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1.
Weathering of Hitura (W Finland) nickel sulphide mine tailings and release of heavy metals into pore water was studied with mineralogical (optical and electron microscopy, X-ray diffraction) and geochemical methods (selective extractions). Tailings were composed largely of serpentine, micas and amphiboles with only minor carbonates and sulphides. Sulphides, especially pyrrhotite, have oxidized intensively in the shallow tailings in 10–15 years, but a majority of the tailings have remained unchanged. Oxidation has resulted in depletion of carbonates, slightly decreased pH, and heavy metal (Ni, Zn) release in pore water as well as in the precipitation of secondary Fe precipitates. Nevertheless, in the middle of the tailings area, where the oxidation front moves primarily downward, released heavy metals have been adsorbed and immobilized with these precipitates deeper in the oxidation zone. In contrast to what was seen in pore water pH, but in accordance with static tests of the previous studies, the neutralisation potential ratio (NPR) calculated based on the mineralogical composition and the total sulphur content suggested that tailings are ‘not potentially acid mine drainage (AMD) generating’. However, the calculated buffering capacity of the tailings resulted largely from the abundant serpentine because of the low carbonate content. Despite its slow weathering rate, serpentine may buffer the acidity to some extent through ion exchange processes in fine ground tailings. Nevertheless, in practice, acid production capacity of the tailings depends primarily on the balance between Ca–Mg carbonates and iron sulphides. NPR calculation based on carbonate and sulphur contents suggested, that the Hitura tailings are ‘likely AMD generating’. The study shows that sulphide oxidation can be significant in mobilisation of heavy metals even in apparently non-acid producing, low sulphide tailings. Therefore, prevention of oxygen diffusion into tailings is also essential in this type of sulphide tailings. 相似文献
2.
Markku Heikkinen 《Journal of Geodesy》1979,53(3):239-245
The Honkasalo term is discussed and the author arrives at the conclusion that its application to gravimetric observations
is harmful and should be avoided. 相似文献
3.
Jussi Heikkinen 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(3):267-274
This paper deals with a novel imaging arrangement for special modeling purpose. The method introduced here will take care of the geometrical consistence of photography. It is based on image ray bundles and is meant for conditions where imaging is accomplished inside the object space (e.g. in case of interior model reconstruction). Imaging is designed to be constrained in terms of camera position and orientation and to consist of two image sequences. The image orientations will be resolved by use of LSQ-estimation in heavily overdetermined conditions. The benefits of overdetermination are discussed and the accuracy assessment in a real experiment is published. The accuracy assessment is accomplished with help of exterior reference and stochastic error propagation. 相似文献
4.
Shayan Nikoohemat Abdoulaye A. Diakit Ville Lehtola Sisi Zlatanova George Vosselman 《Transactions in GIS》2021,25(1):189-212
Indoor 3D models are digital representations of building interiors reconstructed from scanned data acquired by laser scanners, digital depth (RGBD) cameras, and CAD drawings. Consequently, there is noise in the source data and a notable variety in the methods used to treat the noise and to process these data into reconstructed models. Alas, the correctness of these reconstructions and thus their suitability for a given application are uncertain. There is a lack of a robust base logic that would allow for controlling the consistency of these (automatically) generated models. Fortunately, correctness criteria are well‐defined through existing international standards. Hence, we propose a conceptual framework based on formal grammars to check the semantic, geometric, and topological consistency of a reconstructed 3D model. The proposed method proceeds in three steps to validate the model: (1) correctness checking of individual components; (2) consistency verification of instances’ interactions; and (3) model consistency check for targeted applications. Our method identifies the components in the model that violate the given rules derived from the current standards and expert knowledge. Ultimately, we propose a quantified formulation of our method that may be straightforwardly integrated into industrial‐level model checkers. The approach is independent of level of details and reconstruction method. 相似文献
5.
An enzyme assay was developed for studies on peroxidase activities in humic lake water. 3,4-Dimethoxybenzyl alcohol (veratryl alcohol, VeraOH) was used as tracer substrate, and peroxidase (EC 1.11.1.7) activity was measured by high-performance liquid chromatography. The chemical stability of VeraOH and its application as peroxidase substrate was tested under light and dark conditions, different hydrogen peroxide (H2O2) concentrations and humic matter contents. VeraOH was stable under low UV radiation at in situ conditions in lake water (<0.010...0.25 kJ m–2 d–1), laboratory conditions (<0.05...0.30 kJ m–2 d–1), and low (1...100 μM) H2O2 concentrations. However, peroxides oxidized VeraOH above 1...10 mM H2O2 concentration in sterile Millipore-Q and humic lake water. Dark incubations showed little VeraOH oxidation products. The developed peroxidase assay was tested in the growth medium of Phanerochaete chrysosporium and a bacteria isolate (P.M.D. 20.4.3.1) from mesohumic lake Pääjärvi. Peroxidase activities were also measured in natural microbial communities under standard laboratory and under in situ conditions in humic lake water. Incubation times of about 5 to 12 days were usually needed to record significant (P < 0.05) peroxidase activities, in lake waters. In situ peroxidase activities varied in pelagial surface water (0...0.5 m) on a seasonal scale between 74 nmol L–1 h–1 and 273 nmol L–1 (mean: 176 nmol L–1 h–1) and within the water column between 110 nmol L–1 h–1 and 800 nmol L–1 h–1 (mean: 500 nmol L–1 h–1) in polyhumic lake Mekkojärvi. 相似文献
6.
Redistribution of potentially harmful metals and As was studied based on selective extractions in two active sulphide mine tailings impoundments in Finland. The Hitura tailings area contains residue from Ni ore processing, while the Luikonlahti site includes tailings from the processing of Cu–Co–Zn–Ni and talc ores. To characterize the element solid-phase speciation with respect to sulphide oxidation intensity and the water saturation level of the tailings, drill cores were collected from border zones and mid-impoundment locations. The mobility and solid-phase fractionation of Ni, Cu, Co, Zn, Cr, Fe, Ca, Al, As, and S were analysed using a 5-step non-sequential (parallel) selective extraction procedure. The results indicated that metal redistribution and sulphide oxidation intensity were largely controlled by the disposal history and strategy of the tailings (sorting, exposure of sulphides due to delayed burial), impoundment structure and water table, and reactivity of the tailings. Metal redistribution suggested sulphide weathering in the tailings surface, but also in unsaturated proximal areas beside the earthen dams, and in water-saturated bottom layers, where O2-rich infiltration is possible. Sulphide oxidation released trace metals from sulphide minerals at both locations. In the Hitura tailings, with sufficient buffering capacity, pH remained neutral and the mobilized metals were retained by secondary Fe precipitates deeper in the oxidized zone. In contrast, sulphide oxidation-induced acidity and rise in the water table after oxidation apparently remobilized the previously retained metals in Luikonlahti. In general, continuous disposal of tailings decreased the sulphide oxidation intensity in active tailings, unless there was a delay in burial and the reactive tailings were unsaturated after deposition. 相似文献
7.
Abstract A class of exact solutions to the steady, two-dimensional magnetohydrodynamic equations ina cylindrical geometry is presented. These may model both closed and open magnetic structures found in the solar atmosphere. For closed structures, it is found that increasing the flow speed causes the summit of the arcade of closed magnetic fieldlines to rise. Parameter ranges also exist where the solution has regions of open and closed field, and so the solutions may be relevant for modelling flows in solar magnetic structures such as coronal streamers, X-ray bright points coronal plumes and coronal holes. 相似文献
8.
Heather Schijns Suvi Heinonen Douglas R. Schmitt Pekka Heikkinen Ilmo T. Kukkonen 《Geophysical Prospecting》2009,57(6):997-1008
A traveltime inversion technique is applied to model the upper ∼40 m of the subsurface of a glaciated shield rock area in order to calculate static corrections for a multi-azimuth multi-depth walk-away vertical seismic profile and a surface seismic reflection profile. First break information from a seismic refraction survey is used in conjunction with a ray-tracing program and an iterative damped least-squares inversion algorithm to create a two-dimensional model of the subsurface. The layout of the seismic survey required crooked seismic lines and substantial gaps in the source and receiver coverage to be accounted for. Additionally, there is substantial topographical variation and a complex geology consisting of glaciofluvial sediment and glacial till overlying a crystalline bedrock. The resolution and reliability of the models is measured through a parameter perturbation technique, normalized χ2 values, root means square traveltime residuals and comparison to known geology. 相似文献
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10.
Velocities of upper-mantle P waves (Pn) generated by large shallow earthquakes in the Japan area have been studied by the time-term method in three areas of the Japanese islands. Data reported from routinely recording seismic stations, grouped to act as elongated arrays, were used. The velocities observed correspond to the P-wave velocity in the top layer of the mantle. For a region in southwestern Japan not spanned by active volcanoes the value obtained was 8.0 km/s, while for central Japan and on northern Honshu Island the corresponding values were as low as 7.6–7.7 km/s. After allowance for the influence of systematic earthquake mislocation, the probable error of the measurements is estimated not to exceed 0.1 km/s. The differences in P-wave velocity are attributable to the regional variation of subcrustal temperature in Japan reported by Uyeda and Horai, with high temperatures and low velocities in the volcanic zone.The time terms tend to be larger on the Japan Sea side than on the Pacific side of the Japanese islands. We suggest that this is due to an increase in P velocity in the mantle towards the Pacific, perpendicular to our profiles of measurement. 相似文献