The redox states of basic and silicic magmas: a reflection of their source regions?   总被引：22，自引：1，他引：21  

Ian S. E. Carmichael 《Contributions to Mineralogy and Petrology》1991,106(2):129-141

At present the best estimates of the oxygen fugacity of spinel-lherzolites that could be the source material of basic magmas is about five log units below the Ni–NiO buffer to one above it. However partially glassy basic lavas, ranging from MORBs to minettes, all with olivine on their liquidus, cover a wider range, and may have oxygen fugacities that extend to four log units above NNO. Surprisingly the range of oxygen fugacities observed in silicic lavas and ashflows with quartz phenocrysts is smaller, despite a crustal dominated evolution. The peralkaline silicic lava type pantellerite is the most reduced, equivalent to MORBs, whereas the large volume ashflows with phenocrysts of hornblende and/or sphene are the most oxidised. As the concentration of water in the basic lavas is correlated with increase in their redox state, it would seem that water could be the agent of this increase. That this is unlikely is seen in the behavior of silicic ashflows and lavas, particularly those of Yellowstone. Here the silicic magmas of the last 2Ma contain about 2 wt% FeO_(total), and typically phenocrysts of fayalite, quartz and Fe–Ti oxides. Despite extensive exchange of the ¹⁸O of the magma with meteoric water after caldera collapse (Hildreth et al. 1984), there is no displacement of the redox equilibria. Thus the thermal dissociation of molecular H₂O to H₂, and its subsequent diffusive loss to cause oxidation must have been minimal. This could only be so if the activity of water was small, as it would be if H₂O reacted with the silicate liquid to form OH groups (Stolper 1982). The conclusion is that silicic magmas with small amounts of iron and large amounts of water do not have their redox states reset, which in turn presumably reflect their generation. By analogy basic magmas with large amounts of iron and far less water are even less likely to have their redox equilibria disturbed, so that their oxygen fugacities will also reflect their source regions. The effect of pressure on the ferric-ferrous equilibrium in basic magmas can be calculated from experimental measurements of the partial molar volumes of FeO and Fe₂O₃, and their pressure derivatives V/P, in silicate liquids. The effect of pressure is found to be about the same on the liquid as it is for various solid oxygen buffers. Accordingly there should be mantle source regions covering the same range of oxygen fugacity as that found in basic lavas, but so far samples of spinel-lherzolite of equivalent oxygen fugacity to minettes or other potassic lavas have not been found. Whether or not the redox state of phlogopite-pyroxenites is equivalent to these potassic lavas cannot be established without experiment.  相似文献   

Quaternary minettes and associated volcanic rocks of Mascota,western Mexico: a consequence of plate extension above a subduction modified mantle wedge   总被引：12，自引：0，他引：12  

I. S. E. Carmichael  R. A. Lange  James F. Luhr 《Contributions to Mineralogy and Petrology》1996,124(3-4):302-333

 Pleistocene-Holocene volcanism in the Jalisco block of western Mexico is confined to two conspicuous grabens, where potassic eruptives range from absarokites (48–52% SiO₂) and minettes (49–54% SiO₂) through basaltic andesites (53–57% SiO₂), the most voluminous type, to andesites and their lamprophyric equivalent spessartite (58–62% SiO₂); there are no contemporary rhyolitic rocks. This suite has high concentrations of Mg, Cr (<550 ppm) and Ni (<450 ppm) accompanied by large concentrations of K, P, Ba (<4000 ppm) and Sr (<5000 ppm) and elements such as LREE and Zr (<600 ppm). No combination of crystal fractionation and/or crustal contamination can reproduce the compositional range of these magmas, which nevertheless are believed to be genetically related because of their proximity in time and space. Hydrous minerals in the lamprophyres and the typical absence of plagioclase phenocrysts in both basaltic andesites and andesites reflect the relatively high concentrations of water in the magmas, which suppressed the crystallisation of feldspar. Experimental verification of the minimal amounts of water required to reproduce the phenocryst assemblages in selected rocks range from 3.5 to 6%. During ascent in a volcanic conduit, andesitic magma may lose water and consequently precipitate plagioclase, or it may ascend more rapidly, retaining more of its initial water, which stabilises phenocrysts of hornblende at the expense of plagioclase. Our estimates of water concentrations, which are consistent with the various low pressure phenocryst assemblages, will be minimal for the magmas in their source regions, and the process of magmatic dewatering on ascent may be typical in well established volcanic conduits. In accord with the compositions of phenocrystic olivine in the basaltic andesites and the minettes, the values of FeO and Fe₂O₃ of the bulk lavas and scoriae are demonstrably pristine. As a consequence, there are two characteristic features of the Mascota suite: the high range of relative oxygen fugacities (ΔNNO=1–5) and the high Mg# (MgO/MgO+FeO) that ranges from 0.70 to 0.91 (with only one andesite as low as 0.66). From the evidence of phlogopite phenocrysts, a partial melt involving phlogopite would have a higher Mg# than one from olivine (Fo₉₀) and pyroxene alone. As the Mascota series shows a correlation between K₂O and Mg#, we conclude that it was generated by partial fusion of the mantle wedge, with a variable contribution of phlogopite and apatite from veins throughout the lherzolitic assemblage. In conformity with an origin by varying increments of partial fusion of a phlogopite-bearing mantle, all incompatible elements vary linearly with Ti (or K) as if phlogopite (+apatite) in the source dominated their contribution to the partial melts. Fluids from dehydration of the subducting slab presumably deposit hydrous and other minerals in veins in the mantle wedge and also increase its redox state. As the Mascota volcanism occurs in grabens closer to the trench than the main andesite arc, it is concluded that the eruption of these small volumes of hydrous magmas require the tectonically favored ascent paths offered by the extensional grabens to reach the surface from their mantle sources. Received: 24 January 1995 / Accepted: 21 February 1996  相似文献   

Water source dynamics of high Arctic river basins          下载免费PDF全文

Phillip J. Blaen  David M. Hannah  Lee E. Brown  Alexander M. Milner 《水文研究》2014,28(10):3521-3538

Arctic river basins are amongst the most vulnerable to climate change. However, there is currently limited knowledge of the hydrological processes that govern flow dynamics in Arctic river basins. We address this research gap using natural hydrochemical and isotopic tracers to identify water sources that contributed to runoff in river basins spanning a gradient of glacierization (0–61%) in Svalbard during summer 2010 and 2011. Spatially distinct hydrological processes operating over diurnal, weekly and seasonal timescales were characterized by river hydrochemistry and isotopic composition. Two conceptual water sources (‘meltwater’ and ‘groundwater’) were identified and used as a basis for end‐member mixing analyses to assess seasonal and year‐to‐year variability in water source dynamics. In glacier‐fed rivers, meltwater dominated flows at all sites (typically >80%) with the highest contributions observed at the beginning of each study period in early July when snow cover was most extensive. Rivers in non‐glacierized basins were sourced initially from snowmelt but became increasingly dependent on groundwater inputs (up to 100% of total flow volume) by late summer. These hydrological changes were attributed to the depletion of snowpacks and enhanced soil water storage capacity as the active layer expanded throughout each melt season. These findings provide insight into the processes that underpin water source dynamics in Arctic river systems and potential future changes in Arctic hydrology that might be expected under a changing climate. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Long‐term streamflow trends in Hawai'i and implications for native stream fauna     

Hannah M. Clilverd  Yin‐Phan Tsang  Dana M. Infante  Abigail J. Lynch  Ayron M. Strauch 《水文研究》2019,33(5):699-719

Climate change has fundamentally altered the water cycle in tropical islands, which is a critical driver of freshwater ecosystems. To examine how changes in streamflow regime have impacted habitat quality for native migratory aquatic species, we present a 50‐year (1967–2016) analysis of hydrologic records in 23 unregulated streams across the five largest Hawaiian Islands. For each stream, flow was separated into direct run‐off and baseflow and high‐ and low‐flow statistics (i.e., Q10 and Q90) with ecologically important hydrologic indices (e.g., frequency of flooding and low flow duration) derived. Using Mann–Kendall tests with a running trend analysis, we determined the persistence of streamflow trends through time. We analysed native stream fauna from ~400 sites, sampled from 1992 to 2007, to assess species richness among islands and streams. Declines in streamflow metrics indicated a general drying across the islands. In particular, significant declines in low flow conditions (baseflows), were experienced in 57% of streams, compared with a significant decline in storm flow conditions for 22% of streams. The running trend analysis indicated that many of the significant downward trends were not persistent through time but were only significant if recent decades (1987–2016) were included, with an average decline in baseflow and run‐off of 10.90% and 8.28% per decade, respectively. Streams that supported higher native species diversity were associated with moderate discharge and baseflow index, short duration of low flows, and negligible downward trends in flow. A significant decline in dry season flows (May–October) has led to an increase in the number of no‐flow days in drier areas, indicating that more streams may become intermittent, which has important implications for mauka to makai (mountain to ocean) hydrological connectivity and management of Hawai'i's native migratory freshwater fauna.  相似文献   

Development of large‐scale seismites in Upper Cretaceous fluvial sandstones in a fault‐proximal setting          下载免费PDF全文

Michael C. Wizevich  Edward L. Simpson  Hannah L. Hilbert‐Wolf  Sarah E. Tindall 《Sedimentology》2016,63(6):1719-1738

Large‐scale soft‐sediment deformation structures occur within fluvial sandstone bodies of the Upper Cretaceous Wahweap Formation in the Kaiparowits basin, southern Utah, USA. These structures represent an exceptional example of metre‐scale fault‐proximal, seismogenic load structures in nearly homogenous sandstones. The load structures consist of two types: large‐scale load casts and wedge‐shaped load structures. Large‐scale load casts penetrate up to 4·5 m into the underlying sandstone bed. Wedge‐shaped load structures include metre‐scale, parallel, sub‐vertical features and decimetre‐scale features along the periphery of the large‐scale load casts or other wedge‐shaped load structures. Wedge‐shaped load structures contain well‐developed, medial cataclastic shear deformation bands. All load structures contain pervasive well‐defined millimetre‐thick to centimetre‐thick internal laminae, oriented parallel to the outside form of the load structures and asymptotic to deformation bands. Both types of load structures formed because of an inverted density profile, earthquake‐triggered liquefaction and growth of irregularities (a Rayleigh–Taylor instability) on the sandstone–sandstone erosional contact. The internal laminae and deformation bands formed during deformation and clearly demonstrate polyphase deformation, recording a transition from liquefied to hydroplastic to brittle modes of deformation. Decimetre‐scale wedge‐shaped load structures on the edge of the large‐scale load casts probably formed towards the end of a seismic event after the sediment dewatered and increased the frictional contact of grains enough to impart strength to the sands. Metre‐scale wedge‐shaped load structures were created as the tips of downward foundering sediments were driven into fractures, which widened incrementally with seismic pulsation. With each widening of the fracture, gravity and a suction effect would draw additional sediment into the fracture. Superimposed laminae indicate a secondary syndeformational origin for internal laminae, probably by flow‐generated shearing and vibrofluidization mechanisms. Large‐scale and wedge‐shaped load structures, polyphase deformation and secondary laminae may characterize soft‐sediment deformation in certain fault‐proximal settings.  相似文献   

Policy options to streamline the carbon market for agricultural nitrous oxide emissions     

Meredith T. Niles  Hannah Waterhouse  Robert Parkhurst  Eileen L. McLellan  Sara Kroopf 《Climate Policy》2019,19(7):893-907

The majority of emissions of nitrous oxide – a potent greenhouse gas (GHG) – are from agricultural sources, particularly nitrogen fertilizer applications. A growing focus on these emission sources has led to the development in the United States of GHG offset protocols that could enable payment to farmers for reducing fertilizer use or implementing other nitrogen management strategies. Despite the development of several protocols, the current regional scope is narrow, adoption by farmers is low, and policy implementation of protocols has a significant time lag. Here we utilize existing research and policy structures to propose an ‘umbrella’ approach for nitrogen management GHG emissions protocols that has the potential to streamline the policy implementation and acceptance of such protocols. We suggest that the umbrella protocol could set forth standard definitions common across multiple protocol options, and then modules could be further developed as scientific evidence advances. Modules could be developed for specific crops, regions, and practices. We identify a policy process that could facilitate this development in concert with emerging scientific research and conclude by acknowledging potential benefits and limitations of the approach.

Key policy insights

• Agricultural greenhouse gas market options are growing, but are still underutilized

• Streamlining protocol development through an umbrella process could enable quicker development of protocols across new crops, regions, and practices

• Effective protocol development must not compromise best available science and should follow a rigorous pathway to ensure appropriate implementation

  相似文献   

The compressibility of silicate liquids containing Fe2O3 and the effect of composition,temperature, oxygen fugacity and pressure on their redox states     

Victor C. Kress  Ian S. E. Carmichael 《Contributions to Mineralogy and Petrology》1991,108(1-2):82-92

Ultrasonic longitudinal acoustic velocities in oxidized silicate liquids indicate that the pressure derivative of the partial-molar volume of Fe₂O₃ is the same in iron-rich alkali-, alkaline earth- and natural silicate melt compositions at 1 bar. The dV/dP for multicomponent silicate liquids can be expressed as a linear combination of partial-molar constants plus a positive excess term for Na₂O−Al₂O₃ mixing. Partial-molar properties for FeO and Fe₂O₃ components allow extension of the empirical expression of Sack et al. (1980) to permit the calculation of Fe-redox equilibrium in a natural silicate liquid as a function of composition, temperature, fo₂ and pressure; a more formal thermodynamic expression is presented in the Appendix. The predicted equilibrium fo₂ of natural silicate melts, of fixed oxygen content, closely parallels that defined by the metastable assemblage fayalite+magnetite+β-quartz (FMQ), in pressure-temperature space. A silicate melt initially equilibrated at 3 GPa and FMQ, will remain within approximately 0.5 log₁₀ units of FMQ during its closed-system ascent. Thus, for magmas closed to oxygen, iron-redox equilibrium in crystal-poor pristine glassy lavas represents an excellent probe of the relative oxidation state of their source regions.  相似文献   

Lamprophyric lavas in the Colima graben,SW Mexico   总被引：2，自引：3，他引：2  

J. F. Allan  I. S. E. Carmichael 《Contributions to Mineralogy and Petrology》1984,88(3):203-216

The Colima graben, located in SW Mexico, is one of three grabens which intersect about 50 km SSW of Guadalajara, forming a triple junction. The 90 km long, 20–60 km wide Colima graben represents a N-S rift of the E-W trending Mexican Volcanic Belt. Since the Early Pliocene, the Colima graben has served as a locus for the eruption of alkaline lavas, the most recent of which are basanites and minettes erupted from Late Pleistocene cinder cones (Luhr and Carmichael 1981). In this paper, we report on older alkaline lavas which crop out in the graben's walls. These rocks include phlogopite- and hornblende-bearing lamprophyres, a phlogopite-kalsilite-ankaratrite, and high-K andesites. These lavas crop out throughout the Colima graben area, and are intimately associated with calc-alkaline lavas in the field. Compared to these, the alkaline rocks are strikingly enriched in the incompatible elements, particularly Ba, Sr, P, and the LREE. Unlike the younger Late Pleistocene alkaline cinder cone lavas, most of the graben wall lamprophyres and the high-K andesites represent magmas that appear to have undergone significant evolution since their generation, including fractionation, crustal contamination, and possible magma mixing. Least-squares modeling indicates that the cinder cone minettes represent reasonable parental magmas for the graben lamprophyres. The occurrence of these alkaline lavas in an active calc-alkaline volcanic arc is unusual, and we suggest that they are a manifestation of the rifting processes which produced the Colima graben.  相似文献   

Experimental petrology of alkalic lavas: constraints on cotectics of multiple saturation in natural basic liquids     

Richard O. Sack  David Walker  Ian S. E. Carmichael 《Contributions to Mineralogy and Petrology》1987,96(1):1-23

Experimental study of natural alkalic lava compositions at low pressures (pO₂QFM) reveals that crystallization of primitive lavas often occurs in the sequence olivine, plagioclase, clinopyroxene, nepheline without obvious reaction relation. Pseudoternary liquidus projections of multiply saturated liquids coexisting with plagioclase (±olivine±clinopyroxene±nepheline) have been prepared to facilitate graphical analysis of the evolution of lava compositions during hypabyssal cooling. Use of (TiAl₂)(MgSi₂)_–1 and Fe³⁺ (Al)_–1 exchange components is a key aspect of the projection procedure which is succesful in reducing a wide range of compositions to a systematic graphical representation. These projections, and the experiments on which they are based, show that low pressure fractionation plays a significant role in the petrogenesis of many alkalic lava suites from both continental and oceanic settings. However, the role of polybaric fractionation is more evident in the major element chemistry of these lava suites than in many tholeiitic suites of comparable extent. For example, the lavas of Karisimbi, East Africa, show a range of compositions reflecting a polybaric petrogenesis from primitive picrites at 1360° C/18 kb and leading to advanced low pressure differentiates. Evolved leucite-bearing potassic members of this and other suites may be treated in a nepheline-diopside-kspar (+olivine+leucite) projection. Compositional curvature on the plagioclase+clinopyroxene+olivine+leucite cotectic offers a mechanism to explain resorption of plagioclase in alkalic groundmass assemblages and the incompatibility of albite and leucite. This projection is useful for evaluating the extent of assimilation of the alkalic portions of crustal granulites. Assimilation appears to have played some role in the advanced differentiates from Karisimbi.  相似文献   

P total,P_{H_2 O} and the occurrence of cummingtonite in volcanic rocks     

B. J. Wood  I. S. E. Carmichael 《Contributions to Mineralogy and Petrology》1973,40(2):149-158

The phenocryst assemblage of cummingtonite, orthopyroxene, quartz, titanomagnetite and ilmenite in rhyolites of New Zealand has been used to calculate P _total and . The values of P _total and depend strongly upon whether an ideal mixing, or an ordered, model is used for the solid-solutions, but in both cases P _total.The rhyolite magma contained over 9 per cent water (by weight) when the cummingtonite phenocrysts precipitated, and possibly as much as 12 per cent, so that it is surprising that one of these rhyolites is a coherent lava. The calculated values of P _total and are very sensitive to uncertainty in both the composition of the solid-solutions and temperature. Calculations show that >0.7–0.8 P _total for cummingtonite to precipitate in rhyolites, and that iron-rich olivine and cummingtonite could only exist in rhyolites over a small temperature range at a pressure near 5 kilobars. Hornblende phenocrysts co-existing with fayalitic olivine in rhyolites accordingly have a very low activity of Mg₇Si₈O₂₂(OH)₂.  相似文献