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Recently the method of flotation is used as a simple step within a number of procedures of chemical analysis for enrichment of waters or industrial lyes to be investigated by ions. By the example of tin analysis all the possible variants are compared with regard to their efficiency. The advantages result from the using conventional methods of chemical analysis in connection with coprecipitation of traces and their flotation at trace levels of ng/ml. The flotation is a fast method of enrichment, it is easily to handle and sufficiently exact. As a proof example the chemical analysis of Sn, Au and Ag is described.  相似文献   
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The technique of linear parametric programming has been applied to derive sets of internally consistent thermodynamic data for 21 condensed phases of the quaternary system CaO-Al2O3-SiO2-H2O (CASH) (Table 4). This was achieved by simultaneously processing:
  1. calorimetric data for 16 of these phases (Table 1), and
  2. experimental phase equilibria reversal brackets for 27 reactions (Table 3) involving these phases.
Calculation of equilibrium P-T curves of several arbitrarily picked reactions employing the preferred set of internally consistent thermodynamic data from Table 4 shows that the input brackets are invariably satisfied by the calculations (Fig. 2a). By contrast, the same equilibria calculated on the basis of a set of thermodynamic data derived by applying statistical methods to a large body of comparable input data (Haas et al. 1981; Hemingway et al. 1982) do not necessarily agree with the experimental reversal brackets. Prediction of some experimentally investigated phase relations not included into the linear programming input database also appears to be remarkably successful. Indications are, therefore, that the thermodynamic data listed in Table 4 may be used with confidence to predict geologic phase relations in the CASH system with considerable accuracy. For such calculated phase diagrams and their petrological implications, the reader's attention is drawn to the paper by Chatterjee et al. (1984).  相似文献   
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We present a geochemical and isotopic study that, consistent with observed field relations, suggest Sangmelima late Archaean high-K granite was derived by partial melting of older Archaean TTG. The TTG formations are sodic-trondhjemitic, showing calcic and calc-alkalic trends and are metaluminous to peraluminous. High-K granites in contrast show a potassic calc-alkaline affinity that spans the calcic, calc-alkalic, alkali-calcic and alkalic compositions. The two rock groups (TTG and high-K granites) on the other hand are both ferroan and magnesian. They have a similar degree of fractionation for LREE but a different one for HREE. Nd model ages and Sr/Y ratios define Mesoarchaean and slab-mantle derived magma compositions respectively, with Nb and Ti anomalies indicating a subduction setting for the TTG. Major and trace element in addition to Sr and Nd isotopic compositions support field observations that indicate the derivation of the high-K granitic group from the partial melting of the older TTG equivalent at depth. Geochemical characteristics of the high-K granitic group are therefore inherited features from the TTG protolith and cannot be used for determining their tectonic setting. The heat budget required for TTG partial melting is ascribed to the upwelling of the mantle marked by a doleritic event of identical age as the generated high-K granite melts. The cause of this upwelling is related to linear delamination along mega-shear zones in an intracontinental setting.  相似文献   
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Cokriging is applied to the estimation of mineral resources in a polymetallic deposit. Several major steps, which should be taken in using cokriging, are highlighted as necessary practical considerations. The case study is related to an ultramafic copper-nickel deposit. Six elements, Cu, Ni, Au, Ag, Pt, and Pd, occurring in the deposit, are partitioned into three subgroups and the elements within each group are simultaneously estimated on the basis of over 4000 drill assays. A comparison was made between ordinary kriging and cokriging methods through cross-validation. The results show that cokriging has significantly improved the estimates of resources by reducing the overall estimation error by over 15% and the variance of error by over 20%.  相似文献   
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Present rate of uplift in Fennoscandia from GRACE and absolute gravimetry   总被引:2,自引:0,他引:2  
Fennoscandia is a key region for studying effects of glacial isostatic adjustment. The associated mass variations can be detected by the Gravity Recovery and Climate Experiment (GRACE) satellite mission, which observes the Earth's gravity field since April 2002, as well as by absolute gravimetry field campaigns. Since 2003, annual absolute gravity (AG) measurements have been performed in Fennoscandia by the Institut für Erdmessung (IfE, Institute of Geodesy) of the Leibniz Universität Hannover, Germany, within a multi-national cooperation. This offers a unique opportunity for validation and evaluation of the GRACE results. In this preliminary study, the GRACE results are compared to secular gravity changes based on the surveys from 2004 to 2007 with the FG5-220 gravimeter of the IfE.The results from GRACE monthly solutions provided by different analysis centres show temporal gravity variations in Fennoscandia. The included secular variations are in good agreement with former studies. The uplift centre is located west of the Bothnian Bay, the whole uplift area comprises Northern Europe. Nevertheless, the differences between the GRACE solutions are larger than expected and the different centre-specific processing techniques have a very strong effect on possible interpretations of GRACE results. The comparison of GRACE to the AG measurements reveals that the determined trends fit well with results from GRACE at selected stations, especially for the solution provided by the GFZ. Variations of land hydrology clearly influence results from GRACE and the AG measurements.  相似文献   
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Large rock slope failures play a pivotal role in long-term landscape evolution and are a major concern in land use planning and hazard aspects. While the failure phase and the time immediately prior to failure are increasingly well studied, the nature of the preparation phase remains enigmatic. This knowledge gap is due, to a large degree, to difficulties associated with instrumenting high mountain terrain and the local nature of classic monitoring methods, which does not allow integral observation of large rock volumes. Here, we analyse data from a small network of up to seven seismic sensors installed during July–October 2018 (with 43 days of data loss) at the summit of the Hochvogel, a 2592 m high Alpine peak. We develop proxy time series indicative of cyclic and progressive changes of the summit. Modal analysis, horizontal-to-vertical spectral ratio data and end-member modelling analysis reveal diurnal cycles of increasing and decreasing coupling stiffness of a 260,000 m3 large, instable rock volume, due to thermal forcing. Relative seismic wave velocity changes also indicate diurnal accumulation and release of stress within the rock mass. At longer time scales, there is a systematic superimposed pattern of stress increased over multiple days and episodic stress release within a few days, expressed in an increased emission of short seismic pulses indicative of rock cracking. Our data provide essential first order information on the development of large-scale slope instabilities towards catastrophic failure. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   
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