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1.
Olga Hadz̆ija Mladen Jurac̆ić Marija Luić Maja Tonković Biserka Jeric̆ević 《Estuarine, Coastal and Shelf Science》1985,21(5):701-709
The investigation of mineral, granulometric and chemical composition of sediments of the River Krka estuary (Yugoslavia) were performed in order to elucidate the origin of the sediments and the pattern of sedimentation. Estuarine surface sediments were found to be fine-grained with a bimodal distribution. Environmental conditions in estuarine sediments favour conservation of the organic matter (anoxic conditions). The carbohydrates in the sediments were investigated to determine whether they are of terrigenous or authigenous origin. Glucose, galactose, mannose, xylose, rhamnose, glucosamine and glucuronic acid were detected in the sediments. Their mutual relationship indicates a preferentially terrigenous source of sedimented organic material in estuarine sediments. 相似文献
2.
Heavy metals distribution in agricultural topsoils in urban area 总被引：24，自引：0，他引：24
Intensive urbanisation of the Croatian capital of Zagreb has led to a situation where very good agricultural soils, developed mostly on Pleistocene eolian sediments and alluvial and proluvian Holocene sediments are entrapped within urban and suburban areas. Therefore the influence of urban and industrialised environments on the accumulation of metals in agricultural topsoils has been investigated. On an area of 860 km2 of the wider Zagreb region, 331 samples were taken according to a regular 1ǵ km square mesh. Samples were dissolved in aqua regia and analysed for Cd, Cu, Fe, Mn, Ni, Pb and Zn with flame atomic aqua regia absorption spectroscopy. The following concentration ranges have been determined: Cd 0.25-3.85 mg kg-1 (average 0.66 mg kg-1), Cu 4.30-183 mg kg-1 (average 20.8 mg kg-1), Fe 5.8-51.8 g kg-1 (average 27 g kg-1), Mn 79.2-1282 mg kg-1 (average 613 mg kg-1), Ni 0.70-282 mg kg-1 (average 49.5 mg kg-1), Pb 1.50-139 mg kg-1 (average 25.9 mg kg-1), and Zn 15.2-277 mg kg-1 (average 77.9 mg kg-1). Visualisation of the spatial data is made by the aid of GIS, and selected maps of the heavy metal concentrations in topsoils are displayed. Statistical multivariate analysis was carried out for quantitative study and data were processed by means of R-mode factor analysis, applying the varimax-raw rotational technique. F1, which grouped Cd, Pb, Cu, Zn and partially Ni, is characterized as a factor with strongly scattered anthropogenic influence. The elements in F2, Fe, Mn and partially Ni are mainly of geogenic, i.e. pedogenic, origin. The variations in concentrations of the investigated elements are thus of both natural and anthropogenic origins. The variations in the main soil constituents, particularly Fe and Mn, are determined primarily by the composition of different regolithic substrates of the fluvial origin in recent pedogenesis. High concentrations of nickel are also related to morphogenetic characteristics of the wider region, primarily basic and ultrabasic magmatic rocks of the surrounding mountain range. It is, however, assumed that the anomalous nickel concentrations in the vicinity of the highway and the airport are of anthropogenic origin, i.e. caused by fuel combustion. Copper is characterized by strongly scattered anthropogenic influence, which is related particularly to uncontrolled solid waste disposals or discharges of liquid waste from households or agricultural enterprises. With Zn, Pb and Cd, there are two possible ways of diffuse pollution. The Sava River, which drains the area and feeds the abundant Quaternary aquifer spreading below the major part of the investigated agricultural areas, has been exposed to intensive pollution by mining, industry and cities in the recent history. The part of the area with the highest determined concentrations of Zn, Pb and Cd was repeatedly flooded as recently as the previous decade; therefore, the recent sedimentation of the river deposits exposed to pollution is a very probable cause of the accumulation of metals in this until recently inundation area. The other way is atmospheric deposition of particles from urban sources (industrial emission, traffic, waste disposals, heating plants, etc.). In addition to agricultural enterprises, several economically important, but ecologically risky, facilities are situated in the vicinity of the water-protection area. The area is intersected by a very busy ring road, while a marshalling yard, the city dump, pharmaceutical and chemical industry, the district-heating plant and the airport are all located in close proximity. The geochemical maps show a clear relationship between human activities and metal concentration gradients. 相似文献
3.
Donald C. Thornton Alan R. Bandy Robert G. Ridgeway Arthur R. Driedger III Marija Lalevic 《Journal of Atmospheric Chemistry》1990,11(4):299-308
Stable isotopic dilution was applied to the determination of dimethyl sulfide (DMS) in ambient air at the low part-per-trillion by volume (pptrv) levels. Perdeuterated DMS was used as an internal standard in the gas chromatography/mass spectrometry determination. The isotopically labelled internal standard provided insensitivity to possible losses of DMS in sampling and analysis. The lower limit of detection (LLD) was 1 pptrv with a sample acquisition time of 2 min. 相似文献
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Aquatic dance flies (Empididae; Clinocerinae and Hemerodromiinae) are important components of freshwater assemblages, especially in running waters. They are predators as larvae and adults and thus essential for understanding aquatic food webs. This study was conducted in Plitvice lakes National Park (Croatia) representing a wide variety of freshwater habitats (springs, streams, lakes and tufa barriers). Adults were collected monthly from March 2007 until March 2009 using pyramid-type emergence traps at 13 locations. A total of 3865 specimens comprising 18 species were collected. The dominant genus was Chelifera, while the most abundant species was Hemerodromia unilineata. All species were univoltine except Chelifera precabunda, Chelifera pyrenaica and Chelifera stigmatica that were bivoltine. Considerable differences in composition and structure of aquatic dance flies assemblages were recorded along a longitudinal gradient of studied sites, primarily related to differences in physical and chemical parameters of water. Water temperature was the main factor influencing the timing of emergence. Hemerodromia species preferred variable water temperature throughout the year while the majority of the Chelifera species preferred stable water temperature characteristic of spring sites. Furthermore, discharge affected assemblage composition of aquatic dance flies. The highest abundance of aquatic dance flies was recorded in lotic habitats with fast water current over substrates of moss, gravel and particulate tufa with detritus. These results give a new insight on microhabitat preference and their distribution on unique karstic habitats. 相似文献
6.
Jelena Pantić Vladimir Urbanovich Vesna Poharc-Logar Bojan Jokić Marija Stojmenović Aleksandar Kremenović Branko Matović 《Physics and Chemistry of Minerals》2014,41(10):775-782
Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibro-milling for homogenization and activation of precursors. During the high-pressure and high-temperature synthesis (HPS) process at 4 GPa and 1,200 °C, sphene undergoes into phase transition, from room-temperature phase P21 /a to high-temperature phase A2/a. Evidence of that structural phase transition is given in this paper using infrared, Raman spectroscopy and X-ray powder diffraction. Rietveld refinement was employed to get the structural information of the synthesized powder. The most important structural change due to phase transition, the disappearance of the characteristic out-of-center distortion of the Ti atom and moving to the center of octahedra, was confirmed. HPS is an effective method for producing full-dense ceramics without any additives. Reduction of particle size occurred during high-pressure compaction. Microstructure and particle size of both phases were analyzed by scanning electron microscopy. 相似文献
7.
da Silveira Lucas Cardoso de Oliveira Amauri Pereira Sánchez Maciel Piñero Codato Georgia Ferreira Maurício Jonas Marques Filho Edson Pereira Božnar Marija Zlata Mlakar Primož 《Boundary-Layer Meteorology》2022,185(2):161-195
Boundary-Layer Meteorology - Statistical properties of turbulence, specifically variances of velocity components, temperature, water vapor, and carbon dioxide densities, are observationally... 相似文献
8.
Igor Bogunovic Darija Bilandzija Zeljko Andabaka Domagoj Stupic Jesús Rodrigo Comino Marija Cacic Luka Brezinscak Edi Maletic Paulo Pereira 《Arabian Journal of Geosciences》2017,10(15):340
The use of machinery in vineyards is increasing soil compaction and erosion. However, there is a lack of information about the impacts of different management practices on soil conditions of vineyards. Therefore, the aim of this study was to assess soil compaction in Croatian vineyards under four different management systems: no-tillage (NT) system, conventional tillage (CT), yearly inversed grass covered (INV-GC) and tillage managed (INV-T) treatments. Four key top-soil (0–20 cm) parameters were assessed in the different land uses: bulk density (BD), penetration resistance (PR), soil water content (SWC) and carbon dioxide (CO2) fluxes. Tractor traffic increased the BD and PR in all treatments, with exception of CT treatment, as consequence of tillage. SWC showed higher values in INV-GC treatment during the dry period; meanwhile, it was similar during the wet season in every management type. Lower CO2 fluxes were found in INV-GC and NT than in the CT and INV-T treatments. 相似文献
9.
da Silveira Lucas Cardoso de Oliveira Amauri Pereira Sánchez Maciel Piñero Codato Georgia Ferreira Maurício Jonas Filho Edson Pereira Marques Božnar Marija Zlata Mlakar Primož 《Boundary-Layer Meteorology》2022,185(2):197-197
Boundary-Layer Meteorology - 相似文献
10.
AbstractMeasurements made in the past few decades undeniably indicate change in the climate. The most visible sign of global climate change is air temperature, while less visible indicators include changes in river water temperatures. Changes in river temperature can significantly affect the environment, primarily the biosphere. The physical, biological and chemical characteristics of the river are directly affected by water temperature, although estimation of this relationship presents a complex problem. Although river temperature is influenced by hydrological and meteorological factors, the purpose of this study is to model daily water temperature using only one known parameter, mean air temperature. The relationship between the daily mean air and daily water temperature of the River Drava in Croatia is analysed using linear regression, stochastic modelling or nonlinear regression and multilayer perceptron (MLP) feed-forward neural networks. The results indicate that the MLP models are much better models which can be used for the estimation and prediction of daily mean river temperature.
Editor D. Koutsoyiannis; Associate editor M. Acreman 相似文献