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1.
Biogenic barium, mostly in the barite (BaSO4) form, has been proposed as a tracer for export production in the ocean. Here we report on biogenic barium (Baxs) and particulate organic carbon (POC) fluxes from sediment traps deployed at the DYFAMED site in the Northwestern Mediterranean Sea. Baxs fluxes display average values of 37 ± 45 and 50 ± 58 μg/m2/d at 200 and 1000 m respectively, and are linearly correlated to POC fluxes (mean values of 7.9 ± 9.3 and 6.8 ± 6.8 mg C/m2/d at 200 and 1000 m). Export production estimates, calculated using published Baxs- or POC-based algorithms, all fall below or close to the lower limit of potential export values proposed in the literature. This work clearly demonstrates the usefulness of Baxs as a tracer of oceanic export production in the Northwestern Mediterranean Sea. However, development of a quantitative export production proxy requires a clear understanding of the underlying cause(s) for the observed spatial variations in the relationship between Baxs and POC fluxes. The present study confirms that the processes leading to barite formation differ between margin and open-ocean sites and probably account for much of the regional variability in the POC/Baxs ratio.  相似文献   
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In 1972 UNESCO created the World Heritage List to 'preserve the world's superb natural and scenic areas and historic sites for the present and future generations of citizens of the entire world'. Nominated sites must be of 'outstanding universal value' and meet at least one of ten selection criteria, six cultural and four natural. Teide National Park (TNP) was inscribed in the World Heritage List in 2007 for its natural beauty and its 'global importance in providing evidence of the geological processes that underpin the evolution of oceanic islands' (Criteria vii and viii). The geological values rendering PNT an exceptional site are analysed in this article. Volcanism in Tenerife and TNP correspond to the Ocean Island Alkali Basalts (OIB), whereas the already nominated (1987) Hawaii Volcanoes National Park, from a different geodynamic setting, belongs to the Tholeiitic series (OIT). Both National Parks complement each other to represent the entire range of products, features and landscapes of oceanic islands. The main geological elements of this Park include Las Cañadas Caldera, one of the most spectacular, best exposed and accessible volcanic calderas on Earth, two active rifts, and two large felsic stratovolcanoes, Teide and Pico Viejo, rising 3718 m above sea level and around 7500 m above the ocean floor, together the third highest volcanic structure in the world after the Mauna Loa and Mauna Kea volcanoes on the island of Hawaii.  相似文献   
4.
The goal of this study was to statistically analyse the variability of global irradiance and ultraviolet erythemal (UVER) irradiance and their interrelationships with global and UVER irradiance, global clearness indices and ozone. A prediction of short-term UVER solar irradiance values was also obtained. Extreme values of UVER irradiance were included in the data set, as well as a time series of ultraviolet irradiance variability (UIV). The study period was from 2005 to 2014 and approximately 250,000 readings were taken at 5-min intervals. The effect of the clearness indices on global irradiance variability (GIV) and UIV was also recorded and bi-dimensional distributions were used to gather information on the two measured variables. With regard to daily GIV and UIV, it is also shown that for global clearness index (kt) values lower than 0.6 both global and UVER irradiance had greater variability and that UIV on cloud-free days (kt higher than 0.65) exceeds GIV. To study the dependence between UIV and GIV the χ2 statistical method was used. It can be concluded that there is a 95% probability of a clear dependency between the variabilities. A connection between high kt (corresponding to cloudless days) and low variabilities was found in the analysis of bi-dimensional distributions. Extreme values of UVER irradiance were also analyzed and it was possible to calculate the probable future values of UVER irradiance by extrapolating the values of the adjustment curve obtained from the Gumbel distribution.  相似文献   
5.
Changes in phytoplankton composition and degradation of particulate organic matter (POM) in the northwestern Mediterranean Sea were studied using time-series sediment trap samples collected during the spring of 2003 at the DYFAMED station. Lipid biomarkers (pigments, fatty acids, sterols, acyclic isoprenoids, alkenones and n-alkanols) were used to identify the main contributors to the POM produced during two phytoplankton blooms, while the effects of photooxidation, autoxidation and biodegradation were differentiated using characteristic lipid degradation products. Traps collected material corresponding to pre-bloom, bloom and post-bloom periods. Pigment analyses in the integrated (0-200 m) water column samples indicated that diatoms dominated the initial stages of the bloom event, with smaller amounts of haptophytes and pelagophytes. During the second part of bloom event there was a switch to haptophyte dominance with significant contributions from diatoms and pelagophytes, and an increased contribution from cryptophytes. Fatty acid distributions in the trap samples reflected contributions from marine bacteria, phytoplankton and zooplankton. Photooxidation and autoxidation products of monounsaturated oleic, cis-vaccenic and palmitoleic acids were detected along with photooxidation products from the chlorophyll side-chain. The relatively good correlation between the variation of U37K′ index and specific phytol autoxidation product percentage allowed us to attribute the alterations of U37K′ observed during the pre-bloom period and in the deeper traps to the involvement of selective autoxidative degradation processes. A variety of sterol oxidation products formed by biohydrogenation, autoxidation and photooxidation were detected. Sterol degradation products appeared to be less suited than oxidation products of monounsaturated fatty acids for the precise monitoring of the degradation state of POM, but their stable functionalized cyclic structure constitutes a useful tool to estimate the part played by biotic and abiotic processes. In these waters, biotic degradation generally predominates, but abiotic degradation is not negligible and, as expected, the extent of biotic degradation increases with depth. To obtain a more complete picture of POM degradation, the use of a pool of lipid degradation products (i.e. from unsaturated fatty acids, the phytyl side-chain and sterols) should be employed.  相似文献   
6.
Olivier  Monod  Michel  Faure  Juan-Carlos  Salinas 《Island Arc》1994,3(1):25-34
Abstract The pre-Oligocene structure of southwest Mexico, south of the trans-Mexico volcanic axis, is investigated from Taxco (Guerrero state, abbreviation: Gro) to the Pacific coast. Three volcano-sedimentary units are recognized; from east to west the calc-alkaline Teloloapan, tholeiitic Arcelia and calc-alkaline Zihuatanejo suites. Structural and stratigraphic data show that the Teloloapan volcanic arc, active during ?Late Jurassic and early Cretaceous, was built upon continental basement. The Teloloapan lavas are overlain by the Albian–Cenomanian Morelos platform carbonates and followed by the Upper Cretaceous Mexcala flysch. In contrast, the Arcelia pillow lavas are associated with sandstones and cherts of Albian-?Cenomanian age. The Zihuatanejo arc was also installed upon continental basement and its magmatic activity was in part coeval with Arcelia magmatism. Unlike the almost undeformed Zihuatanejo volcanic rocks, all the other volcanic units are involved in east-vergent thrusting and recumbent folding associated with ductile tectonics, as well as the Late Cretaceous Mexcala flysch overlying the Morelos platform carbonates. Contrasting with previous views, the present results do not support a major mid-Cretaceous thrusting event in the study area. The new geodynamic interpretation proposed here considers that the Arcelia rocks were formed in a marginal basin situated east of the Zihuatanejo arc. Closure of this basin in Paleocene times is responsible for the east vergent thrust tectonics in SW Mexico.  相似文献   
7.
The DYFAMED time-series station, located in the open Ligurian Sea, is one of the few pluriannual flux programs in the world and the longest in the Mediterranean Sea. The trap data series is one of only three multi-decadal data sets in existence, and it provides flux information for an environment that is distinct from the other long-term data sets. At DYFAMED, downward fluxes of particles, carbon and other major elements have been regularly measured with sediment traps since 1986 at fixed depths of 200 and 1000 m. An overview is presented of the main trends of particle and carbon fluxes observed during the period 1988–2005, period when the mooring was located on the northern side of the Ligurian Sea. In spite of considerable interannual variability, fluxes displayed a marked seasonal pattern with the highest fluxes occurring during winter and spring and lowest fluxes throughout the stratified season (summer–autumn). Organic carbon fluxes measured at both depths were highly variable over time, ranging from 0.3 to 59.9 (mean 6.8) mg C m−2 d−1 at 200 m, and from 0.2 to 37.1 (mean 4.3) mg C m−2 d−1 at 1000 m. Mass fluxes were maximal in winter, whereas carbon fluxes were maximal in late spring. Reasonably good agreement existed between particle fluxes at both depths over the years, indicating a relatively efficient and rapid transport of particles from the upper ocean to the deep sea. However, during certain periods mass flux increased with depth suggesting lateral inputs of particles that by-pass the upper trap. Since 1999, the system has apparently shifted towards an increasing occurrence of extreme flux events in response to more vigorous mixing of the water column during the winter months. Although annual mass fluxes have increased in the last years, mean POC fluxes have not substantially changed over time, due mainly to lower carbon contents of the sinking particles during maxima of mass flux.  相似文献   
8.
There is currently a huge gulf between natural scientists’ understanding of climate tipping points and economists’ representations of climate catastrophes in integrated assessment models (IAMs). In particular, there are multiple potential tipping points and they are not all low-probability events; at least one has a significant probability of being passed this century under mid-range (2–4 °C) global warming, and they cannot all be ruled out at low (<2 °C) warming. In contrast, the dominant framing of climate catastrophes in IAMs, and in critiques of them, is that they are associated with high (> 4 °C) or very high (> 8 °C) global warming. This discrepancy could qualitatively alter the predictions of IAMs, including estimates of the social cost of carbon. To address this discrepancy and assess the economic impact of crossing different climate tipping points, we highlight a list of scientific points that should be considered, at least in a stylised form, in simplified IAMs. For nine different tipping events, the range of expected physical climate impacts is summarised and some suggestions are made for how they may translate into socio-economic impacts on particular sectors or regions. We also consider how passing climate tipping points could affect economic growth.  相似文献   
9.
Abstract

The Powell Basin is one of the few present-day examples of a small isolated ocean basin largely surrounded by blocks of continental crust. The continental blocks in this basin result from the fragmentation of the northern Antarctic Peninsula. This basin was created by the eastward motion of the South Orkney microcontinent relative to the Antarctic Peninsula. The axial rift, identified by multichannel seismic profiles obtained during the HESANT 92/93 cruise, and the gravimetric anomalies of the basin plain, together with the transcurrent faults along the northern and southern margins, indicate a predominant WSW-ENE trend of basin extension. The South Orkney microcontinent was incorporated into the Antarctic Plate during the Miocene as a consequence of the end of basin spreading. The eastern and western margins are conjugate and have an intermediate crust in the region of transition to the basin plain. The differences in the basement structure and the architecture of the depositional units suggest that the extensional process was asymmetrical. The southern transtensive margin and the northern transcurrent margin are rectilinear and steep, without any intermediate crust in the narrow fault zone between the base of the continentalblocks slope and the oceanic crust. The multichannel seismic profiles across the central sector of the basin reveal a spreading axis with a double ridge and a central depression filled with sediments. The geometry of the reflectors in this depression indicates that the ponded deposits belong to the early stages of oceaniccrust accretion. This structure is similar to the overlapping spreading centres observed in fast-spreading oceanic axes, where the spreading axis has relay and overlapping segments.

The depositional units of the margins and basin plain have been grouped into four depositional sequences, comprising the classic stages in the formation of an ocean basin: pre-rift (S1), syn-rift (S2), syn-drift (S3), and post-drift (S4). The pre-rift sequence has deformed reflectors and is observed in the southern and eastern margins. The syn-rift sequence, tectonically disrupted, fills depressions bounded by faults and is well-developed in the eastern margin where it is truncated by an erosive surface identified as the break-up unconformity. The syn-drift sequence is wedge-shaped in the basin, thickening towards the margins and having onlap relations on the flanks of the spreading ridge. The post-drift sequence is the thickest unit and is characterised by a cyclic pattern of alternating packages of high-amplitude reflectors, very continuous, and low-amplitude reflectors. Towards the western and eastern margins, the same sequence has channel-levee complexes and channelised, wedged bodies attributed to turbiditic deposits of submarine fans derived from canyons located in the slope and outer shelf. The cyclic nature of this sequence is probably related to advancing and receding grounded ice sheets in the continental shelf since the latest Miocene.  相似文献   
10.
The different sources of lipid compounds present in sinking particles collected in a sediment trap mooring deployed in the Alboran Sea (SW Mediterranean) were elucidated using the molecular marker concept. A significant contribution of cyanobacterial lipids was identified based on the occurrence of a series of 3- and 5-methylalkanes and dimethylalkanes. Further evidence of cyanobacterial inputs was obtained by principal component analysis of all data showing diploptene and n-alkanes in the range C14–C22 clustered together with those branched alkanes. The use of methyl and dimethyl alkanes to trace cyanobacterial sources in the water column is proposed with advantage to sterols which are usually masked by phytoplanktonic sterols. The sterol distribution indicates phytoplankton as a major source with a contribution from heterotrophic zooplanktonic. Both fossil and biogenic sources can be contributors to the large unresolved complex mixture (UCM) found in these samples.  相似文献   
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