Exposure history of the Torino meteorite     

R. Wieler  Th. Graf  P. Signer  S. Vogt  G. F. Herzog  C. Tuniz  D. Fink  L. K. Fifield  J. Klein  R. Middleton  A. J. T. Jull  P. Pellas  J. Masarik  G. Dreibus 《Meteoritics & planetary science》1996,31(2):265-272

Abstract— We determined He, Ne, Ar, ¹⁰Be, ²⁶Al, ³⁶Cl, and ¹⁴C concentrations, as well as cosmic-ray track densities and halogen concentrations in different specimens of the H6 chondrite Torino, in order to constrain its exposure history to cosmic radiation. The Torino meteoroid had a radius of ～20 cm and travelled in interplanetary space for 2.5–10 Ma. Earlier, Torino was part of a larger body. The smallest possible precursor had a radius of 55 cm and a journey through space longer than ～65 Ma. If the first-stage exposure took place in a body with a radius of >3 m or in the parent asteroid, then it lasted nearly 300 Ma. The example of Torino shows that it is easy to underestimate first-stage exposure ages when constructing two-stage histories.  相似文献   

Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois     

B.L. Herzog  R.A. Griffin  C.J. Stohr  L.R. Follmer  W.J. Morse  W.J. Su 《Ground Water Monitoring & Remediation》1989,9(2):82-89

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.  相似文献   

⁴⁰Ar³⁹Ar ages of Allende     

Elmar K. Jessberger  Bogna Dominik  Thomas Staudacher  Gregory F. Herzog 《Icarus》1980,42(3):380-405

KAr and/or ⁴⁰Ar³⁹Ar plateau ages of Allende samples—whole rock, matrix, chondrules, white inclusions–range from 3.8 AE for matrix of ?5 AE for some white inclusions, but cluster strongly near 4.53 AE. This age marks the dominant KAr resetting of Allende materials. Age spectra show disturbances due to ³⁹Ar recoil or some other argon redistribution processes. Possible explanations for the apparent presolar ages (>4.6 AE) include: ?20% loss of ³⁹Ar; ?40% loss of ⁴⁰K ～3.8 AE ago with no loss of ⁴⁰Arl trapped argon of unique ⁴⁰Ar/³⁶Ar isotopic composition; admixture of “very old” presolar grains.  相似文献   

Editorial: The LITFASS-98 experiment     

F. Beyrich  T. Foken  H.-J. Herzog 《Theoretical and Applied Climatology》2002,73(1-2):1-2

  相似文献   

An Issue of Permanence: Assessing the Effectiveness of Temporary Carbon Storage     

Howard Herzog  Ken Caldeira  John Reilly 《Climatic change》2003,59(3):293-310

In this paper, we present a method to quantify the effectiveness of carbon mitigation options taking into account the `permanence' of the emissions reduction. While the issue of permanence is most commonly associated with a `leaky' carbon sequestration reservoir, we argue that this is an issue that applies to just about all carbon mitigation options. The appropriate formulation of this problem is to ask `what is the value of temporary storage?' Valuing temporary storage can be represented as a familiar economic problem, with explicitly stated assumptions about carbon prices and the discount rate. To illustrate the methodology, we calculate the sequestration effectiveness for injecting CO₂ at various depths in the ocean. Analysis is performed for three limiting carbon price assumptions: constant carbon prices (assumes constant marginal damages), carbon prices rise at the discount rate (assumes efficient allocation of a cumulative emissions cap without a backstop technology), and carbon prices first rise at the discount rate but become constant after a given time (assumes introduction of a backstop technology). Our results show that the value of relatively deep ocean carbon sequestration can be nearly equivalent to permanent sequestration if marginal damages (i.e., carbon prices) remain constant or if there is a backstop technology that caps the abatement cost in the not too distant future. On the other hand, if climate damages are such as to require a fixed cumulative emissions limit and there is no backstop, then a storage option with even very slow leakage has limited value relative to a permanent storage option.  相似文献   

Continuous Multi‐probe Measurements in Fastflowing Waters Using a Hydrographic Slot     

Bernhard Karrasch  Michael Herzog 《洁净——土壤、空气、水》2005,33(2):165-169

Taking continuous spatiotemporal in situ measurements with multi‐probes in fast‐flowing waters/rivers can be problematic because the sensors may be damaged by high shear forces and flotsam. To protect the multi‐probe and to enable easy access for the maintenance and calibration of the sensors, a special multi‐probe holder fixed in a hydrographic slot was developed. The validation of the probe system revealed a “memory effect” at short time scales (< 10 s) within sharp gradients caused by the overflow container of the multi‐probe rack keeping the sensors submerged in the sample water. Continuously recorded data (conductivity, temperature, pH, oxygen concentration and saturation, as well as in vivo fluorescence of chlorophyll‐a) from a research cruise on board the RV ALBIS along the river Elbe (river km 309) and entering the river Saale are presented. This river stretch upstream of the city of Magdeburg to the mouth of the Saale tributary was found to have a complex physicochemical character, which is attributable to the long mixing process of water from the river Saale and the river Elbe.  相似文献   

Isotopic compositions of oxygen, iron, chromium, and nickel in cosmic spherules: Toward a better comprehension of atmospheric entry heating effects     

Cécile Engrand  Kevin D. McKeegan  Gregory F. Herzog  Laurence E. Nyquist 《Geochimica et cosmochimica acta》2005,69(22):5365-5385

Large, correlated, mass-dependent enrichments in the heavier isotopes of O, Cr, Fe, and Ni are observed in type-I (metal/metal oxide) cosmic spherules collected from the deep sea. Limited intraparticle variability of oxygen isotope abundances, typically <5‰ in δ¹⁸O, indicates good mixing of the melts and supports the application of the Rayleigh equation for the calculation of fractional evaporative losses during atmospheric entry. Fractional losses for oxygen evaporation from wüstite, assuming a starting isotopic composition equal to that of air (δ¹⁸O = 23.5‰; δ¹⁷O = 11.8‰), are in the range 55%-77%, and are systematically smaller than evaporative losses calculated for Fe (69%-85%), Cr (81%-95%), and especially Ni (45%-99%). However, as δ¹⁸O values increase, fractional losses for oxygen approach those of Fe, Cr, and Ni indicating a shift in the evaporating species from metallic to oxidized forms as the spherules are progressively oxidized during entry heating. The observed unequal fractional losses of O and Fe can be reconciled by allowing for a kinetic isotope mass-dependent fractionation of atmospheric oxygen during the oxidation process and/or that some metallic Fe may have undergone Rayleigh evaporation before oxidation began.In situ measurements of oxygen isotopic abundances were also performed in 14 type-S (silicate) cosmic spherules, 13 from the Antarctic ice and one from the deep sea. Additional bulk Fe and Cr isotopic abundances were determined for two type-S deep-sea spherules. The isotopic fractionation of Cr isotopes suggest appreciable evaporative loss of Cr, perhaps as a sulfide. The oxygen isotopic compositions for the type-S spherules range from δ¹⁸O = −2‰ to + 27‰. The intraspherule isotopic variations are typically small, ∼5% relative, except for the less-heated porphyritic spherules which have preserved large isotopic heterogeneities in at least one case. A plot of δ¹⁷O vs. δ¹⁸O values for these spherules defines a broad parallelogram bounded at higher values of δ¹⁷O by the terrestrial fractionation line, and at lower values of δ¹⁷O by a line parallel to it and anchored near the isotopic composition of δ¹⁸O = −2.5‰ and δ¹⁷O = −5‰. Lack of independent evidence for substantial evaporative losses suggests that much of this variation reflects the starting isotopic composition of the precursor materials, which likely resembled CO, CM, or CI chondrites. However, the enrichments in heavy isotopes indicate that some mixing with atmospheric oxygen was probably involved during atmospheric entry for some of the spherules. Isotopic fractionation due to evaporation of incoming grain is not required to explain most of the oxygen isotopic data for type-S spherules. However spherules with barred olivine textures that are thought to have experienced a more intense heating than the porphyritic ones might have undergone some distillation. Two cosmic spherules, one classified as a radial pyroxene type and the other showing a glassy texture, show unfractionated oxygen isotopic abundances. They are probably chondrule fragments that survived atmospheric entry unmelted.Possible reasons type-I spherules show larger degrees of isotopic fractionation than type-S spherules include: a) the short duration of the heating pulse associated with the high volatile content of the type-S spherule precursors compared to type-I spherules; b) higher evaporation temperatures for at least a refractory portion of the silicates compared to that of iron metal or oxide; c) lower duration of heating of type-S spherules compared to type-I spherules as a consequence of their lower densities.  相似文献   

Phylogeography of the pelagic fish Seriola lalandi at different scales: confirmation of inter-ocean population structure and evaluation of southern African genetic diversity     

BL Swart  AE Bester-van der Merwe  SE Kerwath 《African Journal of Marine Science》2016,38(4):513-524

The study investigated the global and regional phylogeography of the yellowtail kingfish Seriola lalandi by examining genetic diversity and population genetic structure of this species at inter-and intra-ocean level and on a regional scale. DNA fragments of two mitochondrial genes, cytochrome b (Cytb) and cytochrome c oxidase subunit I (COI) and one nuclear gene, recombination activating gene 1 (RAG1), were sequenced to investigate the global-scale phylogeography of this species. The population genetic structure within the South Pacific, as well as along the South African coastline, was examined further using six microsatellite markers. Three distinct clades were identified for S. lalandi, which correspond with previously described subspecies of the North-East Pacific, North-West Pacific and the Southern Hemisphere. Within the latter, additional divergence was observed between the South Pacific and the South-East Atlantic regions. Divergence estimates were indicative of a Pacific origin for S. lalandi populations, because of Pleistocene vicariant events. Microsatellite analyses revealed overall significant genetic differentiation between South African and South Pacific samples. This corroborates recent findings on the global phylogeography of the species. No population differentiation was observed within South Africa, indicating high levels of gene flow.  相似文献   

Testing a radiative upper boundar condition in a nonlinear model with hybrid vertical coordinate     

H. -J. Herzog 《Meteorology and Atmospheric Physics》1995,55(3-4):185-204

Summary The application of a radiative upper boundary condition (RUBC) in a mesoscale numerical weather prediction (NWP) model with hybrid vertical coordinate is presented. Results of two- and three-dimensional numerical simulations are discussed. Starting from earlier work by Klemp and Durran (1983) and Bougeault (1983) the radiative upper boundary condition is formally derived for a hybrid vertical coordinate. The basic assumptions include hydrostaticity, linearity, neglect of Coriolis effects and restriction to internal gravity waves. The resulting RUBC is global in space and local in time. In a second step. the RUBC is tested in a twodimensional vertical-plane version of the NWP model, in which essential properties of the full three-dimensional model have been preserved. Gravity wave experiments clearly show the superiority of the RUBC over the commonly used lid-type upper boundary condition. For the setting with an isolated bell-shaped mountain with resolution-independent steepness, the RUBC tends to work more effectively with increasing horizontal resolution. At the same time, the application of a radiative instead of a lid-type, and thus reflecting, upper boundary condition appears to become more important with decreasing mesh width. Finally, the RUBC is introduced into the full three-dimensional NWP model. This requires further approximations. In particular for a limited-area model, the geopotential field at the uppermost model level needs to be bi-periodic. Here, a linear detrending technique is applied. First results for a weather situation with strong northwesterly flow towards the Alps show that application of the RUBC drastically reduces the development of unrealistic standing, hydrostatic mountain waves, which become apprent as distinct mesoscale ridge-trough structures in the simulation with the lid-type upper boundary. Implications of the RUBC on the time-stepping procedure of the NWP model are also discussed. In the experiments whown, the additional RUBC-terms are treated explicitly.  相似文献   

辽宁盖县梁屯—矿洞沟碱性正长岩杂岩体的U—Pb和Sm—Nd年龄及其地质意义   总被引：17，自引：14，他引：17  

蔡剑辉  阎国翰  牟保磊  许保良  邵宏翔  许荣华 《岩石学报》2002,18(3):349-354

辽宁梁屯 -矿洞沟杂岩体主要由辉石正长岩、霓辉正长岩和霓辉角闪正长岩等碱性岩石组成 ,具有全岩 Rb- Sr等时线年龄 186 6± 115 Ma和 ISr=0 .70 4 9的同位素特征 ,是我国目前报道的最古老的碱性正长岩类。本文报道了该岩体的锆石U- Pb和全岩 Sm- Nd同位素测试资料 ,获得了锆石 U- Pb同位素年龄为 185 7± 2 0 Ma、Sm- Nd等时年龄为 1787± 180 Ma、εNd(t) =- 4 .8～ - 5 .0的数据。它们反映出该杂岩体形成年龄的上限为 185 7± 2 0 Ma、下限不小于 1787± 180 Ma,来源于富集地幔物质。基于这些数据并结合区域地质资料分析 ,作者提出了华北地台北缘古元古宙存在有富集地幔储库 ,以及辽河群主体形成于 190 0 Ma以前的认识  相似文献