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During three cruises in the Black Sea, organised in July 1995 and April–May 1997, biological and chemical parameters that can influence the carbon budget were measured in the water column on the NW shelf, particularly in the mixing zone with Danube River waters. We observed in early spring (end of April–May) conditions an important input of freshwater organisms that enhanced the microbial activity in the low salinity range. High bacterial activity regenerates nitrogen in the form of nitrates, but is also responsible for an important consumption of ammonium and phosphate, leading to a high N/P ratio and a strong deficit in phosphorus. The consequence is a limitation of phytoplankton development but also a production of carbohydrates that accumulate all along the salinity gradient. These mechanisms are responsible for a seasonal accumulation of dissolved organic carbon (DOC) that increases from 210 μM in winter to about 280 μM in summer. All this excess DOC disappears during winter, probably degraded by bacterial activity. The degradation of carbon-rich organic matter increases the phosphorus demand by bacteria bringing limitation to phytoplankton primary production.  相似文献   
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We discuss the main mechanisms affecting the dynamical evolution of Near-Earth Asteroids (NEAs) by analyzing the results of three numerical integrations over 1 Myr of the NEA (4179) Toutatis. In the first integration the only perturbing planet is the Earth. So the evolution is dominated by close encounters and looks like a random walk in semimajor axis and a correlated random walk in eccentricity, keeping almost constant the perihelion distance and the Tisserand invariant. In the second integration Jupiter and Saturn are present instead of the Earth, and the 3/1 (mean motion) and v 6 (secular) resonances substantially change the eccentricity but not the semimajor axis. The third, most realistic, integration including all the three planets together shows a complex interplay of effects, with close encounters switching the orbit between different resonant states and no approximate conservation of the Tisserand invariant. This shows that simplified 3-body or 4-body models cannot be used to predict the typical evolution patterns and time scales of NEAs, and in particular that resonances provide some fast-track dynamical routes from low-eccentricity to very eccentric, planet-crossing orbits.On leave from the Department of Mathematics, University of Pisa, Via Buonarroti 2, 56127 Pisa, Italy, thanks to the G. Colombo fellowships of the European Space Agency.  相似文献   
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This paper reviews major findings of the Multidisciplinary Experimental and Modeling Impact Crater Research Network (MEMIN). MEMIN is a consortium, funded from 2009 till 2017 by the German Research Foundation, and is aimed at investigating impact cratering processes by experimental and modeling approaches. The vision of this network has been to comprehensively quantify impact processes by conducting a strictly controlled experimental campaign at the laboratory scale, together with a multidisciplinary analytical approach. Central to MEMIN has been the use of powerful two-stage light-gas accelerators capable of producing impact craters in the decimeter size range in solid rocks that allowed detailed spatial analyses of petrophysical, structural, and geochemical changes in target rocks and ejecta. In addition, explosive setups, membrane-driven diamond anvil cells, as well as laser irradiation and split Hopkinson pressure bar technologies have been used to study the response of minerals and rocks to shock and dynamic loading as well as high-temperature conditions. We used Seeberger sandstone, Taunus quartzite, Carrara marble, and Weibern tuff as major target rock types. In concert with the experiments we conducted mesoscale numerical simulations of shock wave propagation in heterogeneous rocks resolving the complex response of grains and pores to compressive, shear, and tensile loading and macroscale modeling of crater formation and fracturing. Major results comprise (1) projectile–target interaction, (2) various aspects of shock metamorphism with special focus on low shock pressures and effects of target porosity and water saturation, (3) crater morphologies and cratering efficiencies in various nonporous and porous lithologies, (4) in situ target damage, (5) ejecta dynamics, and (6) geophysical survey of experimental craters.  相似文献   
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The variability and origin of the Coloured Dissolved Organic Matter (CDOM) were studied in the Belgian coastal and adjacent areas including offshore waters and the Scheldt estuary, through the parameters: absorption at 375 nm, aCDOM(375), and the slope of the absorption curve, S. aCDOM(375) varied between 0.20 and 1.31 m−1 and between 0.97 and 4.30 m−1 in the marine area and Scheldt estuary, respectively. S fluctuated between 0.0101 and 0.0203 nm−1 in the marine area and between 0.0167 and 0.0191 nm−1 in the Scheldt estuary. The comparative analysis of aCDOM(375) and S variations evidenced different origins of CDOM in the BCZ. The Scheldt estuarine waters showed decreasing aCDOM(375) values with increasing salinity but constant S value of ∼0.018 nm−1 suggesting a dominant terrestrial origin of CDOM. On the contrary, samples collected in the marine domain showed a narrow range of aCDOM(375) but highly variable S suggesting the additional presence of autochthonous sources of CDOM. This source was evidenced based on the sorting of the marine offshore data according to the stage of the phytoplankton bloom when they were collected. A clear distinction was made between CDOM released during the growth stage characterized by high S (∼0.017 nm−1) and low aCDOM(375) and the decay phase characterized by low S (∼0.013 nm−1) and high aCDOM(375). This observation was supported by CDOM measurements performed on pure phytoplankton cultures which showed increased CDOM release along the wax and wane of the bloom but decreasing S. We concluded that the high variability of the CDOM signature in offshore waters is explained by the local biological production and processing of CDOM.  相似文献   
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Exchange of groundwater and lake water with typically quite different chemical composition is an important driver for biogeochemical processes at the groundwater‐lake interface, which can affect the water quality of lakes. This is of particular relevance in mine lakes where anoxic and slightly acidic groundwater mixes with oxic and acidic lake water (pH < 3). To identify links between groundwater‐lake exchange rates and acid neutralization processes in the sediments, exchange rates were quantified and related to pore‐water pH, sulfate and iron concentrations as well as sulfate reduction rates within the sediment. Seepage rates measured with seepage meters (?2.5 to 5.8 L m‐2 d‐1) were in reasonable agreement with rates inverted from modeled chloride profiles (?1.8 to 8.1 L m‐2 d‐1). Large‐scale exchange patterns were defined by the (hydro)geologic setting but superimposed by smaller scale variations caused by variability in sediment texture. Sites characterized by groundwater upwelling (flow into the lake) and sites where flow alternated between upwelling and downwelling were identified. Observed chloride profiles at the alternating sites reflected the transient flow regime. Seepage direction, as well as seepage rate, were found to influence pH, sulfate and iron profiles and the associated sulfate reduction rates. Under alternating conditions proton‐consuming processes, for example, sulfate reduction, were slowed. In the uppermost layer of the sediment (max. 5 cm), sulfate reduction rates were significantly higher at upwelling (>330 nmol g‐1 d‐1) compared to alternating sites (<220 nmol g‐1 d‐1). Although differences in sulfate reduction rates could not be explained solely by different flux rates, they were clearly related to the prevailing groundwater‐lake exchange patterns and the associated pH conditions. Our findings strongly suggest that groundwater‐lake exchange has significant effects on the biogeochemical processes that are coupled to sulfate reduction such as acidity retention and precipitation of iron sulfides. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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From 1998 to 2002 investigations were carried out to estimate both the quantity and quality (heavy metal contents) of suspended matter loads discharged into a floodplain area measuring approx. 5 km2 of the Central German river Weiße Elster, a tributary of the river Saale in the Elbe river basin. Flood sediments, suspended particulate matter, and floodplain soils were investigated especially for the main pollutants Cd, Zn, Cu, Pb, Cr, and Hg. Supplementary gamma spectroscopy examinations were performed to help to identify the age of deposits in order to estimate sedimentation rates for last decades. The recent flood sediments are contaminated by up to 33 times the geogenic background (Cd). Up to 55% of the total annual SPM load of the river Weiße Elster is relocated into the investigated retention area in the flood‐stricken year 2002. The sedimentation rates for the last 50 years vary between 0.5 mm/a and 1 mm/a in far away and rarely flooded parts and between 1 mm/a and 2 mm/a in the frequently flooded parts of the inflow of the retention area.  相似文献   
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The LMDZ4 general circulation model is the atmospheric component of the IPSL–CM4 coupled model which has been used to perform climate change simulations for the 4th IPCC assessment report. The main aspects of the model climatology (forced by observed sea surface temperature) are documented here, as well as the major improvements with respect to the previous versions, which mainly come form the parametrization of tropical convection. A methodology is proposed to help analyse the sensitivity of the tropical Hadley–Walker circulation to the parametrization of cumulus convection and clouds. The tropical circulation is characterized using scalar potentials associated with the horizontal wind and horizontal transport of geopotential (the Laplacian of which is proportional to the total vertical momentum in the atmospheric column). The effect of parametrized physics is analysed in a regime sorted framework using the vertical velocity at 500 hPa as a proxy for large scale vertical motion. Compared to Tiedtke’s convection scheme, used in previous versions, the Emanuel’s scheme improves the representation of the Hadley–Walker circulation, with a relatively stronger and deeper large scale vertical ascent over tropical continents, and suppresses the marked patterns of concentrated rainfall over oceans. Thanks to the regime sorted analyses, these differences are attributed to intrinsic differences in the vertical distribution of convective heating, and to the lack of self-inhibition by precipitating downdraughts in Tiedtke’s parametrization. Both the convection and cloud schemes are shown to control the relative importance of large scale convection over land and ocean, an important point for the behaviour of the coupled model.  相似文献   
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