The kinematics of the large western knot in the halo of the young planetary nebula NGC 6543     

Deborah L. Mitchell  M. Bryce  J. Meaburn  J. A. López  M. P. Redman  D. Harman  M. G. Richer  H. Riesgo 《Monthly notices of the Royal Astronomical Society》2005,362(4):1286-1294

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Framing in geographical analysis of environmental conflicts: Theory, methodology and three case studies     

Deborah F. Shmueli 《Geoforum》2008,39(6):2048-2061

When applied to environmental concerns, framing offers a rigorous conceptual and analytic approach with potentially practical significance for dealing with complex issues relevant to geography. The purpose of this article is to introduce framing concepts, typology and modes of analysis to address issues which geographers commonly treat: disputes over land ownership and uses, competition for water resources, cultural clashes over control of territory and resources and the impact of spatial patterns and structures when siting noxious sites. Framing analysis is applied to three cases of environmental conflict in Israel and, more generally, for understanding conflicts revolving around the management of human habitats in relation to the physical environment.  相似文献   

Sulfur in peridotites and gabbros at Lost City (30°N, MAR): Implications for hydrothermal alteration and microbial activity during serpentinization   总被引：1，自引：0，他引：1  

Adélie Delacour  Gretchen L. Früh-Green  Deborah S. Kelley 《Geochimica et cosmochimica acta》2008,72(20):5090-5110

Variations in sulfur mineralogy and chemistry of serpentinized peridotites and gabbros beneath the Lost City Hydrothermal Field at the southern face of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) were examined to better understand serpentinization and alteration processes and to study fluid fluxes, redox conditions, and the influence of microbial activity in this active, peridotite-hosted hydrothermal system. The serpentinized peridotites are characterized by low total sulfur contents and high bulk δ³⁴S values close to seawater composition. Low concentrations of ³⁴S-enriched sulfide phases and the predominance of sulfate with seawater-like δ³⁴S values indicate oxidation, loss of sulfide minerals and incorporation of seawater sulfate into the serpentinites. The predominance of pyrite in both serpentinites and gabbros indicates relatively high fO₂ conditions during progressive serpentinization and alteration, which likely result from high fluid fluxes during hydrothermal circulation and evolution of the Lost City system from temperatures of ∼250 to 150 °C. Sulfate and sulfide minerals in samples from near the base of hydrothermal carbonate towers at Lost City show δ³⁴S values that reflect the influence of microbial activity. Our study highlights the variations in sulfur chemistry of serpentinized peridotites in different marine environments and the influence of long-lived, moderate temperature peridotite-hosted hydrothermal system and high seawater fluxes on the global sulfur cycle.  相似文献   

Nitrogen uptake kinetics in the Ross Sea, Antarctica     

William P. Cochlan  Deborah A. Bronk   《Deep Sea Research Part II: Topical Studies in Oceanography》2001,48(19-20)

The first estimates of uptake kinetic parameters for NH₄⁺, NO₃⁻, and urea in the Ross Sea, Antarctica were measured on three cruises during austral late winter–early spring 1996 (pre-bloom), late spring 1997 (bloom development), and summer 1997 (bloom decline). Nitrogen (N) uptake experiments were conducted with water collected at the 50% light penetration depth using trace-metal clean protocols and ¹⁵N tracer techniques. At all sites, ambient NO₃⁻ concentrations ranged from 5.8 to 30.5 μg-at N l⁻¹ and silicic acid concentrations were greater than 62.0 μg-at Si l⁻¹. The following trends were observed. First, based on maximum uptake rates (V_max), apparent N utilization followed the order NO₃⁻>NH₄⁺>urea during the pre-bloom and bloom development cruises. During the summer cruise, as the bloom was declining, the apparent order of utilization was NH₄⁺>NO₃⁻>urea. Second, evidence for possible repression of NO₃⁻ uptake by elevated NH₄⁺ concentrations was only observed at one site. Third, the kinetic parameters of NH₄⁺ uptake rates corrected for isotope dilution were compared with the kinetic parameters determined from uncorrected rates. In this comparison, the measure of substrate affinity, α (α=V_max/K_s) increased by an average of 4.6-fold when rates were corrected for isotope dilution, but values of V_max remained unchanged. Fourth, using bacterial production data, the magnitude of bacterial N uptake was estimated. Assuming that all bacterial N demands were met with NH₄⁺, the estimated bacterial portion of NH₄⁺ uptake ranged from <1%, when the ratio of bacteria to autotrophic biomass was low, to 35%, when bacterial abundance and biomass were highest. Finally, dramatic changes in NH₄⁺ uptake capacity were observed at one station (Stn. O), where kinetic parameters were measured during all three cruises. We hypothesize that a mutualistic relationship exists between phytoplankton and heterotrophic bacteria, and that the creation of microzones of high NH₄⁺ concentrations contributed to the changes seen at this station.  相似文献   

Precious metals in massive base metal sulfide deposits     

R. W. Hutchinson 《International Journal of Earth Sciences》1990,79(2):241-263

Gold and silver are ubiquitous, sometimes minor but economically important metals in massive base metal sulfide ores. Their content, proportions and distribution in the ores depend on complex, interrelated factors of their source, mobilization, transport and deposition.Different types of these deposits are formed by similar seafloor hydrothermal systems operating, however, in widely differing tectono-stratigraphic environments which span a spectrum from ensimatic-oceanic, through continent-margin to ensialic-continental ones. Like those of the base metals, the proportions and distribution of the precious metals in the ores vary regionally with these changing depositional environments. This suggests that precious metal content of the sub-seafloor rocks in which the generative fluids circulate is one factor that governs the amounts and distribution in the ores. The lithology of these source-rocks is also important. Pillowed, tholeiitic basalts have high permeability, golddepleted crystalline pillow interiors and relatively gold-rich palagonitic rims, and are consequently particularly favorable sources.Mobilization of gold from the sub-seafloor rocks may require basalt-water, and/or carbonaceous sediment-water reactions to produce strongly reduced bisulfide, carbonyl or cyanide complexes that promote gold transport. Chloride complexing and transport are less important for gold but more so for silver and the base metals.Seafloor hydrothermal discharge at shallow depth is commonly accompanied by boiling, steamblast explosions in the vent and resulting deep penetration and mixing of cool, oxygenated seawater with rising hot, reduced metalliferous fluid. This results in deposition of both chloride- and isulfide-complexed gold at depth and centrally in the footwall stockwork or in copper ore in the base of the massive body. Chloride-complexed silver, stable to lower temperatures, is carried farther and deposited with higher-level and more distal, massive zinc-lead ores. Boiling in deep water, however, although possible, is rare. This fact minimizes deep fluid mixing and allows transport of lower temperaturestable, bisulfide-complexed gold to the seafloor and outward from the vent. Gold too, is then deposited with the shallower, distal, massive zinc-lead-silver ore. Late-stage changes in fluid Eh, salinity and activity of sulfur during evolution of the generative hydrothermal system, and by discharge through previously deposited, early stage sulfides around the vent also cause diagenetic remobilization of gold, moving it to shallower, more distal locations in the system. In combination, these relationships explain the three associations of gold in primary, in-situ massive sulfide deposits; in central, deep footwall stockwork mineralization with or without copper, in central copper ore in the base of the massive body and in shallow, peripheral pyritic zinclead-silver ore.Primary, in-situ ore near the vent is sometimes reworked by seafloor density flows which transport clasts of the primary sulfides down-slope, mix them with rock and sedimentary detritus and redeposit them to form secondary, transported ore. Gold, like iron and the base metals, is diluted during this clastic transport. But silver and barite may be enriched indicating transport in the density flows not only as clasts of primary ore but partly also m solution in the hydrothermal fluids that, in this case, must have lubricated the density flows.

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Zusammenfassung Gold- und Silbervorkommen in massiven Metallsulfid-Lagerstätten sind stets ökonomisch wichtige Metalle, auch wenn sie nur in geringen Konzentrationen vorliegen. Der Gehalt an diesen Metallen und ihre Verteilung innerhalb der Lagerstätte hängt von komplexen, sich gegenseitig beeinflussenden Faktoren wie Metallquelle, Art der Mobilisation, Transport und Fällung ab.Unterschiedliche Lagerstättentypen werden von ähnlichen hydrothermalen Systemen auf den Ozeanböden gebildet. Die tektonostratigraphischen Environments unterscheiden sich dabei allerdings beträchtlich; sie befinden sich in ensimatisch-ozeanischen, kontinentalrandlichen und ensialischkontinentalen Bereichen. Innerhalb dieser regional wechselnden Ablagerungsbedingungen variiert Konzentration und Verteilung der Edelmetalle in den Lagerstätten wie bei den einfachen Metallen. Dies bedeutet, daß der Gehalt an Edelmetallen der Gesteine, die den Meeresboden unterlagern und durch die die metallhaltigen Lösungen zirkulieren, ein Faktor ist, der Menge und Verteilung der Metalle in der Lagerstätte steuert. Ebenso ist die Lithologie dieser Gesteine von Bedeutung. Als besonders gut geeignete Quellen gelten kissenartige tholeitische Basalte mit hoher Permeabilität, goldarmen Kisseninneren und relativ goldreichem palagonitischem Rand.Um das Gold aus diesen Gesteinen mobilisieren zu können, bedarf es einer Reaktion zwischen Basalt und Wasser und/oder eines karbonatischen Sediments mit Wasser, um stark reduziertes Bisulfid, Carbonyl-oder Cyanidkomplexe zu bilden, die den Goldtransport ermöglichen. Chlorid-Komplexbildung und -Transport sind zwar wichtig für Silber und einfache Metalle, für Gold spielen sie nur eine untergeordnete Rolle.Der Austritt hydrothermaler Lösungen an Ozeanböden in geringer Tiefe wird in der Regel von Sieden und explosionsartigem Dampfaustritt begleitet und führt deshalb zu einem tiefen Eindringen und Durchmischen von kaltem, sauerstoffreichen Meereswasser mit den aufsteigenden heißen, reduzierten metallischen Lösungen. Daher kommt es zur Fällung von sowohl an Chloridkomplexe als auch an Bisulfidkomplexe gebundenem Gold. Diese Ausfällung findet in größerer Tiefe statt und zwar hauptsächlich im liegenden Stockwerk oder mit Kupfer zusammen an der Basis der massiven Lagerstätte. An Chloridkomplexe gebundenes Silber ist auch bei niedrigeren Temperaturen stabil, wird also weiter transportiert und in einem höheren Niveau in distal gelegenen Blei-Zink-Lagerstätten gefällt. In größeren Wassertiefen kommt es seltener zu dem beobachteten Sieden der austretenden Lösungen. Diese Tatsache reduziert das Durchmischen der Lösungen in größeren Tiefen und ermöglicht den Transport von Gold, das an Bisulfidkomplexe gebunden ist. In diesem Fall ist die Verbindung auch bei niedrigeren Temperaturen noch stabil also transportfähig und kann bis zum Meeresboden oder außerhalb des Schlotes in Lösung bleiben. Dabei kann das Gold zusammen mit Blei, Zink und Silber in mehr distalen Lagerstätten angereichert werden. Späte Änderungen in Eh, Salinität und Schwefelaktivität der Lösungen während der Entwicklung des hydrothermalen Systems, sowie der Austritt durch früher abgelagerte den Schlot umgebende Sulfide, können eine diagenetische Gold-Remobilisation auslösen. Auch dabei kann das Metall zu in geringer Tiefe liegenden, distalen Ablagerungsorten transportiert werden. Berücksichtigt man alle Faktoren, so erklären diese Verhältnisse die drei möglichen Goldvorkommen in primären, in-situ vorliegenden Sulfid-Lagerstätten: Mit Kupfer vergesellschaftet, allerdings nicht unbedingt, zentral im liegenden Stockwerk; an der Basis der Kupferlagerstätte und in geringer Tiefe in Verbindung mit peripheren Blei-Zink-Silber-Vorkommen.Primäre, in-situ neben Schloten vorkommende Lagerstätten werden in einigen Fällen von meeresbodennahen Masseströmen aufgearbeitet. Diese transportieren Sulfidkomponenten, die während des Transports mit Sediment und Gesteinsbruchstücken vermischt und schließlich als sekundäre sedimentäre Lagerstätte abgelagert werden. Durch diesen Transport und die Mischung der Klastika wird die Goldkonzentration in der späteren Lagerstätte stark reduziert. Silber und Barit können dagegen in Ausnahmefällen während des Transports angereichert werden, da diese Komponenten nicht nur als Sulfidbruchstücke transportiert werden, sondern auch in Lösung in den hydrothermalen Lösungen vorhanden sein können. Diese Lösungen dienen in solchen Fällen den Masseströmen als Gleithorizont.

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Résumé Dans les gisements de sulfures métalliques massifs, l'or et l'argent sont des métaux ubiquistes, parfois mineurs, mais toujours d'importance économique. Leur teneur et leur distribution dans les corps minéralisés dépendent de facteurs complexes, en relation les uns avec les autres, tels que: leur source, leur mobilité, leurs modalités de transport et de dépôt.A partir des mêmes systèmes hydrothermaux en action sur le fond de la mer, divers types de gisements peuvent être engendrés, selon leur environnement tectono-stratigraphique: océanique ensimatique, de marge continentale ou continental ensialique. Les teneurs et la répartition des métaux précieux, comme celle des autres métaux varient régionalement selon ces divers milieux. Ceci suggère que le contenu en métaux précieux dans les roches sous-jacentes au fond marin à travers lesquelles circulent les solutions minéralisantes est un facteur qui détermine leurs teneurs et leurs répartitions dans les minerais. La lithologie de ces roches-sources est également importante. Une source particulièrement significative est représentée par les coussins des basaltes tholéiitiques, très perméables, avec leur coeur pauvre en or et leur couronne palagonitique relativement riche.Le lessivage de l'or dans les roches situées sous le fond marin peut impliquer des réactions eau-basalte et/ou eausédiments carbonatés, réactions susceptibles d'engendrer les bisulfures très réduits et les complexes carbonés ou cyanurés qui permettent le transport de l'or. Le transport par complexes chlorurés joue un rôle subordoné dans le cas de l'or, mais important dans le cas de l'argent et des autres métaux.L'arrivée de solutions hydrothermales sur les fonds marins peu profonds est d'ordinaire accompagnée d'ébullitons et d'émissions explosives de vapeur, ce qui provoque la pénétration profonde d'eau de mer froide et oxygénée et son mélange avec les fluides métallifères chauds et réducteurs ascendants. Il en résulte le dépôt de complexes aurifères bisulfurés et chlorurés. Cette précipitation s'opère en profondeur, particulièrement dans les roches sous-jacentes ou dans le minerai de cuivre, à la base des corps minéralisés massifs. L'argent des complexes chlorurés, stables à plus basse température, est transporté plus loin et se dépose, en situation plus distale, dans les minerals massifs de Pb-Zn. Dans les mers profondes, l'ébullition, sans être impossible, est néanmoins un phénomène rare; cette circonstance minimise le mélange des fluides en profondeur et permet le transport de l'or jusqu'à la surface du fond et même loin des évents sous la forme de complexes bisulfurés stables à basse température. L'or est alors déposé en situation distale peu profonde avec les minerals massifs de Zn-Pb-Ag. Des modifications tardives d'Eh, de salinité et d'activité du soufre dans les solutions au cours de l'évolution du système hydrothermal, de même que le lessivage des sulfures déjà accumulés autour des évents entraînent une remobilisation diagénétique de l'or vers des situations distales d'eau peu profonde. La combinaison de ces divers facteurs permet d'expliquer les trois occurrences de l'or dans les dépôts in situ de sulfures massifs primaires: dans les parties centrales des masses sous-jacentes en association ou non avec le Cu, à la base des corps minéralisés en Cu, et à faible profondeur, en liaison avec les gisements périphériques de Pb-Zn-Ag.Les gisements primaires, formés in situ près des évents sont parfois remaniés par des courants de densité, qui emportent des clastes de sulfures, les mélangent aux débris sédimentaires et les redéposent sous forme de minerais secondaires. De tels transports provoquent la dilution de l'or, en même temps que celle du fer et des autres métaux. Par contre, l'argent et la barite peuvent subir un enrichissement car leur transport dans les courants de densité ne s'effectue pas seulement sous forme de clastes, mais également en solution dans des fludies hydrothermaux, lesquels, dans ce cas, contribuent à lubrifier le courant de densité.

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Low temperature volatile production at the Lost City Hydrothermal Field, evidence from a hydrogen stable isotope geothermometer   总被引：1，自引：0，他引：1  

Giora Proskurowski  Marvin D. Lilley  Deborah S. Kelley  Eric J. Olson 《Chemical Geology》2006,229(4):331-343

Although commonly utilized in continental geothermal work, the water-hydrogen and methane-hydrogen isotope geothermometers have been neglected in hydrothermal studies. Here we report δD-CH₄ and δD-H₂ values from high-temperature, black smoker-type hydrothermal vents and low-temperature carbonate-hosted samples from the recently discovered Lost City Hydrothermal Field. Methane deuterium content is uniform across the dataset at − 120 ± 12‰. Hydrogen δD values vary from − 420‰ to − 330‰ at high-temperature vents to − 700‰ to − 600‰ at Lost City. The application of several geothermometer equations to a suite of hydrothermal vent volatile samples reveals that predicted temperatures are similar to measured vent temperatures at high-temperature vents, and 20-60 °C higher than those measured at the Lost City vents. We conclude that the overestimation of temperature at Lost City reflects 1) that methane and hydrogen are produced by serpentinization at > 110 °C, and 2) that isotopic equilibrium at temperatures < 70 °C is mediated by microbial sulfate reduction. The successful application of hydrogen isotope geothermometers to low-temperature Lost City hydrothermal samples encourages its employment with low-temperature diffuse hydrothermal fluids.  相似文献   

Developing ecotourism in First World, resource-dependent areas   总被引：1，自引：0，他引：1  

Deborah Che 《Geoforum》2006,37(2):212-226

Ecotourism, an economic diversification tool most commonly applied in the Third World as a means to protect ecosystems, preserve local cultures, and spur economic development, has recently been applied in First World resource-dependent areas. While ecotourism has traditionally focused on Third World ‘undisturbed’ protected lands, it has also been developed in their First World equivalents (i.e., old-growth forests) as well as in First World sites of past resource extraction and in places where current agricultural practices maintain cherished cultural landscapes. Forest County, Pennsylvania, a timber-dependent area, sought to diversify its economy by developing ecotourism based on its unique Allegheny hardwood forests, which are produced by timber harvesting. This ecotourism would encourage amenity-based, locally-driven economic development and maintain timber harvesting. While government and foundation supported ecotourism development efforts in areas dependent on resource extraction have incorporated some of ecotourism’s ideals, these operations have had mixed success. Such isolated areas, which have traditionally drawn visitors independently engaging in traditional outdoor recreation activities, have not been able to draw enough customers willing to pay for natural and cultural history tours. If ecotourism is to be successful, such areas may need further government support and destination branding to increase name recognition in order to counter the global orientation of the nature tour industry. For true community development, local collaborative efforts including resource and environmental interests are also required in which primary production is connected to processing and consumers through value-added and service sector activities such as tourism.  相似文献   

Branding the design metropole: the case of Montréal, Canada     

Norma M Rantisi  Deborah Leslie 《Area》2006,38(4):364-376

As part of a broader process of inter-urban competition, city governments have increasingly sought to 'position' themselves as centres of creativity. In these branding initiatives, culture is viewed as a tool of urban regeneration and economic development. Our paper examines the case of Commerce Design Montréal, an annual design competition run by the City of Montréal, which aims to brand Montréal as a centre of design. Commerce Design Montréal is an example of a 'fast' policy initiated by the state, but carried out by business owners and citizens. As such, it represents a downloading of the responsibility for economic development to the private or individual scale and adopts only a partial view of the varied actors and uses that are implicated in the design process. The paper considers the opportunities and challenges that this model presents for promoting design as a form of urban regeneration in a neo-liberal context.  相似文献   

The Sahelian desertification debate: a view from the American south-west     

Charles F. Hutchinson 《Journal of Arid Environments》1996,33(4):519-524

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Calcium carbonate dissolution in deep sea sediments: reconciling microelectrode, pore water and benthic flux chamber results   总被引：1，自引：0，他引：1  

Richard A. Jahnke  Deborah B. Jahnke 《Geochimica et cosmochimica acta》2004,68(1):47-59

We report the benthic fluxes of O₂, titration alkalinity (TA), Ca²⁺, NO₃⁻, PO₄³⁻, and Si(OH)₄ from in situ benthic flux chamber incubations on the Ceara Rise and Cape Verde Plateau and compare them to previously published results. We find within analytical uncertainty that the TA flux is twice the calcium flux, suggesting that dissolution/precipitation of CaCO₃ is the principal mechanism controlling benthic TA and Ca²⁺ fluxes. At sites where the sediments contain significant (>35%) CaCO₃ and the overlying waters are supersaturated with respect to CaCO₃, the ratios of the total dissolution rate to the remineralization rate are significantly less than at all other study sites. We propose that these observations can be explained by precipitation of fresh CaCO₃ at the supersaturated sediment surface followed by redissolution deeper in the sediments because of metabolically-produced CO₂. A numerical simulation is presented to demonstrate the feasibility of this explanation. In addition, surface exchange reactions in high-CaCO₃ sediments coupled with high rates of particle mixing may also impact rates of metabolic dissolution and depress chamber-derived estimates of carbonate alkalinity and calcium benthic fluxes. These results suggest that at supersaturated, high CaCO₃ locations, previous models of sediment diagenesis may have overestimated the impact of metabolic dissolution on the preservation of CaCO₃ deposited on the sea floor.  相似文献