The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl     

Geraldo Magela da Costa  Gabriel de Oliveira Polli  Márcio A. Kahwage  Eddy de Grave  Antônio Claret Soares Sabioni  Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.  相似文献   

Detection and 2d modelling of cavities using pole–dipole array     

Fernando A. Monteiro Santos  António R. Andrade Afonso 《Environmental Geology》2005,48(1):108-116

The resistivity method is often used in cave prospecting. In this paper the pole–dipole array ability to detect cavities at different depths and with different water contents is investigated. The research was performed using analogical and numerical modelling. According to the results, empty caves at a depth less than four times its diameter can be easily detected. The ability of the pole–dipole array to detect water-filled caves reaches a minimum at filling percentages of 30–50%. Overburden effects research shows that low resistivity overburden reduces the resolution capability of the array. This study shows that equivalent results can be obtained by modelling the empty caves as infinite resistivity bodies or, alternatively, as very high resistivity ones. The analysis of field data acquired in the Maciço Calcário Estremenho (Portugal) shows the practical importance of the pole–dipole array in cavities prospecting.  相似文献   

Assessing the effects of land cover and future climate conditions on the provision of hydrological services in a medium‐sized watershed of Portugal          下载免费PDF全文

Claudia Carvalho‐Santos  João Pedro Nunes  António T. Monteiro  Lars Hein  João Pradinho Honrado 《水文研究》2016,30(5):720-738

The separated and combined effects of land‐cover scenarios and future climate on the provision of hydrological services were evaluated in Vez watershed, northern Portugal. Soil and Water Assessment Tool was calibrated against daily discharge, sediments and nitrates, with good agreements between model predictions and field observations. Four hypothetical land‐cover scenarios were applied under current climate conditions (eucalyptus/pine, oak, agriculture/vine and low vegetation). A statistical downscaling of four General Circulation Models, bias‐corrected with ground observations, was carried out for 2021–2040 and 2041–2060, using representative concentration pathway 4.5 scenario. Also, the combined effects of future climate conditions were evaluated under eucalyptus/pine and agriculture/vine scenario. Results for land cover revealed that eucalyptus/pine scenario reduced by 7% the annual water quantity and up to 17% in the summer period. Although climate change has only a modest effect on the reduction of the total annual discharge (?7%), the effect on the water levels during summer was more pronounced, between ?15% and ?38%. This study shows that climate change can affect the provision of hydrological services by reducing dry season flows and by increasing flood risks during the wet months. Regarding the combined effects, future climate may reduce the low flows, which can be aggravated with eucalyptus/pine scenario. In turn, peak flows and soil erosion can be offset. Future climate may increase soil erosion and nitrate concentration, which can be aggravated with agriculture scenario. Results moreover emphasize the need to consider both climate and land‐cover impacts in adaptation and land management options at the watershed scale. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Temporal and spatial changes in soil micronutrients in managed <Emphasis Type="Italic">Nothofagus pumilio</Emphasis> forest of Tierra del Fuego,Argentina     

Romina Mansilla  Juan Carlos Nóvoa-Muñoz  Xabier Pontevedra-Pombal  Verónica Pancotto  Antía Gómez-Armesto  Julio Escobar  Alicia Moretto 《Environmental Earth Sciences》2016,75(9):738

  相似文献   

Concentrations and physicochemical speciation of heavy metals in urban runoff sediment from São Gonçalo—Rio de Janeiro/Brazil     

José Antônio Baptista Neto  Carlos Marclei Arruda Rangel  Estefan Monteiro Da Fonseca  Marília Teresa Lima Do Nascimento  Ana Dalva De Oliveira Santos  Bruno Cezar Baptista Rodrigues  Gustavo Vaz De Melo 《Environmental Earth Sciences》2016,75(17):1209

  相似文献   

Influence of Particle Morphology on the Hydraulic Behavior of Coal Ash and Sand     

Karla Salvagni Heineck  Rosemar Gomes Lemos  Juan Antônio Altamirano Flores  Nilo Cesar Consoli 《Geotechnical and Geological Engineering》2010,28(4):325-335

Flexible-wall hydraulic conductivity tests were carried out on bottom ash, fly ash and compacted specimens of sand with additions of 0, 3, 6, 9 and 18% of bentonite. In order to study the effect of bentonite inclusion and particle morphology on the hydraulic conductivity of the admixtures, an investigation was undertaken based on thin section micrographs. It was found that, for both bottom and fly ash admixtures, bentonite addition reduced only one order of magnitude the hydraulic conductivity, from 1.78 × 10⁻⁶ m/s to 1.39 × 10⁻⁷ m/s. On the other hand, the sand hydraulic conductivity was reduced five orders of magnitude, from 3.17 × 10⁻⁵ m/s to 5.15 × 10⁻¹⁰ m/s. Among several factors that can be responsible for the difficulty in reducing hydraulic conductivity, such as ash grain size distribution and elevated cation concentration (leached from the ash) in pore water, it can also be recalled the high particle voids observed in the ash by means of microscopic analysis. The same is not true with the sand, which has solid particles, without inner voids.  相似文献   

Geotechnical Characterization by In situ and Lab Tests to the Back-Analysis of a Supported Excavation in Metro do Porto   总被引：1，自引：1，他引：0  

António Viana da Fonseca  Sara Rios Silva  Nuno Cruz 《Geotechnical and Geological Engineering》2010,28(3):251-264

This paper summarizes the geotechnical characterization conducted for the design and subsequent analysis of a strutted excavation in “Metro do Porto”. This region is geologically dominated by heterogeneous weathered granite masses with deep residual soil profiles. Local saprolitic soils exhibit, by their nature, a particular behavior characterized by very sensitive and weak relic micro-structures, due to their specific genesis. This study has included the interpretation of a significant volume of in situ test results, triaxial tests over undisturbed samples and monitoring data, giving rise to specific correlations between testing and design parameters. Real time monitoring enabled a back-analysis by FEM of a well instrumented section of the strutted excavation, which was calibrated taking into account the derived correlations and the deformability behavior of this specific geotechnical ambient. This geomaterial, although revealing very high initial stiffness values (for very small strain ranges) has shown low stiffness values for “medium to high” strain levels, reflecting a singular strong non-linearity in the stress-strain behavior.  相似文献   

Natural Variability of Shear Strength in a Granite Residual Soil from Porto     

Luís Pinheiro Branco  António Topa Gomes  António Silva Cardoso  Carla Santos Pereira 《Geotechnical and Geological Engineering》2014,32(4):911-922

The renewal imposed by the Eurocodes regarding the methodologies of safety evaluation requires a statistical analysis of the variability of ground geotechnical parameters. However, the studies published in the reviewed literature do not cover the typical materials from the northeast region of Portugal—residual soils from granite—to which a strong heterogeneity is associated. Hence, a statistical characterization of the natural variability of a granite residual soil from Porto has been made through a significant amount of experimental tests, focusing on its geomechanical properties. In order to provide a database for probabilistic analysis of problems involving this type of soils, an appropriate statistical law has been used to model its variability, which has been quantified by means of coefficients of variation and scales of fluctuation.  相似文献   

Generative Adversarial Network Applied to Ore Type Modeling in Complex Geological Environments     

Jordão  Helga  Azevedo  Leonardo  Sousa  António Jorge  Soares  Amílcar 《Mathematical Geosciences》2022,54(7):1165-1182

Mathematical Geosciences - In complex geological environments, the spatial domain characterization of different ore types has been one of the most important challenges in the assessment of mineral...  相似文献   

Mechanical Behavior of Microbially Induced Calcite Precipitation Cemented Sand     

de Rezende  Igor Marasini  Prietto  Pedro Domingos Marques  Thomé  Antônio  Dalla Rosa  Francisco 《Geotechnical and Geological Engineering》2022,40(4):1997-2008

Geotechnical and Geological Engineering - New sustainable ground improvement techniques have been recently required for applications in onshore and offshore geotechnical structures. The...  相似文献