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1.
S. Solberg T. Krognes F. Stordal OØ Hov H. J. Beine D. A. Jaffe K. C. Clemitshaw S. A. Penkett 《Journal of Atmospheric Chemistry》1997,28(1-3):209-225
Simultaneousindependent measurements of NOy and NOx(NOx= NO + NO2) by high-sensitivitychemiluminescence systems and of PAN (peroxyacetylnitrate) and PPN (peroxypropionyl nitrate) by GC-ECDwere made at Spitsbergen in the Norwegian Arcticduring the first half year of 1994. The average mixingratio of the sum of PAN and PPN (denoted PANs)increased from around 150 pptv in early winter to amaximum of around 500 pptv in late March, whereasepisodic peak values reached 800 pptv. This occurredsimultaneously with a maximum in ozone which increasedto 45–50 ppbv in March–April. The average NOxmixing ratio was 27 pptv and did not show any cyclethrough the period. The NOy mixing ratio showeda maximum in late March, while the difference betweenNOy and PAN decreased during spring. This is anindication of the dominance of PAN in the NOybudget in the Arctic, but possible changes in theefficiency of the NOy converter could alsocontribute to this. Although most PAN in theArctic is believed to be due to long range transport,the observations indicate local loss and formationrates of up to 1–2 pptv h-1 in April–May.Measurements of carbonyl compounds suggest thatacetaldehyde was the dominant, local precursor ofPAN.Now at 1. 相似文献
2.
Sverre Solberg Norbert Schmidbauer Arne Semb Frode Stordal Øystein Hov 《Journal of Atmospheric Chemistry》1996,23(3):301-332
Several years of measurements of ozone, hydrocarbons, sulphate and meteorological parameters from Spitsbergen in the Norwegian Arctic are presented. Most of the measurements were taken on the Zeppelin Mountain at an altitude of 474 m a.s.l. The focus is the episodes of ozone depletion in the lower troposphere in spring, which are studied in a climatological way. Episodes of very low ozone concentrations are a common feature on the Zeppelin Mountain in spring. The low ozone episodes were observed from late March to the beginning of June. When the effect of transport direction was subtracted, the frequenty of the low ozone episodes was found to peak in the beginning of May, possibly reflecting the seasonal cycle in the actual depletion process. Analyses based on trajectory calculations show that most of the episodes occurred when the air masses were transported from W-N. Ozone soundings show that the ozone depletion may extend from the surface and up to 3–4 km altitude. The episodes were associated with a cold boundary layer beneath a thermally stable layer, suppressing mixing with the free troposphere. The concentration of several individual hydrocarbons was much lower during episodes of low ozone than for the average conditions. The change in concentration ratio between the hydrocarbons was in qualitative agreement with oxidation of hydrocarbons by Br and Cl atoms rather than by OH radicals. 相似文献
3.
Two years of individual nonmethane hydrocarbon (NMHC) measurements at a rural site close to the south coast of Norway show that there was a distinct annual cycle with a late winter maximum and late summer minimum in the slowly reacting NMHCs acetylene, ethane, propane and i- and n-butane. The average January—March concentrations were a factor 2–4 higher than the July-September concentrations. Also ethene, propene and the pentanes show a similar annual cycle, but the individual scatter in the measurements in particular of propene, is large. The highest concentrations of NMHC were found in winter for easterly transport on a regional scale (out to 1500 km from the site), and for southeasterly transport in the summer. 相似文献
4.
A long-range transport model with nonlinear chemical reactions is described. The model contains 35 pollutants and 70 chemical reactions. This is a Eulerian model defined on a space domain containing the whole of Europe. The spherical space domain (corresponding to the Earth's surface covered by the model) is mapped into a square plane domain and discretized by using a 32×32 grid. The grid increments are equidistant (both along the Ox axis and along the Oy axis). The choice of values of the physical parameters involved in the model and the numerical treatment of the model are shortly discussed. The model is tested with meteorological data for 1985 and 1989. The numerical results are compared with measurements at stations located in different European countries. Extensive comparisons of ozone concentrations for July 1985 with measurements taken at 24 European stations are also carried out. Results concerning three episodes in July 1985 as well as results obtained in the study of the sensitivity of the ozone concentrations to variations of NO
x
and/or anthropogenic VOC emissions are presented. The advantages and the limitations of such a model are discussed. The model is continuously improved by adding new modules to it. The plans for improvements in the near future are outlined. 相似文献
5.
Two new Th ii lines have been identified in the spectrum of the solar photosphere. The abundance derived from these lines together with the previously known Th ii line at 4019 Å, is log
Th = 0.85 ± 0.20 in the log
H = 12.00 scale. Analysis of three Pb i lines in the photospheric spectrum resulted in an abundance of log
pb = 1.90 ± 0.10. The solar Th/Pb ratio is:
Th/
Pb = 0.09
-0.005
0.09
. 相似文献
6.
Basin modelling studies are carried out in order to understand the basin evolution and palaeotemperature history of sedimentary basins. The results of basin modelling are sensitive to changes in the physical properties of the rocks in the sedimentary sequences. The rate of basin subsidence depends, to a large extent, on the density of the sedimentary column, which is largely dependent on the porosity and therefore on the rate of compaction. This study has tested the sensitivity of varying porosity/depth curves and related thermal conductivities for the Cenozoic succession along a cross‐section in the northern North Sea basin, offshore Norway. End‐member porosity/depth curves, assuming clay with smectite and kaolinite properties, are compared with a standard compaction curve for shale normally applied to the North Sea. Using these alternate relationships, basin geometries of the Cenozoic succession may vary up to 15% from those predicted using the standard compaction curve. Isostatic subsidence along the cross‐section varies 2.3–4.6% between the two end‐member cases. This leads to a 3–8% difference in tectonic subsidence, with maximum values in the basin centre. Owing to this, the estimated stretching factors vary up to 7.8%, which further gives rise to a maximum difference in heat flow of more than 8.5% in the basin centre. The modelled temperatures for an Upper Jurassic source rock show a deviation of more than 20 °C at present dependent on the thermal conductivity properties in the post‐rift succession. This will influence the modelled hydrocarbon generation history of the basin, which is an essential output from basin modelling analysis. Results from the northern North Sea have shown that varying compaction trends in sediments with varying thermal properties are important parameters to constrain when analysing sedimentary basins. 相似文献
7.
Ø. Grøn 《Astrophysics and Space Science》1988,140(2):429-430
The gravitational field equations in Dunn's scalar-tensor theory of gravitation are generalized by including a cosmological constant. The resulting equations are solved for a Robertson-Walker line-element with flat three-space. The solution represents a cosmological model that develops into an inflationary era. 相似文献
8.
Asgeir Sorteberg Øystein Hov Sverre Solberg Kjetil Tørseth Hans Areskoug Martin Ferm Kit Granby Heikki Lättilä Karin Persson David Simpson 《Journal of Atmospheric Chemistry》1998,30(2):241-271
Observations of the concentration of several nitrogen containing compounds at five rural Scandinavian sites during March–June 1993 are reported. Total nitrate (NO
3
-
+ HNO3) and total ammonium (NH
4
+
+ NH3) were measured by denuder and filter pack. In general the methods agree well. At all sites the particulate fraction dominated, with the largest fraction of NO
3
-
and the lowest of NH
4
+
at the sites which were closest to the emission sources. The fraction of NO
3
-
of total nitrate increased with increasing NO2 concentrations, indicating that the nighttime conversion of NO2 to NO
3
-
is an important route of formation for NO
3
-
. A positive correlation was found between HNO3 and O3 in June at all sites, while no correlation was found early in the spring. Model calculations were made with a lagrangian boundary layer photooxidant model for the whole period, and compared to the measured concentrations. The calculated ratio between mean observed and modelled daily maximum concentrations of ozone over the measurement period were within +/–10% at all sites. The models ability to describe the daily ozone maximum concentration was satisfactory with an average deviation of 19–22% from the observed concentrations. HNO3 was underestimated by over 50% at all sites except the one closest to the emission sources. The correlation between modelled and observed concentrations was generally best for the sites with shortest transport distance from the sources of emission. 相似文献
9.
10.
Ø. Grøn 《Astrophysics and Space Science》1990,173(2):191-225
The research on viscous cosmological models is reviewed and carried further. Inflationary cosmological models of Bianchi type-I with shear, bulk, and nonlinear viscosity are studied. The inflation field energy is represented by a two-components cosmic fluid consisting of a vacuum fluid and a Zel'dovich fluid. It is shown that there exist models in which the viscous Zel'dovich fluid removes the initial singularity of the corresponding viscosity free models. The mean expansion of a Zel'dovich dominated unvierse is found to be independent of shear viscosity and anisotropy. Bulk viscosity and shear viscosity cause exponential decay of anisotropy, while nonlinear viscosity causes power-law decay of anisotropy. 相似文献