Meteoric fluid‐rock interaction in Variscan shear zones     

Camille Dussaux  Aude Gbelin  Philippe Boulvais  Vronique Gardien  Stephen Grimes  Andreas Mulch 《地学学报》2019,31(4):366-372

Variscan shear zones in the Armorican Massif represent sites of strong fluid‐rock interaction. The hydrogen isotope composition of muscovite (δD_Ms) from syntectonic leucogranite allows to determine the source of fluids that infiltrated the footwall of three detachment zones and the South Armorican Shear Zone. Using temperatures of hydrogen isotope exchange estimated from microstructural data, we calculate the hydrogen isotope ratios of water (δD_water) present within the shear zones during high‐temperature deformation. A ~40‰ difference in δD_water values from deep to shallow crustal level reveals a mixing relationship between deep crustal fluids with higher δD values that range from ?34 to ?33‰, and meteoric fluids with δD values as low as ?74‰ in the upper part of detachment footwalls.  相似文献   

Effects of magnetic interactions in anisotropy of magnetic susceptibility: Models, experiments and implications for igneous rock fabrics quantification     

Philippe Gaillot  Michel de Saint-Blanquat  Jean-Luc Bouchez   《Tectonophysics》2006,418(1-2):3

Besides granites of the ilmenite series, in which the anisotropy of magnetic susceptibility (AMS) is mainly controlled by paramagnetic minerals, the AMS of igneous rocks is commonly interpreted as the result of the shape-preferred orientation of unequant ferromagnetic grains. In a few instances, the anisotropy due to the distribution of ferromagnetic grains, irrespective of their shape, has also been proposed as an important AMS source. Former analytical models that consider infinite geometry of identical and uniformly magnetized and coaxial particles confirm that shape fabric may be overcome by dipolar contributions if neighboring grains are close enough to each other to magnetically interact. On these bases we present and experimentally validate a two-grain macroscopic numerical model in which each grain carries its own magnetic anisotropy, volume, orientation and location in space. Compared with analytical predictions and available experiments, our results allow to list and quantify the factors that affect the effects of magnetic interactions. In particular, we discuss the effects of (i) the infinite geometry used in the analytical models, (ii) the intrinsic shape anisotropy of the grains, (iii) the relative orientation in space of the grains, and (iv) the spatial distribution of grains with a particular focus on the inter-grain distance distribution. Using documented case studies, these findings are summarized and discussed in the framework of the generalized total AMS tensor recently introduced by Cañon-Tapia (Cañon-Tapia, E., 2001. Factors affecting the relative importance of shape and distribution anisotropy in rocks: theory and experiments. Tectonophysics, 340, 117–131.). The most important result of our work is that analytical models far overestimate the role of magnetic interaction in rock fabric quantification. Considering natural rocks as an assemblage of interacting and non-interacting grains, and that the effects of interaction are reduced by (i) the finite geometry of the interacting clusters, (ii) the relative orientation between interacting grains, (iii) their heterogeneity in orientation, shape and bulk susceptibility, and (iv) their inter-distance distribution, we reconcile analytical models and experiments with real case studies that minimize the role of magnetic interaction onto the measured AMS. Limitations of our results are discussed and guidelines are provided for the use of AMS in geological interpretation of igneous rock fabrics where magnetic interactions are likely to occur.  相似文献   

Erratum to: Drivers and mechanisms for enhanced summer monsoon precipitation over East Asia during the mid-Pliocene in the IPSL-CM5A     

Yong Sun  Tianjun Zhou  Gilles Ramstein  Camille Contoux  Zhongshi Zhang 《Climate Dynamics》2016,46(5-6):2027-2027

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Sedimentary archives of the French Atlantic coast (inner Bay of Vilaine,south Brittany): Depositional history and late Holocene climatic and environmental signals     

Philippe Sorrel  Bernadette Tessier  François Demory  Agnès Baltzer  Firas Bouaouina  Jean-Noël Proust  David Menier  Camille Traini 《Continental Shelf Research》2010,30(10-11):1250-1266

The late Holocene is of particular interest to our understanding of the evolution of coastal sedimentary systems because this period encompasses warmer and cooler periods, and rising sea level in northern Europe. Based on an approach combining AMS ¹⁴C, sedimentological and rock magnetic analyses on sediment cores complemented with seismic data collected in the macrotidal Bay of Vilaine (south Brittany), we document the depositional history of the inner bay coeval to the mid- to late-Holocene transgression in south Brittany. Correlation between sedimentary archives revealed the main sedimentary infilling phases during the last 6000 years. Four units (U1–U4) are recognized in the coastal sediment wedge of the system, corresponding to the stepwise marine invasion of the bay. We show that (1) marine inundation, due to the steep morphology of the bedrock, is diachronous between distal and proximal records. A time lag of ～1000 years is inferred over a distance of less than 5 km; (2) in the outer areas, the sedimentation has been condensed since 3000 years; (3) proximal estuarine archives offer the best record of sedimentary processes covering the last 2000 years, including the Medieval Warm Period (MWP).Correlations in proximal records in the Bay of Vilaine assess the connection between coastal sedimentary dynamics, climatic conditions and anthropogenic activities during the MWP. We match the preservation of clay deposits to increased river-borne suspended matter transported to the estuary probably as a result of accelerated land-use development (higher soil erosion) in the catchment area between ca. 880 and 1050 AD. Because the preservation of estuarine sedimentary successions is favoured when coastal wave sediment reworking is minimal, it is proposed that the prevailing climatic regime in south Brittany during the MWP likely resembled to that of the preferred negative phase of the North Atlantic Oscillation (NAO). Our data are fairly consistent with other late Holocene records from northern Europe including the Atlantic seaboard. However, they outline the difficulty in interpreting climatic and anthropogenic signatures in coastal sedimentary records where high-resolution chronologies required to unravel their respective influences are still missing.  相似文献   

Shape preferred orientation of object populations: automatic analysis of digitized images   总被引：1，自引：0，他引：1  

Patrick Launeau  Jean-Luc Bouchez  Keith Benn 《Tectonophysics》1990,180(2-4):201-211

An automatic technique is presented for systematic shape preferred orientation (SPO) analysis of crystal fabrics in rocks. This technique is based on digitization of an image with a CCD camera and separation of an object population from its matrix. The image is analysed globally using a rotating grid that is superimposed on the square pixel grid of the computer screen. The parametric method is based on counting intercepts in all directions. The interceps rose provides information on both the orientation and strength of the SPO. Problems of hardware-related counting noise anisotropy are avoided using an original method of filtering the intercept function with a linear, sliding mask on the counting grid. The technique was tested both on single objects of different shapes and on different populations of identical objects. A very high degree of accuracy was obtained for orientation measurements. Fabric shape parameters are introduced which are specific to this intercept technique; they compare favourably with shape parameters used in axial fabric analysis.  相似文献   

Strain partitioning in a pluton during emplacement in transpressional regime: the example of the Néouvielle granite (Pyrenees)     

G. Gleizes  D. Leblanc  P. Olivier  J. Bouchez 《International Journal of Earth Sciences》2001,90(2):325-340

This microstructural and anisotropy of magnetic susceptibility study of the internal structures of the Hercynian Néouvielle granite pluton (100 km²) provides new data indicating that the pluton was emplaced during the main Hercynian tectonic event recognized in the Pyrenees. It also provides new data about the later Alpine deformation localized along narrow mylonitic bands. These bands acted as reverse faults and have not rotated the Hercynian structures that define the main part of the pluton. The pluton is composed of two structural domains: the northern half of the pluton displays a beak shape in map view, with subhorizontal E-W trending lineations of magmatic origin; the southern half is semi-circular and displays rather steeply northward plunging lineations corresponding to magmatic and high temperature (HT) solid-state microstructures. These features are associated with magma deformation during emplacement. Magma deformation corresponds, in the northern half of the pluton, to an E-W strike-slip deformation recognized in the enveloping pelitic metasediments of Carboniferous age and, in the southern half of the pluton, to southward overthrusting recognized in the enveloping quartzites of Devonian age. Juxtaposition in a single granite body of transcurrent and compressive domains is viewed as a strain partitioning in the magma. This strain partitioning is linked to both the transpressive character of the main regional deformation event and the rheological contrast between the pelitic country rocks and quartzose country rocks.  相似文献   

Determination of Total Organic Carbon Content and δ¹³C in Carbonate-Rich Detrital Sediments     

Valier Galy  Julien Bouchez  Christian France-Lanord 《Geostandards and Geoanalytical Research》2007,31(3):199-207

The determination of total organic carbon content and composition in detrital sediments requires careful removal of their carbonate minerals. In detrital sediments containing large amounts of carbonates, including dolomite, this can only be achieved by liquid acid leaching that may solubilise a significant proportion of the organic carbon. For a set of detrital sediments from the Himalayan system and the Amazon River as well as five geological reference materials, we determined the proportion of organic carbon (C_org) solubilised during acid leaching. This proportion is significant for all analysed sediments and generally tends to increase with the organic carbon content. Compared to other types of sediments analysed, clay fractions extracted from river sediments and bed sediments with very low organic carbon content have high and low proportions of acid soluble C_org respectively. In Himalayan and Amazon river sediments, the proportion of C_org solubilised during acid leaching was relatively constant with average values of 14 and 19 % respectively. Thus, it is possible to correct the C_org content for the dissolved organic carbon content measured after decarbonation. Data presented here show that C_org dissolved during liquid acid leaching must be taken into account. After careful calibration, the method presented here should, therefore, be applied to any carbonate-rich detrital sediment.  相似文献   

U–Pb dating of the end of the Pan-African orogeny in the Tuareg shield: the post-collisional syn-shear Tioueine pluton (Western Hoggar, Algeria)     

J. L. Paquette  R. Caby  M. T. Djouadi  J. L. Bouchez 《Lithos》1998,45(1-4):245-253

The Tioueine pluton intrudes the Neoproterozoic series of the Iskel terrane, located in the Tuareg shield, western Hoggar. The consistency of the internal structures as well as the nature and organization of the associated microstructures demonstrate that the Tioueine pluton was emplaced syn-kinematically while N–S strike–slip shear zones were active. The syn-tectonic emplacement of the Tioueine massif implies that this pluton, although belatedly crystallized, entirely belongs to the concept of post-collisional magmatism. In order to date precisely the late Pan-African tectono-metamorphic event in the studied area, an U–Pb age of 523±1 Ma was obtained from abraded zircons of a late quartz–syenite from the Tioueine pluton. This early Cambrian age is younger than the other plutons of the Tuareg shield, which were mainly emplaced between 630 Ma and 580 Ma. This dating also shows that the Tuareg shield was not a single coherent block at 525 Ma, but rather an amalgam of active terranes moving each other along major shear zones. Finally, the Tioueine massif represents probably the final welding of the Tuareg shield assembly of terranes and consequently the end of the post-collisional orogenic episode in the whole Pan-African belt.  相似文献   

Pelagic tar off Georgia and Florida in relation to physical processes     

Camille Cordes  Larry Atkinson  Richard Lee  Jack Blanton 《Marine pollution bulletin》1980,11(11):315-317

Following the Ixtoc I oil rig blowout in Campeche Bay we hypothesized that resulting tarballs should eventually appear in the Gulf Stream off Gerogia and that because of dynamic barriers in the innershelf little would reach nearshore areas. To test these hypotheses, surface tows to collect floating tar were taken off the coasts of Georgia and Florida in October and December, 1979.No tar was found within 40 km of the shore. All samples more than 40 km offshore contained some tar. The mean concentration was 0.82 mg m^?2 with a range of 0.01–5.6 mg m^?2. Closely spaced sampling showed extreme variation but trends were consistent. Perylene was the most abundant compound in the tarballs.  相似文献   

Speciation of naturally-accumulated uranium in an organic-rich soil of an alpine region (Switzerland)     

Simona Regenspurg  Camille Margot-Roquier  Pascal Froidevaux  Pilar Junier 《Geochimica et cosmochimica acta》2010,74(7):2082-2098

Very high concentrations of uranium (up to 4000 ppm) were found in a natural soil in the Dischma valley, an alpine region in the Grisons canton in Switzerland. The goal of this study was to examine the redox state and the nature of uranium binding in the soil matrix in order to understand the accumulation mechanism. Pore water profiles collected from Dischma soil revealed the establishment of anoxic conditions with increasing soil depth. A combination of chemical extraction methods and spectroscopy was applied to characterize the redox state and binding environment of uranium in the soil. Bicarbonate extraction under anoxic conditions released most of the uranium indicating that uranium occurs predominantly in the hexavalent form. Surprisingly, the uranium redox state did not vary greatly as a function of depth. X-ray absorption near edge spectroscopy (XANES), confirmed that uranium was present as a mixture of U(VI) and U(IV) with U(VI) dominating. Sequential extractions of soil samples showed that the dissolution of solid organic matter resulted in the simultaneous release of the majority of the soil uranium content (>95%). Extended X-ray absorption fine structure (EXAFS) spectroscopy also revealed that soil-associated uranium in the soil matrix was mainly octahedrally coordinated, with an average of 1.7 axial (at about 1.76 Å) and 4.6 to 5.3 equatorial oxygen atoms (at about 2.36 Å) indicating the dominance of a uranyl-like (UO₂²⁺) structure presumably mixed with some U(IV). An additional EXAFS signal (at about 3.2 Å) identified in some spectra suggested that uranium was also bound (via an oxygen atom) to a light element such as carbon, phosphorus or silicon. Gamma spectrometric measurements of soil profiles failed to identify uranium long-life daughter products in the soil which is an indication that uranium originates elsewhere and was transported to its current location by water. Finally, it was found that the release of uranium from the soil was significantly promoted at very low pH values (pH 2) and increased with increasing pH values (between pH 5 and 9).  相似文献