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1.
Thallium(I) has been added to estuarine sediment suspended in various natural and artificial aqueous samples in order to examine its reactivity under simulated estuarine conditions. In river water and sea water, adsorption of Tl to sediment was so rapid that a period of desorption-relaxation succeeded instantaneous adsorption. Entire time-courses could not be fitted with a conventional kinetic model, but pseudo-first-order forward and reverse rate constants of 0.0044 and 0.30 h−1, respectively, were derived for river water by omitting measurements defining the adsorption “overshoot” observed at the onset of the experiment. The extent of adsorption after a 16 h equilibration period was considerably greater in river water than in sea water, and displayed a quasi-linear increase with increasing pH over the range 2-9 in the former but no clear dependence on pH in the latter. A logarithmic reduction in the sediment-water distribution coefficient, KD, was observed on estuarine mixing from river water to sea water. Experiments conducted in electrolyte solutions coupled with inorganic equilibrium speciation modeling revealed that the effect was the combined result of a reduction in the activity of Tl+, an increase in the proportion of TlCl0 and increasing competition for adsorption sites from K+ with an increase in salinity. Overall, there was little experimental evidence for either the oxidation of Tl+ or its complexation by dissolved organic matter. The findings of the investigation are discussed in terms of the likely behavior of Tl in estuaries. 相似文献
2.
Dieter F. E. Stolle 《国际地质力学数值与分析法杂志》1991,15(6):399-416
This paper explores similarities and differences between initial stress and initial strain methods of analyses. The author takes the position that both methods, although perhaps conceptually different, are actually numerically the same. A simple approach for providing closed-form stability criteria for explicit and implicit time-marching procedures is described. For the case of associated, non-hardening viscoplasticity the approach provides criteria which are identical to those of Cormeau for explicit schemes. An implicit time-marching scheme which avoids the compliance matrix inversions at the constitutive level is also presented. Like many other implicit methods, this implicit time-marching scheme is unconditionally stable for θ≥½. The connection between initial strain plasticity and an explicit viscoplastic time-marching scheme is also addressed. 相似文献
3.
The Kas Formation in SE Turkey was deposited as part of the Permian sequence on the northern margin of the Arabian Plate. Its stratigraphic relationship to time‐equivalent strata of the Arabian Plate was mentioned briefly in previous studies, but has not been elaborated and illustrated in detail. This biostratigraphic review of existing palaeontological data has improved the accuracy of age interpretation for the Kas Formation, and the relationship of its excellent palynological record to the international Permian chronostratigraphic units. As a result, this study has identified a number of key palynological species from the Kas Formation, which occur as well as in the ‘Basal Khuff Clastics’ of Saudi Arabia and in the ‘Khuff transition section’ of Oman. All these units have approximately the same age: Wordian to early Capitanian, based on ‘age control’ provided by Foraminifera. This study also demonstrates that, by using key palynological taxa, correlation of strata would be possible across the entire Arabian Plate in this narrow time range. Hence, the ‘Oman and Saudi Arabia Palynological Zone 6’ (OSPZ6) is applicable throughout the Arabian Plate area, including the northern regions of SE Turkey and Iraq. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
4.
Patricio Crespo Amelie Bücker Jan Feyen Kellie B. Vaché Hans‐Georg Frede Lutz Breuer 《水文研究》2012,26(25):3896-3910
In this study, the Mean Transit Time and Mixing Model Analysis methods are combined to unravel the runoff generation process of the San Francisco River basin (73.5 km2) situated on the Amazonian side of the Cordillera Real in the southernmost Andes of Ecuador. The montane basin is covered with cloud forest, sub‐páramo, pasture and ferns. Nested sampling was applied for the collection of streamwater samples and discharge measurements in the main tributaries and outlet of the basin, and for the collection of soil and rock water samples. Weekly to biweekly water grab samples were taken at all stations in the period April 2007–November 2008. Hydrometric data, Mean Transit Time and Mixing Model Analysis allowed preliminary evaluation of the processes controlling the runoff in the San Francisco River basin. Results suggest that flow during dry conditions mainly consists of lateral flow through the C‐horizon and cracks in the top weathered bedrock layer, and that all subcatchments have an important contribution of this deep water to runoff, no matter whether pristine or deforested. During normal to low precipitation intensities, when antecedent soil moisture conditions favour water infiltration, vertical flow paths to deeper soil horizons with subsequent lateral subsurface flow contribute most to streamflow. Under wet conditions in forested catchments, streamflow is controlled by near surface lateral flow through the organic horizon. Exceptionally, saturation excess overland flow occurs. By absence of the litter layer in pasture, streamflow under wet conditions originates from the A horizon, and overland flow. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
5.
Amelie Bücker Patricio Crespo Hans-Georg Frede Kellie Vaché Felipe Cisneros Lutz Breuer 《Aquatic Geochemistry》2010,16(1):127-149
We investigated controls on the water chemistry of a South Ecuadorian cloud forest catchment which is partly pristine, and
partly converted to extensive pasture. From April 2007 to May 2008 water samples were taken weekly to biweekly at nine different
subcatchments, and were screened for differences in electric conductivity, pH, anion, as well as element composition. A principal
component analysis was conducted to reduce dimensionality of the data set and define major factors explaining variation in
the data. Three main factors were isolated by a subset of 10 elements (Ca2+, Ce, Gd, K+, Mg2+, Na+, Nd, Rb, Sr, Y), explaining around 90% of the data variation. Land-use was the major factor controlling and changing water
chemistry of the subcatchments. A second factor was associated with the concentration of rare earth elements in water, presumably
highlighting other anthropogenic influences such as gravel excavation or road construction. Around 12% of the variation was
explained by the third component, which was defined by the occurrence of Rb and K and represents the influence of vegetation
dynamics on element accumulation and wash-out. Comparison of base- and fast flow concentrations led to the assumption that
a significant portion of soil water from around 30 cm depth contributes to storm flow, as revealed by increased rare earth
element concentrations in fast flow samples. Our findings demonstrate the utility of multi-tracer principal component analysis
to study tropical headwater streams, and emphasize the need for effective land management in cloud forest catchments. 相似文献
6.
7.
Ellen Stolle 《Geological Journal》2016,51(2):223-235
The palynological record from the Permian part of the Çakraz Formation from the Çamdağ area of NW Turkey has been investigated in order to obtain a more precise age assessment than achieved in previous studies. The ‘Late Permian’ age and a possible age range beginning in the Roadian (mid Permian) were discussed before for sections of palynomorph‐bearing strata occurring within the formation. These deposits are now assigned to the late Cisuralian/Guadalupian and considered to be not older than early Kungurian, and not younger than Capitanian. The new age assessment was conducted via a long‐distance, intercontinental palynostratigraphic correlation from NW Turkey to South America, where results of radiometric datings were linked to some siliciclastic sections by absolute ages to the chronostratigraphy. Common conspicuous taxa in pollen‐dominated assemblages from both regions are Lueckisporites and Vittatina such as Lueckisporites virkkiae, L. latisaccus, L. stenotaeniatus, Vittatina corrugata, V. subsaccata and V. wodehousei. These species co‐occur in strata of the northern as well as southern palaeohemisphere settings (NW Turkey and S America). Thus, Lueckisporites latisaccus, L. stenotaeniatus and Vittatina corrugata are, as well as L. virkkiae or V. subsaccata, considered as being cosmopolitan. Due to the more precise palynological dating of part of the Çakraz Formation and surrounding deposits they are here broadly correlated with Permian continental successions from the Southern Alps, Italy, including the Val Daone Conglomerate and the Verrucano Lombardo/Val Gardena Sandstone (Gröden) red beds, and the Rotliegend deposits of Germany. These results support some earlier views regarding the age and stratigraphic equivalences with European deposits. The new age for the Çakraz Formation also supports recent considerations as middle Permian (part Guadalupian), and as Cisuralian for the lower parts of the formation, such as the fossil‐bearing section with plants and tetrapod traces further east in NW Turkey, where the unit also crops out. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
8.
Takabatake Tomoyuki St-Germain Philippe Nistor Ioan Stolle Jacob Shibayama Tomoya 《Natural Hazards》2019,98(1):267-291
Natural Hazards - In the present study, numerical simulations were conducted to estimate the spatio-temporal characteristics of tsunami inundation for municipalities on Vancouver Island, Canada, as... 相似文献
9.
Soares Gabriel Yamazaki Yosuke Matzka Jürgen Pinheiro Katia Stolle Claudia Alken Patrick Yoshikawa Akimasa Uozumi Teiji Fujimoto Akiko Kulkarni Atul 《Studia Geophysica et Geodaetica》2019,63(2):304-319
Studia Geophysica et Geodaetica - Ground and space-based geomagnetic data were used in the investigation of the longitudinal, seasonal and lunar phase dependence of the equatorial counter... 相似文献
10.
Micromechanical analysis of non-coaxiality between stress and strain increment in granular materials
Acta Geotechnica - It is known that non-coaxiality between the directions of the principal stresses and the principal plastic strain increments in granular material is physically resulted from the... 相似文献