Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H₂S concentrations   总被引：2，自引：0，他引：2  

Chunfang Cai  Zengye Xie  Richard H. Worden  Guoyi Hu  Lansheng Wang  Hong He 《Marine and Petroleum Geology》2004,21(10):1265-1279

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.  相似文献   

粤西地区县域城镇化发展探讨——以广东省高州市为例   总被引：1，自引：0，他引：1  

张志斌  雷春芳 《山地学报》2006,24(6):709-715

受地理条件、经济基础等因素的制约,粤西地区面临着城镇化进程滞后、整体发展层次偏低等一系列问题。加速推进县域城镇化是加快粤西地区经济发展,缩小与发达地区差距的内在要求和必然选择。以高州市为例,全面总结了粤西地区县域城镇化发展的特点及存在的主要问题,并在系统分析其城镇化发展机制的基础上,提出通过完善城镇体系,加强产业集聚,提升建设品位,增强城镇自我发展能力等促进县域城镇化发展。  相似文献   

Early Yanshanian post-orogenic granitoids in the Nanling region
Petrological constraints and geodynamic settings   总被引：1，自引：0，他引：1  

Peirong Chen  Renmin Hua  Bangtong Zhang  Jianjun Lu  Chunfang Fan 《中国科学D辑(英文版)》2002,45(8):755-768

Early Yanshanian magmatic suites predominate absolutely in the Nanling granite belt. They consist mainly of monzogranite and K-feldspar granite. There occur associations of early Yanshanian A-type granitoids (176 Ma-178 Ma) and bimodal volcanic rocks (158 Ma-179 Ma) in southern Jiangxi and southwestern Fujian in the eastern sector of the granite belt and early Yanshanian basalts (177 Ma-178 Ma) in southern Hunan in the central sector of the belt. Both the acid end-member rhyolite in the bimodal volcanic rock association and A-type granitoids in southern Jiangxi have the geochemical characteristics of intraplate granitic rocks and the basic end-member basalt of the association is intraplate tholeiite, while the basaltic rocks in southern Hunan include not only intraplate tholeiite but also intraplate alkali basalt. Therefore the early Yanshanian magmatic suites in the Nanling region are undoubtedly typical post-orogenic rock associations. Post-orogenic suites mark the end of a post-collision or late orogenic event and the initiation of Pangaea break-up, indicating that a new orogenic Wilson cycle is about to start. Therefore it may be considered that the early Yanshanian geodynamic settings in the Nanling region should be related to post-orogenic continental break-up after the Indosinian orogeny and the break-up did not begin in the Cretaceous.  相似文献   

沉积盆地流体—岩石相互作用研究的现状   总被引：17，自引：0，他引：17  

蔡春芳 《地球科学进展》1996,11(6):575-579

沉积盆地流体－岩石相互作用研究主要是通过实验地球化学和岩石学，地球化学模拟方法开展的，综述了这一领域的研究现状，主要包括有机酸来源和分布及期 对矿物稳定性的影响，地层水成因与演化、烃类与岩石间的氧化还原反应、以及储层润湿性的变化等，并展望了其 发展趋势。  相似文献   

民和盆地上侏罗统湿型冲积扇沉积   总被引：2，自引：0，他引：2  

蔡春芳  关银录 《矿物岩石》1997,17(2):61-66

本文通过岩相特征、粘土矿物分布、早期成岩矿物组合、微量元素等特征的综合分析，认为民和盆地上侏罗统下部为一较典型的湿型冲积扇沉积。冲积扇扇中发育河道冲刷充填和漫流沉积，而泥石流不发育。沉积层序与现代湿型冲积扇可对比。扇体中粘土岩及早期成岩矿物组合中富含高岭石，应与扇体发育时的潮湿气候和弱酸性流体的较强的淋滤有关。由粘土岩中微量元素因子分析进一步表明，该地层中富硼、钒的特征与相邻非扇相地层明显不同  相似文献   

Mineralogy and geochemistry of granitoids from Kinnaur region,Himachal Higher Himalaya,India: Implication on the nature of felsic magmatism in the collision tectonics     

Brajesh Singh  Santosh Kumar  Masao Ban  Kazuo Nakashima 《Journal of Earth System Science》2016,125(7):1329-1352

Felsic magmatism in the southern part of Himachal Higher Himalaya is constituted by Neoproterozoic granite gneiss (GGn), Early Palaeozoic granitoids (EPG) and Tertiary tourmaline-bearing leucogranite (TLg). Magnetic susceptibility values (<3 ×10^?3 SI), molar Al₂ O ₃/(CaO + Na₂ O + K ₂O) (≥1.1), mineral assemblage (bt–ms–pl–kf–qtz ± tur ± ap), and the presence of normative corundum relate these granitoids to peraluminous S-type, ilmenite series (reduced type) granites formed in a syncollisional tectonic setting. Plagioclase from GGn (An₁₀–An₃₁) and EPG (An₁₅–An₃₃) represents oligoclase to andesine and TLg (An₂–An₁₅) represents albite to oligoclase, whereas compositional ranges of K-feldspar are more-or-less similar (Or₈₈ to Or₉₅ in GGn, Or₈₆ to Or₉₇ in EPG and Or₈₇ to Or₉₄ in TLg). Biotites in GGn (Mg/Mg + Fe^t= 0.34–0.45), EPG (Mg/Mg + Fe^t= 0.27–0.47), and TLg (Mg/Mg + Fe^t= 0.25–0.30) are ferribiotites enriched in siderophyllite, which stabilised between FMQ and HM buffers and are characterised by dominant 3Fe\(\rightleftharpoons \)2Al, 3Mg\(\rightleftharpoons \)2Al substitutions typical of peraluminous (S-type), reducing felsic melts. Muscovite in GGn (Mg/Mg + Fe^t=0.58–0.66), EPG (Mg/Mg + Fe^t=0.31?0.59), and TLg (Mg/Mg + Fe^t=0.29–0.42) represent celadonite and paragonite solid solutions, and the tourmaline from EPG and TLg belongs to the schorl-elbaite series, which are characteristics of peraluminous, Li-poor, biotite-tourmaline granites. Geochemical features reveal that the GGn and EPG precursor melts were most likely derived from melting of biotite-rich metapelite and metagraywacke sources, whereas TLg melt appears to have formed from biotite-muscovite rich metapelite and metagraywacke sources. Major and trace elements modelling suggest that the GGn, EPG and TLg parental melts have experienced low degrees (～13, ～17 and ～13%, respectively) of kf–pl–bt fractionation, respectively, subsequent to partial melting. The GGn and EPG melts are the results of a pre-Himalayan, syn-collisional Pan-African felsic magmatic event, whereas the TLg is a magmatic product of Himalayan collision tectonics.  相似文献   

库车坳陷新生代构造应力场恢复     

郑淳方  侯贵廷  詹彦  于璇  赵文韬 《地质通报》2016,35(1):130-139

库车坳陷的构造变形及演化与南天山造山带的发育密切相关。库车坳陷新近纪以来的喜马拉雅晚期构造运动最为强烈,形成了天山山前大型冲断带,并造就了现今的构造格局。通过对库车坳陷北部构造样式的识别及各种应力场指示标志的测量、统计和构造解析,对野外获得的应力场指示标志划分了期次,认为喜马拉雅晚期应力场标志为近南北向挤压。结合库车坳陷区域构造要素,如地质体几何形态、边界条件、岩石力学参数等,运用弹性力学有限元数值模拟的方法获得了喜马拉雅晚期库车坳陷的区域应力场。模拟结果表明,库车坳陷喜马拉雅晚期最大主压应力方向为近南北向,与古应力场标志拟合较高,可以为库车坳陷裂缝预测和评价提供依据,对勘探开发有应用价值。  相似文献   

A direction-dependent shear strength criterion for rock joints with two new roughness parameters     

Liren Ban  Chengzhi Qi  Chunsheng Lu 《Arabian Journal of Geosciences》2018,11(16):466

The surface morphology of a rock joint is closely related to its mechanical properties. To reasonably characterize a rock surface, two new roughness parameters were proposed in this paper. One is related to the average slope angle of asperities that contribute to the shear strength, and the other reflects the frictional behavior of asperities that is defined as the maximum possible contact area in the shear direction. Taking the standard joint roughness coefficient profiles as example, these two roughness parameters can be applied to describe the directional characteristics of shear strength. Based on their relationships with initial dilation angles, the proposed roughness parameters were incorporated into a peak shear strength criterion. It is shown that the predicted peak shear strength is consistent with experimental data, and there is a power–law relationship. The application range of new roughness parameters was determined, which may facilitate a measurement process.  相似文献   

长输管道抗震研究的新进展   总被引：2，自引：0，他引：2  

陈贵清  郝婷玥  吴班  王兴国 《地震工程与工程振动》2006,26(3):193-196

本文主要从以下4个方面:地震对长输管道的危害、长输管道震害的研究方法、管道抗震分析和管道抗震的措施,介绍了近几年长输管道抗震方面的研究进展,指出了今后长输管道的研究方向。  相似文献   

CA FCM方案与其它几种人工增雨评估方案的比较     

房彬  肖辉  班显秀 《气象科技》2008,36(5):612-621

对河南省12次飞机增雨作业,分别采用作业区域趋势对比双比分析评估方案、区域趋势相关回归分析方案、区域趋势协变量多元回归分析方案、浮动对比区历史回归分析方案（FCM）、以降水量为协变量的CAFCM（ClusterAnalysis〖CD*2〗based Floating Control historical regression Method）方案和以降水量和整层大气可降水量为协变量的CAFCM方案进行效果评估,均得到大于15％的相对增雨量。对结果比较分析表明：协变量由降水量和整层大气降水量两个组成的C  相似文献