Degradation of lubricating oils by marine bacteria observed by quantitative mass spectrometry     

Yasushi Kawakami  Hajime Nishimura 《Journal of Oceanography》1981,37(1):1-7

Bacterial degradation of the hydrocarbons of lubricating oils was investigated by mass spectrometric analysis which gives both total amount and the composition of hydrocarbon types of residual oil. An unused lubricating oil, which mainly consisted of hydrocarbon types with only a small percentage ofn-alkanes, was degraded by marineBacillus sp. andPseudomonas sp. with 55 % and 25 % decreases in 10 days, respectively. Susceptibility of respective hydrocarbon types to biodegradation was in the following order: alkanes > non-condensed cycloalkanes, mono-aromatics > condensed cycloalkanes. A used lubricating oil of different brand showed a larger decrease than the unused oil. Both species of bacteria degraded large portions of alkane fraction of Arabian light crude oil.  相似文献   

Seasonal Variability of Near-Surface Heat Budget of Selected Oceanic Areas in the North Tropical Indian Ocean   总被引：1，自引：0，他引：1  

Chithra Shaji  Satoshi Iizuka  Tomonori Matsuura 《Journal of Oceanography》2003,59(1):87-103

The results obtained from an Ocean General Circulation Model (OGCM), the Modular Ocean Model 2.2, forced with the National Center for Environmental Prediction/National Center for Atmospheric Research reanalysis data, and observational data have been utilized to document the climatological seasonal cycle of the upper ocean response in the Tropical Indian Ocean. We address the various roles played by the net surface heat flux and the local and remote ocean dynamics for the seasonal variation of near-surface heat budget in the Tropical Indian Ocean. The investigation is based in seven selected boxes in the Arabian Sea, Bay of Bengal and the Equatorial Indian Ocean. The changes of basin-wide heat budget of ocean process in the Arabian Sea and the Western Equatorial Indian Ocean show an annual cycle, whereas those in the Bay of Bengal and the Eastern Equatorial Indian Ocean show a semi-annual cycle. The time tendency of heat budget in the Arabian Sea depends on both the net surface heat flux and ocean dynamics while on the other hand, that in the Bay of Bengal depends mainly on the net surface flux. However, it has been found that the changes of heat budget are very different between western and eastern regional sea areas in the Arabian Sea and the Bay of Bengal, respectively. This difference depends on seasonal variations of the different local wind forcing and the different ocean dynamics associated with ocean eddies and Kelvin and Rossby waves in each regional sea areas. We also discuss the comparison and the connection for the seasonal variation of near-surface heat budget among their regional sea areas. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Sulfide evolution in high-temperature to ultrahigh-temperature metamorphic rocks from Lützow–Holm Complex, East Antarctica     

T. Kawakami  D.J. Ellis  A.G. Christy 《Lithos》2006,92(3-4):431-446

The high-temperature (HT) to ultrahigh-temperature (UHT) metamorphic rocks from Lützow–Holm Complex, East Antarctica show a systematic difference between sulfide assemblages in the rock matrix and those found as inclusions in the silicates stable in high-temperatures. Matrix sulfides are commonly pyrite with or without pentlandite and chalcopyrite. On the other hand, inclusion sulfides are pyrrhotite with or without pentlandite and chalcopyrite lamellae. When recalculated into integrated single-phase sulfide compositions, inclusion sulfides from the UHT region showed a wider range of solid–solution composition than the inclusion sulfides from the HT region. The host minerals of the sulfides with extreme solid–solution compositions are those stable at the peak of metamorphism such as orthopyroxene and garnet. One of the most extreme ones is included in orthopyroxene coexisting with sillimanite ± quartz, which is the diagnostic mineral assemblage of UHT metamorphism. These observations suggest that sulfide inclusions preserve their peak metamorphic compositions. Pyrrhotite did not revert to pyrite because of the closed system behavior of sulfur in inclusion sulfides. On the other hand, in the rock matrix where the open system behavior of sulfur is permitted, original sulfides were partly to completely altered by the later fluid activity.  相似文献   

Large-scale penetration test using a drop hammer     

S. Okubo  K. Fukui  J. Kawakami 《Rock Mechanics and Rock Engineering》1997,30(2):113-118

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Oxygen isotope speedometry in granulite facies garnet recording fluid/melt–rock interaction (Sør Rondane Mountains,East Antarctica)     

Fumiko Higashino  Daniela Rubatto  Tetsuo Kawakami  Anne‐Sophie Bouvier  Lukas P. Baumgartner 《Journal of Metamorphic Geology》2019,37(7):1037-1048

In situ analysis of a garnet porphyroblast from a granulite facies gneiss from Sør Rondane Mountains, East Antarctica, reveals discontinuous step‐wise zoning in phosphorus and large δ¹⁸O variations from the phosphorus‐rich core to the phosphorus‐poor rim. The gradually decreasing profile of oxygen isotope from the core (δ¹⁸O = ~15‰) to the rim (δ¹⁸O = ~11‰) suggests that the ¹⁸O/¹⁶O zoning was originally step‐wise, and modified by diffusion after the garnet rim formation at ~800°C and 0.8 GPa. Fitting of the ¹⁸O/¹⁶O data to the diffusion equation constrains a duration of the high‐T event (~800°C) to c. 0.5–40 Ma after the garnet rim formation. The low δ¹⁸O value of the garnet rim, together with the previously reported low δ¹⁸O values in metacarbonates, indicates regional infiltration, probably along a detachment fault, of low δ¹⁸O fluid/melt possibly derived from meta‐mafic to ultramafic rocks.  相似文献   

Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific     

Yoshihisa?MinoEmail author  Chiho?Sukigara  Makio?C.?Honda  Hajime?Kawakami  Kazuhiko?Matsumoto  Masahide?Wakita  Minoru?Kitamura  Tetsuichi?Fujiki  Kosei?Sasaoka  Osamu?Abe  Jan?Kaiser  Toshiro?Saino 《Journal of Oceanography》2016,72(6):819-836

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.  相似文献   

A simple model to estimate monthly forest evapotranspiration in Japan from monthly temperature     

Hikaru Komatsu  Tomonori Kume  Kyoichi Otsuki 《水文研究》2010,24(13):1896-1911

The estimation of evapotranspiration (E) in forested areas is required for various practical purposes (e.g. evaluation of drought risks) in Japan. This study developed a model that estimates monthly forest E in Japan with the input of monthly temperature (T). The model is based on the assumptions that E equals the equilibrium evaporation rate (E_eq) and that E_eq is approximated by a function of T. The model formulates E as E (mm month⁻¹) = 3·48 T ( °C) + 32·3. The accuracy of the model was examined using monthly E data derived using short‐term water balance (WB) and micrometeorological (M) methods for 15 forest sites in Japan. The model estimated monthly E more accurately than did the Thornthwaite and Hamon equations according to regression analysis of the estimated E and E derived using the WB and M methods. Although the model tended to overestimate monthly E, the overestimation could be reduced by considering the effect of precipitation on E. As T data are commonly available all over Japan, the model would be a useful tool to estimate forest E in Japan. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Space-time distribution patterns of destructive earthquakes in the inner belt of central Japan: Activity intervals and locations of earthquakes     

Yuji Kanaori  Shin-ichi Kawakami  Kenji Yairi 《Engineering Geology》1991,31(3-4):209-230

Based on a block structure model of the inner belt of central Japan, an examination was conducted of the space-time distribution patterns of destructiv magnitudes M 6.4 or greater (M =Japan Meteorological Agency Scale). The distribution patterns revealed a periodicity in earthquake activit seismic gaps. Major NW—SE trending left-lateral active faults divide the inner belt of central Japan into four blocks, 20–80 km wide. The occurrenc A.D. with M ≥ 6.4, which have caused significant damage, were documented in the inner belt of central Japan. The epicenters of these earthquakes close to the block boundaries.

Using the relationship between the magnitude of earthquakes which occurred in the Japanese Islands and the active length of faults that generated them, movement is calculated for each historical earthquake. Space—time distributions of earthquakes were obtained from the calculated lengths, the latitud of generation. When an active period begins, a portion or segment of the block boundary creates an earthquake, which in turn appears on the ground surf active period ends when the block boundary generates earthquakes over the entire length of the block boundary without overlapping.

Five seismic gaps with fault lengths of 20 km or longer can be found in the inner belt of central Japan. It is predicted that the gaps will generate ea magnitudes of 7.0. These data are of significance for estimating a regional earthquake risk over central Japan in the design of large earthquake resist

The time sequences of earthquakes on the block boundaries reveal a similar tendency, with alternating active periods with seismic activity and quiet pe activity. The inner belt of central Japan is now in the last stage of an active period. The next active period is predicted to occur around 2500 A.D.  相似文献   

Natural and anthropogenic aquatic environmental changes reconstructed by paleolimnological analyses in Lake Kitaura,central Japan     

Tomonori Naya  Yoshihiro Tanimura  Yutaka Kanai  Fujio Kumon  Kazuo Amano 《Journal of Paleolimnology》2007,37(4):547-563

In order to assess the recent anthropogenic environmental changes in Lake Kitaura, central Japan, changes during the past few centuries were reconstructed from results of radiometric and tephrochlonological age determination, magnetic susceptibility measurements, total organic carbon analyses, total nitrogen analyses and fossil diatom analyses on a sediment core from the lake. A total of six major and sub-zones are recognized according to the diatom fossil assemblages, and we discuss aquatic environmental change in Lake Kitaura mainly based on these diatom assemblage change. Zone Ia and Zone Ib (older than AD 1707) are marine to brackish. In Zone IIa (AD␣1707–AD 1836), most of the brackish diatoms disappeared, and were replaced by freshwater species indicating a decrease in salinity. We interpret the salinity decrease in Zone I–IIa as a sea-level fall during the Little Ice Age. The salinity of the lake decreased to near freshwater conditions in Zone IIb (AD 1836–AD 1970), which could arise from alteration in River Tone or development of a sandspit in the mouth of River Tone in addition to sea-level change. In Zone IIIa (AD 1970–AD 1987), the diatom assemblage indicates a freshwater environment, and sedimentation rates increase rapidly. These changes reflect sedimentary environment change and an ecosystem transition due to the construction of the tide gate. In Zone IIIb (AD 1987–AD 2002), the diatom flux (valves cm⁻² y⁻¹) increased and species composition changed. The changes in Zone IIIb show a good agreement with limnological monitoring data gathered from the lake. These paleolimnological data suggest that the recent human-induced changes of the aquatic environment of the lake after the 1970s exceed rates during the period concerned in this study.  相似文献   

Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders     

Sanae Koizumi  Takehiko Hiraga  Chihiro Tachibana  Miki Tasaka  Tomonori Miyazaki  Tamio Kobayashi  Asako Takamasa  Naoki Ohashi  Satoru Sano 《Physics and Chemistry of Minerals》2010,37(8):505-518

Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside. Nano-sized powders of colloidal SiO₂ and highly dispersed Mg(OH)₂ with particle size of ≤50 nm are used as chemical sources for MgO and SiO₂, which are common components for all of the aggregates. These powders are mixed with powders of CaCO₃, MgAl₂O_4, and Fe(CO₂CH₃)₂ to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral composites with grain size of 0.3–1.1 μm are successfully synthesized with this method.  相似文献