Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

海岩小说的几种叙述模式及弊端     

姚国军  李霞 《广东海洋大学学报》2006,26(5):87-90

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

射电源0420—014,1334—127和2345—167中的视超光速运动     

沈志强  万同山  洪晓瑜 《中国天文和天体物理学报》1997,(1)

本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实  相似文献   

豫西前河构造蚀变岩型金矿成矿过程中的流体-岩石反应     

曹烨  李胜荣  申俊峰  要梅娟  李庆康  毛付龙 《矿床地质》2008,27(6):714-726

前河金矿区位于华北地台南缘,赋存在中元古界熊耳群安山岩和英安岩中,矿体受断裂破碎带控制。含矿热液在迁移过程中与围岩发生了广泛的流体-岩石反应而引起热液蚀变。本区石英中有4种类型的流体包裹体,均一温度范围为145～331℃,其中含CO2包裹体的完全均一温度主要分布在中-高温区。成矿流体的密度和压力变化范围分别是0.68～0.94g/cm3和(367.01～896.55)×105Pa。金大量沉淀成矿时的流体特征为:温度213～260℃、密度0.80～0.89g/cm3和压力(502.86～710.57)×105Pa。流体相为SO42->Na >Cl->K 型,CO2/H2O比值及N2、H2S、Ar、C2H6等挥发分的含量明显增高,f(CO2)、f(H2S)、f(CH4)和Eh值增大;f(O2)、f(H2O)和pH值减小。在青磐岩化安山岩的基础上发生的流体-岩石反应是造成本矿床金沉淀成矿的最主要原因。  相似文献   

贵州青岩剖面青岩阶上部牙形石的发现及其意义     

武桂春  姚建新  纪占胜  王立亭 《地质学报》2008,82(2):145-154

在贵州青岩剖面的青岩组之上,原被认为是拉丁期的垄头组下部的层段中发现了牙形石动物群,除少量的分枝分子外,都归属于Neogondolella属,可鉴定为4个种,即Neogondolella bifurcata,N.constricta,N.mombergensis和N.navicula.建立了2个牙形石带,自下而上是Neogondolella bifurcata带和N.cinstricta带.牙形石面貌证明这段地层在时代上非常接近但尚未进入拉丁阶,属于安尼期中晚期,进一步的牙形石工作将很有可能在目前发现的牙形石层段的上部寻找到安尼阶和拉丁阶之间的界限,从而为青岩阶顶界的限定提供可靠的牙形石证据.此外,牙形石的发现还初步实现了青岩阶2大主导门类化石--牙形石和菊石在同一剖面的直接对比关系.  相似文献   

中国滑坡预测预报研究综述   总被引：14，自引：1，他引：13  

王念秦  王永锋  罗东海  姚勇 《地质论评》2008,54(3):355-361

滑坡预测预报是有效预防滑坡灾害的重要途径之一,这方面的研究不仅受到广泛重视,且硕果累累。将中国滑坡预测预报的研究历史划分为四个阶段：① 经验判断——被动防灾避灾阶段;② 定性——半定量分析预测预报阶段;③ 理论方法探索——检验预测预报阶段;④ 理论方法深化——综合应用预测预报阶段。从监测（观测）方法、预测预报方法,以及研究特点等方面进行简要回顾,总结已有监测方法（手段）、预测预报理论、方法的研究现状,认为尚存在：① 监测方法（手段）,包括仪器、设备的精度不足;② 预测预报方法综合性、实用性不强;③ 预测预报专门理论尚待完善等问题。在分析的基础上,提出自己的观点,并进行了发展趋势展望。  相似文献   

藏北高原夏季边界层加热(冷却)特征初探     

谷良雷  胡泽勇  吕世华  姚济敏 《冰川冻土》2008,30(3):421-425

利用GAME-Tibet1998年加强观测期安多探空观测资料与CAMP-Tibet2004年加强观测期那曲探空资料, 分析了藏北高原夏季大气边界层加热(冷却)特征. 结果表明: 夏季, 藏北高原大气边界层的大气加热(冷却)率的逐日变化特征明显, 晴天时较大, 多云和降雨时较小. 白天大气加热率和夜晚大气冷却率的平均值都基本相当, 印证了大气能量守恒.  相似文献   

软硬互层金刚石复合片钻头在地浸砂岩型铀矿中的研究及应用          下载免费PDF全文

要二仓  邢预恩  杨爱军 《探矿工程》2008,35(1):68-70

针对近年在巴音戈壁盆地及鄂尔多斯盆地钻探所遇到的复杂地质情况,研究试验了PDC钻头,在地浸砂岩铀矿钻探生产中取得了良好的效果,并制定总结了相应的钻进参数.  相似文献   

河南省洛宁县寨凹钼矿床流体包裹体研究及矿床成因   总被引：10，自引：0，他引：10  

邓小华陈衍景  姚军明李文博李 诺王 运糜 梅张 颖 《中国地质》2008,35(6):1250-1266

寨凹钼矿床位于华北克拉通南缘的熊耳地体．矿床定位受马超营断裂带的次级断裂控制,矿体呈脉状贼存于太华超群石板沟组黑云角闪斜长片麻岩中。成矿过程包括3个阶段：石英-辉钼矿阶段（I）、石英-多金属硫化物阶段（Ⅱ）、石英-碳酸盐阶段（Ⅲ）,其中,I阶段为主成矿阶段。寨凹钼矿床可见2类流体包裹体,即水溶液型和含子晶包裹体;激光拉曼指示包裹体成分主要为H2O。从早到晚,流体包裹体均一温度从I阶段100～260℃,经Ⅱ阶段110～160℃．变化为Ⅲ阶段120—180℃．矿床总体属于低温热液矿床：流体包裹体盐度从I阶段的2～25wt％NaCl．eqv演化至Ⅱ阶段的6—30wt％NaCl．eqv．然后降为Ⅲ阶段的7～25wt％NaCl．eqv。I阶段均一温度范围宽广、流体包裹体盐度由双峰式演化为单峰式以及包裹体温度-盐度双变图的负相关性指示了流体混合是主要的成矿机制。寨凹钼矿流体包裹体以高密度、高盐度的低温低压流体为特征,是含CaCl,流体参与成矿的结果,热的岩浆流体与冷的含CaCl,的卤水的混合．导致了辉钼矿的沉淀。寨凹钼矿床地质和流体包裹体特征与侵入岩相关的成矿系统一致．指示其成因类型为与侵入岩有关的钼矿床．  相似文献