Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

南海北缘北东东向构造活动性研究     

任镇寰  任奔滔  罗振暖  陈益明  钟贻军 《大地测量与地球动力学》1996,(2)

从地形地貌特征、重磁地球物理场、深部构造与断裂构造以及地震活动、震源机制等多方面论述北东东向构造是南海北缘的主要活动构造。对于长期以来认为新华夏系北东向构造是该区主要活动构造的观点来说，这是一种新的学术思想。  相似文献   

Search For Correlations Between Batse Gamma-Ray Bursts and Supernovae     

JiřÍ Polcar  Martin Topinka  Graziella Pizzichini  Eliana Palazzi  Nicola Masetti  RenÉ Hudec  Věra HudcovÁ 《Astrophysics and Space Science》2005,296(1-4):485-488

We report on our statistical research of space–time correlated supernovae and CGRO-BATSE gamma-ray bursts (GRBs). There exists a significantly higher abundance of core-collapse supernovae among the correlated supernovae, but the subset of all correlated objects does not seem to be physically different from the whole set.  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

射电源0420—014,1334—127和2345—167中的视超光速运动     

沈志强  万同山  洪晓瑜 《中国天文和天体物理学报》1997,(1)

本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实  相似文献   

Baryon loading and the Weibel instability in gamma-ray bursts     

M. Fiore  L. O. Silva  C. Ren  M. A. Tzoufras  W. B. Mori 《Monthly notices of the Royal Astronomical Society》2006,372(4):1851-1855

The dynamics of two counter-streaming electron–positron–ion unmagnetized plasma shells with zero net charge is analysed in the context of magnetic field generation in gamma-ray burst internal shocks due to the Weibel instability. The effects of large thermal motion of plasma particles, arbitrary mixture of plasma species and space charge effects are taken into account. We show that, although thermal effects slow down the instability, baryon loading leads to a non-negligible growth rate even for large temperatures and different shell velocities, thus guaranteeing the robustness and the occurrence of the Weibel instability for a wide range of scenarios.  相似文献   

黄淮海平原地下水开采的水文效应   总被引：1，自引：0，他引：1  

魏忠义  任鸿遵 《地理研究》1985,4(2):65-72

黄淮海平原是我国地下水开发最早,利用程度最高的地区。随着地下水开采量急剧增长,已产生了一系列水文效应变化,其中包括区域地下水位下降和地下水降落漏斗的形成;开采浅层地下水对地表径流和降雨入渗补给的地下水量的影响,井灌井排在盐碱土的改良作用等。  相似文献   

再论贺兰山南部北西向构造成因   总被引：3，自引：0，他引：3  

张进  马宗晋  任文军 《地球科学与环境学报》2005,27(1):19-25,29

贺兰山南部分布着多个方向的构造，其中最明显地是一系列的北西向构造，目前这些构造的相互关系以及形成机制还没有得到合理地解释，争论很大；野外构造研究表明，贺兰山南部北西向构造的形成与青铜峡一固原断裂活动有密切的关系，是该断裂由走滑运动向挤压运动转换时的派生构造；从另一角度也说明，在中新生代由青铜峡一固原断裂所限定的地块(卫宁北山)向东运动，而这些北西向构造的形成主要发生在新生代。由于卫宁北山向东运动的动力来源于青藏高原，因此，贺兰山南部北西向构造的形成与青藏高原的演化有密切的联系。所以。作为中国重要地质界限的南北向构造——贺兰山已经被青藏高原的构造活动所叠加。  相似文献   

Time scale of an early to mid-Paleozoic orogenic cycle of the long-lived Central Asian Orogenic Belt, Inner Mongolia of China: Implications for continental growth   总被引：50，自引：0，他引：50  

Ping Jian  Dunyi Liu  Alfred Krner  Brian F. Windley  Yuruo Shi  Fuqin Zhang  Guanghai Shi  Laicheng Miao  Wei Zhang  Qi Zhang  Liqao Zhang  Jishun Ren 《Lithos》2008,101(3-4):233-259

We present a detailed, new time scale for an orogenic cycle (oceanic accretion–subduction–collision) that provides significant insights into Paleozoic continental growth processes in the southeastern segment of the long-lived Central Asian Orogenic Belt (CAOB). The most prominent tectonic feature in Inner Mongolia is the association of paired orogens. A southern orogen forms a typical arc-trench complex, in which a supra-subduction zone ophiolite records successive phases during its life cycle: birth (ca. 497–477 Ma), when the ocean floor of the ophiolite was formed; (2) youth (ca. 473–470 Ma), characterized by mantle wedge magmatism; (3) shortly after maturity (ca. 461–450 Ma), high-Mg adakite and adakite were produced by slab melting and subsequent interaction of the melt with the mantle wedge; (4) death, caused by subduction of a ridge crest (ca. 451–434 Ma) and by ridge collision with the ophiolite (ca. 428–423 Ma). The evolution of the magmatic arc exhibits three major coherent phases: arc volcanism (ca. 488–444 Ma); adakite plutonism (ca. 448–438 Ma) and collision (ca. 419–415 Ma) of the arc with a passive continental margin. The northern orogen, a product of ridge-trench interaction, evolved progressively from coeval generation of near-trench plutons (ca. 498–461 Ma) and juvenile arc crust (ca. 484–469 Ma), to ridge subduction (ca. 440–434 Ma), microcontinent accretion (ca. 430–420 Ma), and finally to forearc formation. The paired orogens followed a consistent progression from ocean floor subduction/arc formation (ca. 500–438 Ma), ridge subduction (ca. 451–434 Ma) to microcontinent accretion/collision (ca. 430–415 Ma); ridge subduction records the turning point that transformed oceanic lithosphere into continental crust. The recognition of this orogenic cycle followed by Permian–early Triassic terminal collision of the CAOB provides compelling evidence for episodic continental growth.  相似文献   

An absolute paleotemperature record from 10 to 6 Ka inferred from fluid inclusion D/H ratios of a stalagmite from Vancouver Island, British Columbia, Canada     

Ren Zhang  Henry P. Schwarcz 《Geochimica et cosmochimica acta》2008,72(4):1014-1026

By using continuous helium flow during the crushing of calcite speleothem samples, we are able to recover liberated inclusion waters without isotopic fractionation. A paleotemperature record for the Jacklah Jill Cave locality, Vancouver Island, BC, was obtained from a 30-cm tall stalagmite that grew 10.3-6.3 Ka ago, using δ¹⁸O values of the crushed calcite and of the inclusion water as inferred from its δD. It is found that the locality experienced mean annual temperature variations up to 11 °C over a 4-Ka period in the early Holocene. At the beginning of the period, local temperature quickly increased from a minimum of ∼1 °C to around 10 °C, but this early climate optimum, about 3 °C warmer than today, only lasted for ∼1200 years. About 8.6 Ka ago, temperature had declined to ∼7 °C, approximately the same as the modern cave temperature. Since then, the study area has experienced only minor temperature fluctuations, but there was a brief fall to ∼4 °C at around 7 Ka ago, which might be caused by a short lived expansion of local alpine glaciers. The long-term T-dependence of δD was 1.47‰/°C, identical to the value in modern precipitation.  相似文献