Détermination indirecte des limites d'Atterberg par gravimétrie dynamique     

Chantal Proust  Agnès Jullien  Lydie Le Forestier 《Comptes Rendus Geoscience》2004,336(14):1233-1238

This study presents a new method for Atterberg limits measurements using dynamic drying. Indeed, for some polluted clays, or clay mixtures, classical methods cannot be used. The principle of liquid $(W_{\mathrm{L}})$ and plasticity $(W_{\mathrm{P}})$ limits determination by this method is presented. Experimental values for classical clays are close to those obtained with Casagrande's methods, allowing for larger physical mud characterisation. To cite this article: C. Proust et al., C. R. Geoscience 336 (2004).  相似文献   

Mesoscale SST–wind stress coupling in the Peru–Chile current system: Which mechanisms drive its seasonal variability?     

Vera Oerder  François Colas  Vincent Echevin  Sebastien Masson  Christophe Hourdin  Swen Jullien  Gurvan Madec  Florian Lemarié 《Climate Dynamics》2016,47(7-8):2309-2330

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Towards a link between the energetic heterogeneities of the edge faces of smectites and their stability in the context of metallic corrosion     

Murielle Perronnet  Frédéric Villiéras  Michel Jullien  Joël Raynal 《Geochimica et cosmochimica acta》2007,71(6):1463-1479

In the context of the potential confinement of high-level radioactive wastes (HLW) within the clay engineered barrier system (EBS) in deep geological formations, the evolution of the retention properties of smectite when interacting with Fe(0) needs to be assessed. If some potential natural analogues describing iron-clay reactivity are easily found, metallic iron-clay interactions are poorly described in studies regarding the Earth. Therefore, experimental investigations are needed. Several parameters influence Fe(0)-clay interactions, such as temperature, the interlayer composition of swelling clays, and the presence of octahedral Fe³⁺, etc. From a geometrical point of view, it is thought that clay destabilization is mainly controlled by phenomena starting at the edge faces of the particles. In the present work, the rates of the smectite-Fe(0) reaction at 80 °C were assessed by XRD, Mössbauer, and CEC analyses for three smectites. The investigations show marked differences in the degree of stability, which cannot be explained by the crystal-chemistry rules established in previous studies. Therefore, the Fe(0)-smectite interactions were studied in view of textural and energetic surface quantitative analyses. The studied smectites have equivalent nitrogen BET-specific surface areas, equivalent argon edge surface areas and slightly different basal surface areas. This similarity in particle shape indicates that the edge surface area cannot be accounted for when explaining the observed differences in reactivity. However, a correlation is obtained between smectite reactivity and the energetic heterogeneity of its edge faces. This is interpreted in terms of a multiplication of the number of sites on the edge faces, where the electron transfer between Fe(0) and the smectite structure can occur.  相似文献   

Contrasting conditions preceding MIS3 and MIS2 Heinrich events   总被引：2，自引：0，他引：2  

Elsa Jullien  Francis E. Grousset  Sidney R. Hemming  Victoria L. Peck  Ian R. Hall  Cdric Jeantet  Isabelle Billy 《Global and Planetary Change》2006,54(3-4):225-238

This paper presents an integrated multi-tracer study performed on piston cores recovered in the glacial ice-rafted detritus belt, stretching from Newfoundland to the Irish margin across the North Atlantic (40–55°N), in order to compare in detail the internal structure of each Heinrich event (HE). These tracers are IRD counts (quartz, dolomite, volcanic grains), their Nd isotopic composition and Ar–Ar datings of individual hornblende grains. A focus on the detailed structure of HE confirms that all intervals of massive sediment flux, specifically Heinrich layers HL1-to-5 (HLs), were dominated by North American, Laurentide ice-sheet surges from Hudson Strait, that are evident as far east as the Bay of Biscay (European margin). The sequences of events leading up to the HLs, however, present significant dissimilarities. One important difference is that HL2 and HL1 were preceded by “precursor events” (increases in the number of lithic grains per gram from non-Laurentide sediment sources). Sediment debris derived from near-simultaneous iceberg releases originating from the European ice-sheet are only detectable close to the European margin. In contrast there are no comparable precursor events before HL5 and HL4. This observation implies that precursor events are unlikely to be mechanistically linked to the triggering of HEs. The similarity of the HLs, against contrasting background conditions, is a significant observation that should add constraints to their origin.  相似文献   

The impact of African aridity on the isotopic signature of Atlantic deep waters across the Middle Pleistocene Transition     

Bruno Malaizé  Elsa Jullien  Amandine Tisserand  Charlotte Skonieczny  E. Francis Grousset  Frédérique Eynaud  Catherine Kissel  Jérôme Bonnin  Svenja Karstens  Philippe Martinez  Aloys Bory  Vivianne Bout-Roumazeilles  Thibaut Caley  Xavier Crosta  Karine Charlier  Linda Rossignol  José-Abel Flores  Ralph Schneider 《Quaternary Research》2012,77(1):182-191

A high resolution analysis of benthic foraminifera as well as of aeolian terrigenous proxies extracted from a 37 m-long marine core located off the Mauritanian margin spanning the last ~ 1.2 Ma, documents the possible link between major continental environmental changes with a shift in the isotopic signature of deep waters around 1.0–0.9 Ma, within the so-called Mid-Pleistocene Transition (MPT) time period. The increase in the oxygen isotopic composition of deep waters, as seen through the benthic foraminifera δ¹⁸O values, is consistent with the growth of larger ice sheets known to have occurred during this transition. Deep-water mass δ¹³C changes, also estimated from benthic foraminifera, show a strong depletion for the same time interval. This drastic change in δ¹³C values is concomitant with a worldwide 0.3‰ decrease observed in the major deep oceanic waters for the MPT time period. The phase relationship between aeolian terrigeneous signal increase and this δ¹³C decrease in our record, as well as in other paleorecords, supports the hypothesis of a global aridification amongst others processes to explain the deep-water masses isotopic signature changes during the MPT. In any case, the isotopic shifts imply major changes in the end-member δ¹⁸O and δ¹³C values of deep waters.  相似文献   

Aqueous Phase Reaction of HNO4: The Impact on Tropospheric Chemistry     

Frank Dentener  Jason Williams  Swen Metzger 《Journal of Atmospheric Chemistry》2002,41(2):109-133

We use a global atmospheric chemistry transport model to study the possible influence of aqueous phase reactions of peroxynitric acid (HNO₄) on the concentrations and budgets of NO_x, SO_x, O₃ and H₂O₂. Laboratory studies have shown that the aqueous reaction of HNO_4aq withHSO^– _3aq, and the uni-molecular decomposition of the NO₄ ^– anion to form NO₂ ^– (nitrite) occur on a time scale of about a second. Despite a substantial contribution of the reaction of HSO^– _3aq with HNO_4aq to the overall in-cloud conversion of SO₂ to SO₄ ^2–, a simultaneous decrease of other oxidants (most notably H₂O₂) more than compensated the increase in SO₄ ^2– production. The strongest influence of heterogeneous HNO₄ chemistry was found in the boundary layer, where calculated monthly average ozone concentrations were reduced between 2% to 10% andchanges of H₂O₂ between –20% to +10%compared to a simulation which ignores this reaction. Furthermore, SO₂ was increased by 10% to 20% and SO₄ ^2–depleted by up to 10%. Since the resolution of our global model does not enable a detailed comparison with measurements in polluted regions, it is not possible to verify whether considering heterogeneous HNO₄ reactions results in a substantial improvement of atmospheric chemistry transport models. However, the conversion of HNO₄ in the aqueous phase seems to be efficient enough to warrant further laboratory investigations and more detailed model studies on this topic.  相似文献   

Low-latitude “dusty events” vs. high-latitude “icy Heinrich events”     

Elsa Jullien  Francis Grousset  Bruno Malaiz  Josette Duprat  Maria Fernanda Sanchez-Goni  Frdrique Eynaud  Karine Charlier  Ralph Schneider  Aloys Bory  Viviane Bout  Jose Abel Flores 《Quaternary Research》2007,68(3):379-386

It has been proposed that tropical events could have participated in the triggering of the classic, high-latitude, iceberg-discharge Heinrich events (HE). We explore low-latitude Heinrich events equivalents at high resolution, in a piston core recovered from the tropical north-western African margin. They are characterized by an increase of total dust, lacustrine diatoms and fibrous lacustrine clay minerals. Thus, low-latitude events clearly reflect severe aridity events that occurred over Africa at the Saharan latitudes, probably induced by southward shifts of the Inter Tropical Convergence Zone. At a first approximation, it seems that there is more likely synchronicity between the high-latitude Heinrich Events (HEs) and low-latitude events (LLE), rather than asynchronous behaviours.  相似文献   

A general modelling of expansive and non-expansive clays     

J. C. Robinet  M. Pakzad  A. Jullien  F. Plas 《国际地质力学数值与分析法杂志》1999,23(12):1319-1335

This paper presents an elastoplastic model for saturated expansive and non-expansive clays. The original feature of this model is that a plastic mechanism is introduced during unloading to take into account the irreversible swelling of the macroporosities. These strains are induced by the repulsive stresses which are unbalanced at the scale of the microporosities. Thus two yield surfaces are activated: a classical contact yield surface (F_C) similar to an associated modified Cam-clay approach and a swelling yield surface (F_R−A) based on the non-associated plasticity. The formulation considers that for the normally consolidated stress states, the strains are mainly produced by an increase of the contact stresses. For the overconsolidated stress states, the repulsive stresses balance the external stresses. The rheological parameters are easily determined from the results of either triaxial or oedometer tests. The model is then used in a finite element program, using the classical concepts of plasticity, especially for the loading–unloading criterion based on the sign of the plasticity multiplier. Simulations of the convergence of a gallery (under an earth retaining structure) sunk at great depth in Boom clay are presented. The results are compared with those obtained with the Cam-clay model. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Spreadsheet Modeling of Slug Tests Using the van der Kamp Method     

Allan Wylie  Swen Magnuson 《Ground water》1995,33(2):326-329

Slug testing is frequently employed to calculate aquifer transmissivity and hydraulic conductivity. The van der Kamp technique for interpreting slug test data which experience force-free water level oscillations is not routinely employed because it requires adjusting equations to match the observed well response data. This adjustment can be rapid and convenient when a commercial spreadsheet is employed.  相似文献   

Ocean feedback to tropical cyclones: climatology and processes   总被引：1，自引：0，他引：1  

Swen Jullien  Patrick Marchesiello  Christophe E. Menkes  Jérôme Lefèvre  Nicolas C. Jourdain  Guillaume Samson  Matthieu Lengaigne 《Climate Dynamics》2014,43(9-10):2831-2854

This study presents the first multidecadal and coupled regional simulation of cyclonic activity in the South Pacific. The long-term integration of state-of the art models provides reliable statistics, missing in usual event studies, of air–sea coupling processes controlling tropical cyclone (TC) intensity. The coupling effect is analyzed through comparison of the coupled model with a companion forced experiment. Cyclogenesis patterns in the coupled model are closer to observations with reduced cyclogenesis in the Coral Sea. This provides novel evidence of air–sea coupling impacting not only intensity but also spatial cyclogenesis distribution. Storm-induced cooling and consequent negative feedback is stronger for regions of shallow mixed layers and thin or absent barrier layers as in the Coral Sea. The statistical effect of oceanic mesoscale eddies on TC intensity (crossing over them 20 % of the time) is also evidenced. Anticyclonic eddies provide an insulating effect against storm-induced upwelling and mixing and appear to reduce sea surface temperature (SST) cooling. Cyclonic eddies on the contrary tend to promote strong cooling, particularly through storm-induced upwelling. Air–sea coupling is shown to have a significant role on the intensification process but the sensitivity of TCs to SST cooling is nonlinear and generally lower than predicted by thermodynamic theories: about 15 rather than over 30 hPa °C^?1 and only for strong cooling. The reason is that the cooling effect is not instantaneous but accumulated over time within the TC inner-core. These results thus contradict the classical evaporation-wind feedback process as being essential to intensification and rather emphasize the role of macro-scale dynamics.  相似文献