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1.
A study of presolar material in hydrated lithic clasts from metal-rich carbonaceous chondrites 下载免费PDF全文
We report on the investigation of presolar grain inventories of hydrated lithic clasts in three metal-rich carbonaceous chondrites from the CR clan, Acfer 182 (CH3), Isheyevo (CH3/CBb3), and Lewis Cliff (LEW) 85332 (C3-un), as well as the carbon- and nitrogen-isotopic compositions of the fine-grained clast material. Eleven presolar silicate grains as well as nine presolar silicon carbide (SiC) grains were identified in the clasts. Presolar silicate abundances range from 4 to 22 parts per million (ppm), significantly lower than in pristine meteorites and interplanetary dust particles (IDP), and comparable to recent findings for CM2s and CR2 interchondrule matrix. SiC concentrations lie between 9 and 23 ppm, and are comparable to the values for CI, CM, and CR chondrites. The results of our investigation suggest similar alteration pathways for the clast material, the interchondrule matrix of the CR2 chondrites, and the fine-grained fraction of CM2 chondrites. Fine-grained matter of all three meteorites contains moderate to high 15N-enrichments (~50‰ ≤ δ15N ≤ ~1600‰) compared to the terrestrial value, indicating the presence of primitive organic material. We observed no correlation between 15N-enrichments and presolar dust concentrations in the clasts. This is in contrast to the findings from a suite of primitive IDPs, which display in several cases enhanced bulk 15N/14N ratios and high presolar grain abundances of several hundred or even thousand ppm. The bulk 15N/14N ratios of the clasts are comparable to the range for primitive IDPs, suggesting a nitrogen carrier less susceptible to destruction by aqueous alteration than silicate stardust. 相似文献
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Microbial mineralization and assimilation of black carbon: Dependency on degree of thermal alteration 总被引:4,自引:0,他引:4
Black carbon is degraded slowly in the environment and its formation can therefore be an effective sink for atmospheric CO2. This study examined whether charcoal is assimilated by microorganisms or not and estimated the rate of mineralization depending on the degree of thermal alteration of the black carbon. Charcoals were produced at three different temperatures from homogeneously 14C labelled plant material and incubated in soil, and 14C in the evolved CO2 and the microbial biomass was measured. Unlike parallel plant samples, CO2 evolution from the charcoals showed no lag phase, but a period of faster CO2 evolution for the first 5–8 days followed by a period of slow evolution. The mineralization of charcoal appeared to decrease with increasing temperature at which it was produced. This was also the case after the initial period of fast CO2 evolution. With the techniques used, it was not possible to observe any microbial assimilation of charcoal, either because it did not occur, or because the methods used were not sufficiently sensitive. However, the lack of a lag phase in the CO2 evolution from the charcoals is in line with earlier evidence that charcoal is initially oxidized at the surfaces by abiotic processes. 相似文献
7.
Doline probability map using logistic regression and GIS technology in the central Ebro Basin (Spain) 总被引:3,自引:0,他引:3
In the surroundings of Zaragoza, karstification processes are especially intense in covered karst areas where fluvial terraces
lie directly on Tertiary evaporites. Since the beginning of Quaternary, these processes have lead to the development of collapse
and subsidence dolines with a wide range of sizes, which have significant economic impacts. To reduce economic impact and
increase safety, a regional analysis of this phenomenon is needed for spatial management. Therefore, a probability map of
dolines was developed using logistic regression and geographic information system (GIS) techniques. This paper covers the
selection of input data, manipulation of data using the GIS technology, and the use of logistic regression to generate a doline
probability map. The primary variable in the doline development in this area is geomorphology, represented by the location
of endorheic areas and different terrace levels. Secondary variables are the presence of irrigation and the water table gradient. 相似文献
8.
Zaragoza city is located in the central Ebro Basin, in the Iberian Peninsula. The fluvial terraces formed by the Ebro River
present a valuable resource of sand and gravel deposits. However, taking advantage of these available resources implies conflicts
with other land use interests like urban and industrial development as well as agricultural use, which has also traditionally
occupied the alluvial terraces. These deposits represent a substantial groundwater resource that should be preserved for future
generations. The development of spatial decision support systems (SDSS) has greatly assisted efforts for solving land-use
conflicts. These systems combine the benefits of geographic information systems (GIS) and decision support methodologies and
are therefore suitable to manage sustainable development of urban areas. In this contribution, an extraction suitability map
taking into consideration a variety of environmental criteria is created with the help of a SDSS. The method used is the analytical
hierarchy process which is integrated in ArcGIS. Areas most suitable to sand and gravel extraction are located in the high
terraces, and in those terraces covered by pediments where the thickness of resource is relatively high. These areas are far
from valuable natural areas, outside areas most vulnerable to groundwater contamination, and beneath soils with poor irrigation
characteristics. 相似文献
9.
Steven J.K. Symes Lars E. Borg Charles K. Shearer 《Geochimica et cosmochimica acta》2008,72(6):1696-1710
Samarium-neodymium isotopic analyses of unleached and acid-leached mineral fractions from the recently identified olivine-bearing shergottite Northwest Africa 1195 yield a crystallization age of 347 ± 13 Ma and an value of +40.1 ± 0.9. Maskelynite fractions do not lie on the Sm-Nd isochron and appear to contain a martian surface component with low 147Sm/144Nd and 143Nd/144Nd ratios that was added during shock. The Rb-Sr system is disturbed and does not yield an isochron. Terrestrial Sr appears to have affected all of the mineral fractions, although a maximum initial 87Sr/86Sr ratio of 0.7016 is estimated by passing a 347 Ma reference line through the maskelynite fraction that is least affected by contamination. The high initial value and the low initial 87Sr/86Sr ratio, combined with the geologically young crystallization age, indicate that Northwest Africa 1195 is derived from a source region characterized by a long-term incompatible-element depletion.The age and initial Sr and Nd isotopic compositions of Northwest Africa 1195 are very similar to those of Queen Alexandra Range 94201, indicating these samples were derived from source regions with similar Sr-Nd isotopic systematics. These similarities suggest that these two meteorites share a close petrogenetic relationship and might have been erupted from a common volcano. The meteorites Yamato 980459, Dar al Gani 476, Sayh al Uhaymir 005/008, and Dhofar 019 also have relatively old ages between 474 and 575 Ma and trace element and/or isotopic systematics that are indicative of derivation from incompatible-element-depleted sources. This suggests that the oldest group of meteorites is more closely related to one another than they are to the younger meteorites that are derived from less incompatible-element-depleted sources. Closed-system fractional crystallization of this suite of meteorites is modeled with the MELTS algorithm using the bulk composition of Yamato 980459 as a parent. These models reproduce many of the major element and mineralogical variations observed in the suite. In addition, the rare earth element systematics of these meteorites are reproduced by fractional crystallization using the proportions of phases and extents of crystallization that are calculated by MELTS. Other shergottites that demonstrate enrichments in incompatible-elements and have evolved Sr and Nd isotopic systematics have some geochemical systematics that are similar to those observed in the depleted group. Most notably, although they exhibit a very limited range of incompatible trace element and isotopic compositions, they have highly variable major element compositions. This is also consistent with evolution from a common mantle source region by variable amounts of fractional crystallization. If this scenario is correct, it suggests that the combined effects of source composition and fractional crystallization are likely to account for the major element, trace element, and isotopic diversity of all shergottites. 相似文献
10.
Lars Olov Andersson 《Physics and Chemistry of Minerals》2008,35(9):505-520
The EPR spectra of Maxixe-type beryl contain a large number of overlapping signals. The angular dependence of the 1:3:3:1
signal typical for the CH3 radical shows that this radical is located at the center of the channel cavity with its symmetry axis parallel to the crystal
c-axis and is rotating around this axis. Its EPR spectrum is axially symmetric with g
// = 2.00263, g
⊥ = 2.00249 and A// = 2.288 mT, A⊥ = 2.256 mT. These anisotropies have the opposite signs of those found for surface-adsorbed methyl radicals. Hydrogen atoms
are located at position 2a at the center of the beryl cavity and the EPR parameters of the narrow doublet signal are A
0 = 1,407 MHz and g = 2.00230. Another doublet signal, which is broader and has axial symmetry with g
// = 2.00265, g
⊥ = 2.00625 and A// = 0.895 mT, A⊥ = 0.885 mT, could come from a HCO3 radical. One narrow and easily saturated signal with g
// = 2.00227 and g
⊥ = 2.00386 is interpreted to arise from a carbon monoxide radical in the beryl channel, oriented with its axis parallel to
the crystal c-axis. Additional weak doublet lines, which have similar g values as the carbon monoxide radical, are created by nearby hydrogens. A powder spectrum with g
// = 2.0017 and g
⊥ = 2.0004 appears upon UV irradiation of the single crystal and is easily saturated. This spectrum is interpreted to arise
from a carbon dioxide radical, which rotates around its symmetry axis. 相似文献