapted land-use scenario of the NSS. These changes were included in the preferred land-use management option in the regional planning process, which has since been formalized. The NSS provided system insight, scoping analyses, and education, in addition to generating quantitative information on the impact of land-use functions on groundwater quality.  相似文献   

Generalized likelihood uncertainty estimation (GLUE) using adaptive Markov Chain Monte Carlo sampling     

Roberta-Serena Blasone  Jasper A. Vrugt  Henrik Madsen  Dan Rosbjerg  Bruce A. Robinson  George A. Zyvoloski 《Advances in water resources》2008

In the last few decades hydrologists have made tremendous progress in using dynamic simulation models for the analysis and understanding of hydrologic systems. However, predictions with these models are often deterministic and as such they focus on the most probable forecast, without an explicit estimate of the associated uncertainty. This uncertainty arises from incomplete process representation, uncertainty in initial conditions, input, output and parameter error. The generalized likelihood uncertainty estimation (GLUE) framework was one of the first attempts to represent prediction uncertainty within the context of Monte Carlo (MC) analysis coupled with Bayesian estimation and propagation of uncertainty. Because of its flexibility, ease of implementation and its suitability for parallel implementation on distributed computer systems, the GLUE method has been used in a wide variety of applications. However, the MC based sampling strategy of the prior parameter space typically utilized in GLUE is not particularly efficient in finding behavioral simulations. This becomes especially problematic for high-dimensional parameter estimation problems, and in the case of complex simulation models that require significant computational time to run and produce the desired output. In this paper we improve the computational efficiency of GLUE by sampling the prior parameter space using an adaptive Markov Chain Monte Carlo scheme (the Shuffled Complex Evolution Metropolis (SCEM-UA) algorithm). Moreover, we propose an alternative strategy to determine the value of the cutoff threshold based on the appropriate coverage of the resulting uncertainty bounds. We demonstrate the superiority of this revised GLUE method with three different conceptual watershed models of increasing complexity, using both synthetic and real-world streamflow data from two catchments with different hydrologic regimes.  相似文献   

Subglacial processes from drumlins in Clew Bay,western Ireland          下载免费PDF全文

Jasper Knight 《地球表面变化过程与地形》2016,41(2):277-288

Interpretation of subglacial processes and environments can be usefully informed by the stratigraphy and structures of sediments preserved within drumlins, and the down‐ice variability of these sediments. Drumlins in Clew Bay, western Ireland, were formed by westward late Pleistocene ice flow onto the Atlantic shelf, but the depositional processes and environments of these sediments remain uncertain. This study describes and interprets the drumlin stratigraphy and sediment properties and structures from two drumlins on the south side of Clew Bay. Drumlin sediments are dominated by massive to stratified diamicton deposited subglacially by deformation of flows of varying rheology. Folds, shears and clastic dikes within the sediments suggest active subglacial water flow related to variations in ice flow and ice‐bed coupling. The distal ends of the drumlins are dominated by stratified diamicton and gravel units with sandy interbeds. These sediments reflect deposition in a leeside subglacial cavity formed coevally with bedform development. A model is proposed that can account for sediment stratigraphic patterns and drumlin formation. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

NMR Logging to Estimate Hydraulic Conductivity in Unconsolidated Aquifers          下载免费PDF全文

Rosemary Knight  David O. Walsh  James J. Butler Jr.  Elliot Grunewald  Gaisheng Liu  Andrew D. Parsekian  Edward C. Reboulet  Steve Knobbe  Mercer Barrows 《Ground water》2016,54(1):104-114

Nuclear magnetic resonance (NMR) logging provides a new means of estimating the hydraulic conductivity (K) of unconsolidated aquifers. The estimation of K from the measured NMR parameters can be performed using the Schlumberger‐Doll Research (SDR) equation, which is based on the Kozeny–Carman equation and initially developed for obtaining permeability from NMR logging in petroleum reservoirs. The SDR equation includes empirically determined constants. Decades of research for petroleum applications have resulted in standard values for these constants that can provide accurate estimates of permeability in consolidated formations. The question we asked: Can standard values for the constants be defined for hydrogeologic applications that would yield accurate estimates of K in unconsolidated aquifers? Working at 10 locations at three field sites in Kansas and Washington, USA, we acquired NMR and K data using direct‐push methods over a 10‐ to 20‐m depth interval in the shallow subsurface. Analysis of pairs of NMR and K data revealed that we could dramatically improve K estimates by replacing the standard petroleum constants with new constants, optimal for estimating K in the unconsolidated materials at the field sites. Most significant was the finding that there was little change in the SDR constants between sites. This suggests that we can define a new set of constants that can be used to obtain high resolution, cost‐effective estimates of K from NMR logging in unconsolidated aquifers. This significant result has the potential to change dramatically the approach to determining K for hydrogeologic applications.  相似文献   

Petroleum geoscience in Norden - exploration, production and organization     

Anthony M. Spencer Per Ivar Briskeby Lone Dyrmose Christensen Rune Foyn Marie KjФlleberg Erling Kvadsheim Ian Knight Morten Rye-Larsen John Williams 《《幕》》2008,31(1):115-124

Offshore exploration in Norway and Denmark-in the North Sea, the Norwegian Sea and the Barents Sea-has involved drilling about 850 wildcat wells, resulting in about 300 oil and gas finds, of which 84 are fields with production. The recoverable resources of all these finds total about 65 billion barrels of oil equivalent. Almost all these hydrocarbons come from a Jurassic source and the main reservoirs and traps are Jurassic sandstones in fault blocks and Paleocene sandstones or Cretaceous chalks in gentle domes. The article describes four major fields-Ekofisk, Gullfaks, Ormen Lange and SnФhvitto illustrate some of the many challenges in developing and producing the hydrocarbons.
Elsewhere in Norden, there has been much less exploration. Drilling results have mostly been negative in mainland Sweden, onshore Denmark, onshore Svalbard and on- and offshore West Greenland. Minor oil finds have been made in Palaeozoic rocks in the Baltic Sea. The first wells have recently been drilled off the Faroe Islands, resulting in one discovery. No drilling has taken place on- or offshore East Greenland.
As a result of the hydrocarbon activities in Norway and Denmark, petroleum geoscience there has flourished, with 2000 geoscientists currently employed in the industry, many technical innovations made, a wealth of publically available information and a great increase in the understanding of the geology.  相似文献   

Advancing process‐based watershed hydrological research using near‐surface geophysics: a vision for,and review of,electrical and magnetic geophysical methods     

D. A. Robinson  A. Binley  N. Crook  F. D. Day‐Lewis  T. P. A. Ferré  V. J. S. Grauch  R. Knight  M. Knoll  V. Lakshmi  R. Miller  J. Nyquist  L. Pellerin  K. Singha  L. Slater 《水文研究》2008,22(18):3604-3635

We want to develop a dialogue between geophysicists and hydrologists interested in synergistically advancing process based watershed research. We identify recent advances in geophysical instrumentation, and provide a vision for the use of electrical and magnetic geophysical instrumentation in watershed scale hydrology. The focus of the paper is to identify instrumentation that could significantly advance this vision for geophysics and hydrology during the next 3–5 years. We acknowledge that this is one of a number of possible ways forward and seek only to offer a relatively narrow and achievable vision. The vision focuses on the measurement of geological structure and identification of flow paths using electrical and magnetic methods. The paper identifies instruments, provides examples of their use, and describes how synergy between measurement and modelling could be achieved. Of specific interest are the airborne systems that can cover large areas and are appropriate for watershed studies. Although airborne geophysics has been around for some time, only in the last few years have systems designed exclusively for hydrological applications begun to emerge. These systems, such as airborne electromagnetic (EM) and transient electromagnetic (TEM), could revolutionize hydrogeological interpretations. Our vision centers on developing nested and cross scale electrical and magnetic measurements that can be used to construct a three‐dimensional (3D) electrical or magnetic model of the subsurface in watersheds. The methodological framework assumes a ‘top down’ approach using airborne methods to identify the large scale, dominant architecture of the subsurface. We recognize that the integration of geophysical measurement methods, and data, into watershed process characterization and modelling can only be achieved through dialogue. Especially, through the development of partnerships between geophysicists and hydrologists, partnerships that explore how the application of geophysics can answer critical hydrological science questions, and conversely provide an understanding of the limitations of geophysical measurements and interpretation. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献