Compositional variation in Hg-bearing sphalerite from the polymetallic Eskay Creek deposit, British Columbia, Canada   总被引：1，自引：0，他引：1  

Tassos A. Grammatikopoulos  Oleg Valeyev  Tina Roth 《Chemie der Erde / Geochemistry》2006,66(4):307-314

The Eskay Creek, British Columbia, Canada, is a polymetallic, gold- and silver-rich, volcanic-hosted, massive sulfide deposit. The ore in the deposit is divided into subzones distinguished by mineralogy, texture, grade and metallurgical characteristics. This study presents the results of a mineralogical examination of three composite field samples, with emphasis on the chemistry of sphalerite. Sphalerite is associated with variable amounts of Hg-tetrahedrite and cinnabar, and an array of sulfides, sulphosalts and non-opaque minerals. Electron micro probe analyses of sphalerite in the three composite samples reveal wide variations in compositions. The Hg content in sphalerite in the three samples varies between 0.08 and 16.35 wt%, whereas the Fe content ranges from 0.33 to 2.29 wt%. The chemical formula of the sphalerite shows the compositional range (Zn_0.89–0.98Hg_0.01–0.09.Fe_0.005–0.02)S. Sphalerite exhibits an almost perfect substitution of Hg and Zn, as shown by the negative covariance between them. Sphalerite with the highest Hg contents tends to have the lowest Fe concentrations. The highest Hg contents in sphalerite are recorded in the samples with the highest bulk Hg concentrations and with the highest cinnabar contents.

The compositional variations of sphalerite are important because they can be used in mapping ore forming fluids and indicate possible temporal variations. Second, determination of the compositional variation of the sphalerite in the mine has metallurgical implications because the mineral is an important Zn source. The mineralogical data indicate that non-physical processes (e.g. pyrometallurgy) must be used to separate Hg from Zn concentrates, with direct environmental implications, that is, release of metals, such as Hg, into the environment during mining and processing.  相似文献   

Lower crustal melting and the role of open-system processes in the genesis of syn-orogenic quartz diorite–granite–leucogranite associations: constraints from Sr–Nd–O isotopes from the Bandombaai Complex, Namibia     

Tina van de Flierdt  Stephan Hoernes  Stefan Jung  Peter Masberg  Edgar Hoffer  Urs Schaltegger  Hans Friedrichsen 《Lithos》2003,67(3-4):205-226

The Bandombaai Complex (southern Kaoko Belt, Namibia) consists of three main intrusive rock types including metaluminous hornblende- and sphene-bearing quartz diorites, allanite-bearing granodiorites and granites, and peraluminous garnet- and muscovite-bearing leucogranites. Intrusion of the quartz diorites is constrained by a U–Pb zircon age of 540±3 Ma.

Quartz diorites, granodiorites and granites display heterogeneous initial Nd- and O isotope compositions (_{Nd (540 Ma)}=−6.3 to −19.8; δ¹⁸O=9.0–11.6‰) but rather low and uniform initial Sr isotope compositions (⁸⁷Sr/⁸⁶Sr_initial=0.70794–0.70982). Two leucogranites and one aplite have higher initial ⁸⁷Sr/⁸⁶Sr ratios (0.70828–0.71559), but similar initial _Nd (−11.9 to −15.8) and oxygen isotope values (10.5–12.9‰). The geochemical and isotopic characteristics of the Bandombaai Complex are distinct from other granitoids of the Kaoko Belt and the Central Zone of the Damara orogen. Our study suggests that the quartz diorites of the Bandombaai Complex are generated by melting of heterogeneous mafic lower crust. Based on a comparison with results from amphibolite-dehydration melting experiments, a lower crustal garnet- and amphibole-bearing metabasalt, probably enriched in K₂O, is a likely source rock for the quartz diorites. The granodiorites/granites show low Rb/Sr (<0.6) ratios and are probably generated by partial melting of meta-igneous (intermediate) lower crustal sources by amphibole-dehydration melting. Most of the leucogranites display higher Rb/Sr ratios (>1) and are most likely generated by biotite-dehydration melting of heterogeneous felsic lower crust. All segments of the lower crust underwent partial melting during the Pan-African orogeny at a time (540 Ma) when the middle crust of the central Damara orogen also underwent high T, medium P regional metamorphism and melting. Geochemical and isotope data from the Bandombaai Complex suggest that the Pan-African orogeny in this part of the orogen was not a major crust-forming episode. Instead, even the most primitive rock types of the region, the quartz diorites, represent recycled lower crustal material.  相似文献   

Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration     

Tina Sanders  Andreas Schöl  Kirstin Dähnke 《Estuaries and Coasts》2018,41(1):128-138

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.  相似文献   

Deep-sea coral aragonite as a recorder for the neodymium isotopic composition of seawater     

Tina van de Flierdt  Laura F. Robinson 《Geochimica et cosmochimica acta》2010,74(21):6014-6032

Deep-sea corals have been shown to be useful archives of rapid changes in ocean chemistry during the last glacial cycle. Their aragonitic skeleton can be absolutely dated by U-Th data, freeing radiocarbon to be used as a water-mass proxy. For certain species of deep-sea corals, the growth rate allows time resolution that is comparable to ice cores. An additional proxy is needed to exploit this opportunity and turn radiocarbon data into rates of ocean overturning in the past.Neodymium isotopes in seawater can serve as a quasi-conservative water-mass tracer and initial results indicate that deep-sea corals may be reliable archives of seawater Nd isotopes. Here we present a systematic study exploring Nd isotopes as a water-mass proxy in deep-sea coral aragonite. We investigated five different genera of modern deep-sea corals (Caryophyllia, Desmophyllum, Enallopsamia, Flabellum, Lophelia), from global locations covering a large potential range of Nd isotopic compositions. Comparison with ambient seawater measurements yields excellent agreement and suggests that deep-sea corals are reliable archives for seawater Nd isotopes.A parallel study of Nd concentrations in these corals yields distribution coefficients for Nd between seawater and coral aragonite of 1-10, omitting one particular genus (Enallopsamia). The corals and seawater did however not come from exactly the same location, and further investigations are needed to reach robust conclusions on the incorporation of Nd into deep-sea coral aragonite.Lastly, we studied the viability of extracting the Nd isotope signal from fossil deep-sea corals by carrying out stepwise cleaning experiments. Our results show that physical removal of the ferromanganese coating and chemical pre-cleaning have the highest impact on Nd concentrations, but that oxidative/reductive cleaning is also needed to acquire a seawater Nd isotope signal.  相似文献   

Paleoenvironmental reconstruction of Holocene coastal sediments adjacent to archaeological ruins in Aqaba,Jordan     

Alivia J. Allison  Tina M. Niemi 《Geoarchaeology》2010,25(5):602-625

Stratified cultural remains from the Early Roman/Nabataean to Byzantine periods in the coastal zone of Aqaba, Jordan, and analyses of thirteen sediment cores provide evidence for changes in the depositional environment during the Holocene. The overall trend in subsurface sediments is a basal marine transgressive layer overlain by a regressional sequence of embayment lagoonal sediments identified from microfossil analyses, and backshore pond, alluvium, and eolian deposits until the 1st century B.C., when mudbrick structures appear. Based on two radiocarbon dates, a brackish water coastal embayment formed prior to ca. 5900–5700 B.C. and was subsequently filled by siltation. Local tectonic subsidence along faults of the Dead Sea transform may have helped form the lagoon. Freshwater Candona sp. ostracods found in sand layers in the lagoon facies show signs of having been transported and redeposited. These data indicate that lakes or marshes were likely located inland of the study area. Supporting faunal and floral evidence for wetter climatic conditions, wetland habitats, and extensive water diversion and agricultural terraces has been excavated at late Chalcolithic (4000–3500 B.C.) sites in the Aqaba region (Khalil & Schmidt, 2009 ). By the 8th century B.C., the depositional environment along the coastal plain of Aqaba was dominated by distal alluvial fan and eolian sedimentation and the shoreline had prograded about 400m seaward. The migration of human settlements since the 8th century B.C. from the center of the valley toward the southeast may be driven by the changing course of Wadi Yutim and conditions along the coastal plain. © 2010 Wiley Periodicals, Inc.  相似文献   

Comparison of seismic activity for Llaima and Villarrica volcanoes prior to and after the Maule 2010 earthquake     

Cindy Mora-Stock  Martin Thorwart  Tina Wunderlich  Stefan Bredemeyer  Thor H. Hansteen  Wolfgang Rabbel 《International Journal of Earth Sciences》2014,103(7):2015-2028

Llaima and Villarrica are two of the most active volcanoes in the Chilean Southern Volcanic Zone and presently show contrasting types of activity. Llaima is a closed vent edifice with fumarolic activity, while Villarrica has an open vent with a lava lake, continuous degassing and tremor activity. This study is focused on characterizing the relationships between volcanic and seismic activity in the months before and after the 2010 M8.8 Maule earthquake, which was located in NNW direction from the volcanoes. Time series for tremors, long-period and volcano-tectonic events were obtained from the catalogue of the Volcanic Observatory of the Southern Andes (OVDAS) and from the SFB 574 temporary volcanic network. An increase in the amount of tremor activity, long-period events and degassing rates was observed at Villarrica weeks before the mainshock and continued at a high level also after it. This increase in activity is interpreted to be caused by enhanced magma influx at depth and may be unrelated to the Maule event. In Llaima, an increase in the volcano-tectonic activity was observed directly after the earthquake. The simultaneous post-earthquake activity at both volcanoes is consistent with a structural adjustment response. Since this enhanced activity lasted for more than a year, we suggest that it is related to a medium-term change in the static stress. Thus, the Maule earthquake may have affected both volcanoes, but did not trigger eruptions, from which we assume that none of the volcanoes were in a critical state.  相似文献   

Active tectonic morphology and submarine deformation of the northern Gulf of Eilat/Aqaba from analyses of multibeam data   总被引：1，自引：0，他引：1  

Gideon Tibor  Tina M. Niemi  Zvi Ben-Avraham  Abdallah Al-Zoubi  Ronnie A. Sade  John K. Hall  Gal Hartman  Emad Akawi  Abdelrahmem Abueladas  Rami Al-Ruzouq 《Geo-Marine Letters》2010,30(6):561-573

A high-resolution marine geophysical study was conducted during October-November 2006 in the northern Gulf of Aqaba/Eilat, providing the first multibeam imaging of the seafloor across the entire gulf head spanning both Israeli and Jordanian territorial waters. Analyses of the seafloor morphology show that the gulf head can be subdivided into the Eilat and Aqaba subbasins separated by the north-south-trending Ayla high. The Aqaba submarine basin appears starved of sediment supply, apparently causing erosion and a landward retreat of the shelf edge. Along the eastern border of this subbasin, the shelf is largely absent and its margin is influenced by the Aqaba Fault zone that forms a steep slope partially covered by sedimentary fan deltas from the adjacent ephemeral drainages. The Eilat subbasin, west of the Ayla high, receives a large amount of sediment derived from the extensive drainage basins of the Arava Valley (Wadi ’Arabah) and Yutim River to the north–northeast. These sediments and those entering from canyons on the south-western border of this subbasin are transported to the deep basin by turbidity currents and gravity slides, forming the Arava submarine fan. Large detached blocks and collapsed walls of submarine canyons and the western gulf margin indicate that mass wasting may be triggered by seismic activity. Seafloor lineaments defined by slope gradient analyses suggest that the Eilat Canyon and the boundaries of the Ayla high align along north- to northwest-striking fault systems—the Evrona Fault zone to the west and the Ayla Fault zone to the east. The shelf–slope break that lies along the 100 m isobath in the Eilat subbasin, and shallower (70–80 m isobaths) in the Aqaba subbasin, is offset by approx. 150 m along the eastern edge of the Ayla high. This offset might be the result of horizontal and vertical movements along what we call the Ayla Fault on the east side of the structure. Remnants of two marine terraces at 100 m and approx. 150 m water depths line the southwest margin of the gulf. These terraces are truncated by faulting along their northern end. Fossil coral reefs, which have a similar morphological appearance to the present-day, basin margin reefs, crop out along these deeper submarine terraces and along the shelf–slope break. One fossil reef is exposed on the shelf across the Ayla high at about 60–63 m water depth but is either covered or eroded in the adjacent subbasins. The offshore extension of the Evrona Fault offsets a fossil reef along the shelf and extends south of the canyon to linear fractures on the deep basin floor.  相似文献   

ISO SWS Spectroscopy of Proto-Planetary Nebulae     

Bruce J. Hrivnak  Kevin Volk  Sun Kwok 《Astrophysics and Space Science》1997,255(1-2):477-478

We are obtaining low- (SWS01) and medium-resolution (SWS06) spectra of PPNe to investigate spectral features arising in these transitional objects. Three sources with the 21 μm feature have been confirmed, one new source found, and evidence of some substructure seen. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

400 Jahre Mathematik und Astronomie an der Universität Würzburg: Alma Julia Herbipolensis 1582–1982     

Otto Volk 《Celestial Mechanics and Dynamical Astronomy》1982,28(1-2):243-250

Ohne Zusammenfassung

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400 years mathematics and astronomy at the Wurzburg University: Alma Julia herbipolensis 1582–1982

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s. O. Volk, Mathematik, Astronomie und Physik in der Vergangenheit der Universität Würzburg, Festschrift 1982.

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Paper presented at the 1981 Oberwolfach Conference on Mathematical Methods in Celestial Mechanics.  相似文献   

Bemerkungen zur Geschichte der Himmelsmechanik     

O. Volk 《Celestial Mechanics and Dynamical Astronomy》1970,2(3):398-423

Ohne ZusammenfassungPaper presented at the Conference on Celestial Mechanics, Oberwolfach, Germany, Aug. 17–23, 1969.  相似文献