Oxygen isotopic compositions of Allende Type C CAIs: Evidence for isotopic exchange during nebular melting and asteroidal metamorphism     

A.N. Krot  M. Chaussidon  H. Yurimoto  N. Sakamoto  K. Nagashima  I.D. Hutcheon  G.J. MacPherson 《Geochimica et cosmochimica acta》2008,72(10):2534-2555

In situ oxygen isotopic measurements of primary and secondary minerals in Type C CAIs from the Allende CV3 chondrite reveal that the pattern of relative enrichments and depletions of ¹⁶O in the primary minerals within each individual CAI are similar to the patterns observed in Types A and B CAIs from the same meteorite. Spinel is consistently the most ¹⁶O-rich (Δ¹⁷O = −25‰ to −15‰), followed by Al,Ti-dioside (Δ¹⁷O = −20‰ to −5‰) and anorthite (Δ¹⁷O = −15‰ to 0‰). Melilite is the most ¹⁶O-depleted primary mineral (Δ¹⁷O = −5‰ to −3‰). We conclude that the original melting event that formed Type C CAIs occurred in a ¹⁶O-rich (Δ¹⁷O  −20‰) nebular gas and they subsequently experienced oxygen isotopic exchange in a ¹⁶O-poor reservoir. At least three of these (ABC, TS26F1 and 93) experienced remelting at the time and place where chondrules were forming, trapping and partially assimilating ¹⁶O-poor chondrule fragments. The observation that the pyroxene is ¹⁶O-rich relative to the feldspar, even though the feldspar preceded it in the igneous crystallization sequence, disproves the class of CAI isotopic exchange models in which partial melting of a ¹⁶O-rich solid in a ¹⁶O-poor gas is followed by slow crystallization in that gas. For the typical (not associated with chondrule materials) Type C CAIs as well for as the Types A and B CAIs, the exchange that produced internal isotopic heterogeneity within each CAI must have occurred largely in the solid state. The secondary phases grossular, monticellite and forsterite commonly have similar oxygen isotopic compositions to the melilite and anorthite they replace, but in one case (CAI 160) grossular is ¹⁶O-enriched (Δ¹⁷O = −10‰ to −6‰) relative to melilite (Δ¹⁷O = −5‰ to −3‰), meaning that the melilite and anorthite must have exchanged its oxygen subsequent to secondary alteration. This isotopic exchange in melilite and anorthite likely occurred on the CV parent asteroid, possibly during fluid-assisted thermal metamorphism.  相似文献   

Footprint prediction of scalar fluxes from analytical solutions of the diffusion equation   总被引：19，自引：3，他引：16  

P. H. Schuepp  M. Y. Leclerc  J. I. MacPherson  R. L. Desjardins 《Boundary-Layer Meteorology》1990,50(1-4):355-373

The use of analytical solutions of the diffusion equation for footprint prediction is explored. Quantitative information about the footprint, i.e., the upwind area most likely to affect a downwind flux measurement at a given height z, is essential when flux measurements from different platforms, particularly airborne ones, are compared. Analytical predictions are evaluated against numerical Lagrangian trajectory simulations which are detailed in a companion paper (Leclerc and Thurtell, 1990). For neutral stability, the structurally simple solutions proposed by Gash (1986) are shown to be capable of satisfactory approximation to numerical simulations over a wide range of heights, zero displacements and roughness lengths. Until more sophisticated practical solutions become available, it is suggested that apparent limitations in the validity of some assumptions underlying the Gash solutions for the case of very large surface roughness (forests) and tentative application of the solutions to cases of small thermal instability be dealt with by semi-empirical adjustment of the ratio of horizontal wind to friction velocity. An upper limit of validity of these solutions for z has yet to be established.  相似文献   

Accretionary rims on inclusions in the Allende meteorite     

Glenn J. MacPherson  Akihiko Hashimoto  Lawrence Grossman 《Geochimica et cosmochimica acta》1985,49(11):2267-2279

Many inclusions in Allende, particularly those with irregular shapes, are surrounded by a sequence of thin layers which differ from one another in texture, mineralogy and mineral-chemistry. The layer underlying all others contains either: IA, pyroxene needles + olivine + clumps of hedenbergite and andradite; IB, olivine doughnuts; or IC, rectangular olivine crystals. The next layer outward, II, contains tiny (<5 μm) olivine plates and Layer III large (5–10 μm) olivine laths. The final layer, IV, occurs as clumps of andradite + hedenbergite surrounded by magnesium-rich pyroxene needles. It separates Layer III from the Allende matrix which is more poorly sorted and more sulfide-rich than Layer III. Nepheline and iron sulfide are common constituents of most layers, the latter being particularly fine-grained and abundant in Layer II. Although not every layer is present on every inclusion, the sequence of layers is constant. Evidence that the rims are accretionary aggregates includes the presence of highly disequilibrium mineral assemblages and the fact that they are highly porous masses consisting of many euhedral crystals with few intergrowths. In addition, the layers are thickest in topographic hollows on the surfaces of inclusions and the inner layers are absent or discontinuous beyond such irregularities, suggesting that the probability of accretion of crystals was low initially, except in pockets, and became greater later, after a soft cushion of accreted condensate crystals had already formed. Separation of assemblages of different mineralogy, mineral-chemistry and texture into different rim layers seems best explained by nebular models in which long, slow cooling histories allow differentiation during condensation by grain/gas separation processes.  相似文献   

Refractory inclusions in the Murchison meteorite     

Glenn J. MacPherson  Miryam Bar-Matthews  Tsuyoshi Tanaka  Edward Olsen 《Geochimica et cosmochimica acta》1983,47(4):823-839

Mineralogical and petrographic studies of a wide variety of refractory objects from the Murchison C2 chondrite have revealed for the first time melilite-rich and feldspathoid-bearing inclusions in this meteorite, but none of these is identical to any inclusion yet found in Allende. Blue spinel-hibonite spherules have textures indicating that they were once molten, and thus their SiO₂-poor bulk composition requires that they were exposed to higher temperatures (>1550°C) than those deduced so far from any Allende inclusion. Melilite-rich inclusions are similar to Allende compact Type A's, but are more Al-, Ti-rich. One inclusion (MUCH-1) consists of a delicate radial aggregate of hibonite crystals surrounded by alteration products, and probably originated by direct condensation of hibonite from the solar nebular vapor. The sinuous, nodular and layered structures of another group of inclusions, spinel-pyroxene aggregates, suggest that these also originated by direct condensation from the solar nebular gas. Each type of inclusion is characterized by a different suite of alteration products and/or rim layers from all the other types, indicating modification of the inclusions in a wide range of different physico-chemical environments after their primary crystallization. All of these inclusions contain some iron-free rim phases. These could not have formed by reaction of the inclusions with fluids in the Murchison parent body because the latter would presumably have been very rich in oxidized iron. Other rim phases and alteration products could have formed at relatively low temperatures in the parent body, but some inclusions were not in the locations in which they were discovered when this took place. Some of these inclusions are too fragile to have been transported from one region to another in the parent body, indicating that low temperature alteration of these may have occurred in the solar nebula.  相似文献   

The impact of geographical indication on the revitalisation of a regional economy: a case study of 'Boseong' green tea   总被引：1，自引：0，他引：1  

Jeongwook Suh  Alan MacPherson 《Area》2007,39(4):518-527

Geographical indications are legal signs which identify a good as originating in a specific country or region, where the reputation of the product is attributable to its geographical roots. South Korea has operated with a geographical indication system since 1999. This research analyses the regional impacts of geographical indications using the case study of 'Boseong' green tea. The results show that geographical indication has enhanced the image of the product, leading to increased production and the stimulation of tea-related industries. We argue that geographical indication can be used as an effective policy to cope with trade liberalisation.  相似文献   

Formation conditions of aluminum-rich chondrules     

Elodie J. Tronche  Glenn J. MacPherson 《Geochimica et cosmochimica acta》2007,71(13):3361-3381

We have studied the formation conditions of Al-rich chondrules by doing isothermal and dynamic crystallization experiments at one atmosphere on four different chondrule analogue compositions within the pure CaO-MgO-Al₂O₃-SiO₂ system. For the dynamic crystallization experiments, we cooled from both liquidus and subliquidus peak temperatures (T_max), at cooling rates from 5-1000 °C/h. The starting compositions include two with anorthite and two with forsterite as the dominant liquidus phases, all at or near spinel-saturation. One of each pair evolves towards diopside crystallization, and the others cordierite or enstatite crystallization, giving a total of four completely different crystallization sequences analogous to the four basic varieties of Al-rich chondrule recently proposed. Bulk composition is the main controlling factor, both in terms of mineralogy and texture. The textures of the anorthite-rich compositions are more sensitive to T_max than they are to cooling rate, whereas the textures of the forsterite-rich compositions are more sensitive to cooling rate. Comparisons of natural Al-rich chondrules having similar compositions to our synthetic analogues indicate that the natural objects reflect a range of peak heating temperatures, ∼1400-1500 °C, and cooling rates of 10-500 °C/h for porphyritic chondrules and possibly higher (1000 °C/h) for barred chondrules. These conditions are consistent with the conditions inferred for ferromagnesian chondrules but differ from those inferred for some calcium-aluminum-rich inclusions.  相似文献   

A once-molten,coarse-grained,Ca-rich inclusion in Allende     

Glenn J. MacPherson  Lawrence Grossman 《Earth and Planetary Science Letters》1981,52(1):16-24

A compact, spheroidal Type B inclusion in Allende contains melilite laths that project radially inward from the inclusion edge which show interference growth textures. The combined textural and chemical features of this object cannot be explained by independent vapor-solid condensation of grains in space, followed by random aggregation of these grains into an inclusion. Rather, it probably formed from a once-molten droplet that crystallized in response to radiative cooling from its outer surface. The crystallization sequence in this and another similar inclusion in which oxygen isotopes have been measured is: melilite-spinel-anorthite-fassaite. This sequence supports the idea that oxygen isotopic heterogeneities in coarse-grained inclusions were formed after complete solidification of these objects by partial exchange with a less¹⁶O-rich gas, and not during or before a melting event.  相似文献   

Electron microprobe study of a ‘mysterite’-bearing inclusion from the Krymka LL-chondrite     

Lawrence Grossman  John M. Allen  Glenn J. MacPherson 《Geochimica et cosmochimica acta》1980,44(2):211-216

The black inclusion from the Krymka LL3 chondrite previously found to contain ‘mysterite’ by Lewiset al. (1979) belongs to a hitherto unknown class of carbonaceous chondrites. Its olivine and pyroxene compositions. Fo 97–99 and En 96, respectively, are characteristic of carbonaceous chondrites and its plagioclase composition. An 100, is characteristic of C3's. It contains a peculiar group of Co-, Cr-rich metal grains whose compositions are similar, but not identical, to those in C2 chondrites and which also bear some similarities to those in Renazzo. Its weight ratios of total $\text{Fe}\text{SiO}{}_2$ and $\text{solSiO}{}_2\text{MgO}$ are 0.74 and 1.43, respectively, and its atomic ratio of $\text{Si}\text{Al}$ is 10.7, exactly the same as in carbonaceous chondrites. Its bulk chemical composition is very close to that of the Murchison C2 chondrite. The association of mysterite with a special type of carbonaceous chondrite material suggests that mysterite formed by low-temperature condensation in a different region of the nebula from other carbonaceous chondrites.  相似文献   

Turbulence above Lake Ontario: Velocity and scalar statistics     

G. A. McBean  J. I. MacPherson 《Boundary-Layer Meteorology》1976,10(2):181-197

Measurements of the fluctuations of wind, temperature and humidity were made with an instrumented aircraft at altitudes from 30 to 300m above Lake Ontario. The variations of the standard deviations of these fluctuations are examined. By applying Monin-Obukhov similarity theory based on local fluxes, it is shown that the vertical velocity, temperature and humidity fluctuations scale with the local Monin-Obukhov length. In the limit of free convection, 1/3 and –1/3 power laws are approached with constants of 1.2, 1.2, and 0.8 for vertical velocity, temperature and humidity, respectively. The von Karman scale lengths increase with height but were much larger than those found by Taylor et al. (1970).  相似文献   

Non-linear motions of Australian geodetic stations induced by non-tidal ocean loading and the passage of tropical cyclones     

A. Mémin  C. Watson  I. D. Haigh  L. MacPherson  P. Tregoning 《Journal of Geodesy》2014,88(10):927-940

We investigate daily and sub-daily non-tidal oceanic and atmospheric loading (NTOAL) in the Australian region and put an upper bound on potential site motion examining the effects of tropical cyclone Yasi that crossed the Australian coast in January/February 2011. The dynamic nature of the ocean is important, particularly for northern Australia where the long-term scatter due to daily and sub-daily oceanic changes increases by 20–55 % compared to that estimated using the inverted barometer (IB) assumption. Correcting the daily Global Positioning System (GPS) time series for NTOAL employing either a dynamic ocean model or the IB assumption leads to a reduction of up to 52 % in the weighted scatter of daily coordinate estimates. Differences between the approaches are obscured by seasonal variations in the GPS precision along the northern coast. Two compensating signals during the cyclone require modelling at high spatial and temporal resolution: uplift induced by the atmospheric depression, and subsidence induced by storm surge. The latter dominates ( \(>\) 135 %) the combined net effect that reaches a maximum of 14 mm, and 10 mm near the closest GPS site TOW2. Here, 96 % of the displacement is reached within 15 h due to the rapid transit of cyclones and the quasi-linear nature of the coastline. Consequently, estimating sub-daily NTOAL is necessary to properly account for such a signal that can be 3.5 times larger than its daily-averaged value. We were unable to detect the deformation signal in 2-hourly GPS processing and show that seasonal noise in the Austral summer dominates and precludes GPS detection of the cyclone-related subsidence.  相似文献