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1.
We present a 2D numerical model for the growth of calcite from supersaturated aqueous solutions under laminar, open-channel flow conditions. The model couples solution chemistry, precipitation at solution/calcite interfaces, hydrodynamics, diffusion and degassing. The model output is compared with experimental results obtained using an oversaturated calcite solution produced by mixing CaCl2 and Na2CO3. The precipitation rate is observed to increase when the supersaturated solution flows over an obstruction, leading to a growth instability that causes the formation of terraces. At relatively high flow rates, the most important mechanism for this behaviour seems to be hydrodynamic advection of dissolved species either towards or away from the calcite surface, depending on location relative to the obstruction, which deforms the concentration gradients. At lower flow rates, steepening of diffusion gradients around protrusions becomes important. Enhanced degassing over the obstruction due to shallowing and pressure drop is not important on small scales. Diffusion controlled transport close to the calcite surface can lead to a fingering-type growth instability, which generates porous textures. Our results are consistent with existing diffusive boundary layer theory, but for flow over non-smooth surfaces, simple calcite precipitation models that include empirical correlations between fluid flow rate and calcite precipitation rate are inaccurate.  相似文献   
2.
Three outdoor plastic tanks were filled with North Sea water. The water was filtered free of algae and inoculated with the diatom Thalassiosira rotula. Under nearly natural nutrient supply an exponential plankton growth occurred with realistic cell concentrations. The flexible tanks (3–4 m3, 4–5 m deep) were exposed in the German Bight at a station in the outer harbour of Helgoland. The concentration changes of dissolved free amino acids (DFAA) were determined. The direct determination method applied permitted an analysis in picomole range without loss and with good reproducibility. The preliminary concentration of DFAA amounted to 0.2 μmol dm−3 in all three cultures, increasing during the development of T. rotula to 0.9–1.3 μmol dm−3 and decreasing in the stationary phase back again to smaller values. A high degree of temporal variation in DFAA was observed in all three cultures. In spite of these rapid changes in concentration, a good parallel development could be shown for all cultures, which extended as far as the spectra of the amino acids. Relationships between DFAA and other parameters of the culture-systems were examined.  相似文献   
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This paper "summarises some of the major changes which have occurred in international migration to, from, and within Asia in the last two decades....A number of theoretical challenges are put forward regarding the complex interrelationships between international population movements, economic development and social change. The employment of systems approaches, neoclassical economic theory, social networks and institutional approaches, and the potential role of population geography in developing a more comprehensive explanation of the changing dynamics of international migration in the region, are discussed. Also considered are the gender dimension in migration, remittance flows and their consequences, and policy issues."  相似文献   
5.
Runoff and precipitation scaling with respect to drainage area is analyzed for large river basins of the world, those with mean annual runoff in excess of 10 k3/yr. The usefulness of the specific runoff (runoff per unit drainage area, m/yr) to categorize runoff scaling laws across the complete spectrum of climatic and hydrologic conditions is evaluated. It is found that (1) runoff scales with drainage are in those river basins with specific runoff in excess of 0.15 m/yr (r2 = 0.88); (2) runoff scaling with drainage area shows remarkably high statistical correlation (r2= 0.97) in river basins with specific runoff equal to or larger than 1.0 m/yr; (3) runoff does not Inc.rease with Inc.reasing drainage area in river basins with specific runoff below 0.15 m/yr, where no discernible statistical association was found between runoff and drainage area; and (4) precipitation depth (m/yr) is inversely proportional to drainage area raised to a fractional exponent in river basins with specific runoff in excess of 0.15 m/yr.  相似文献   
6.
Water-level fluctuations may be used to promote the expansion of emergent vegetation along lakeshores. We present the case of the lake Volkerak-Zoommeer in the Netherlands, a fresh-water lake created in 1987 after the enclosure of an estuary. Using an experimental area in which the water level could be manipulated, it was shown that partial summer drawdown of the shoreline created suitable conditions for germination and growth of tall emergent species (in particular Phragmites australis). Plant survival and growth depended on subsequent water-level fluctuations and grazing by waterbirds. Based on the experiment and empirical data, a model was developed to predict the effects of the water-level regime on potential reed bed development. The model was applied for four hydrological scenarios that have been considered for the water-level management of the lake.  相似文献   
7.
Many large rivers around the world no longer flow to their deltas, due to ever greater water withdrawals and diversions for human needs. However, the importance of riparian ecosystems is drawing increasing recognition, leading to the allocation of environmental flows to restore river processes. Accurate estimates of riparian plant evapotranspiration (ET) are needed to understand how the riverine system responds to these rare events and achieve the goals of environmental flows. In 2014, historic environmental flows were released into the Lower Colorado River at Morelos Dam (Mexico); this once perennial but now dry reach is the final stretch to the mighty Colorado River Delta. One of the primary goals was to supply native vegetation restoration sites along the reach with water to help seedlings establish and boost groundwater levels to foster the planted saplings. Patterns in ET before, during, and after the flows are useful for evaluating whether this goal was met and understanding the role that ET plays in this now ephemeral river system. Here, diurnal fluctuations in groundwater levels and Moderate Resolution Imaging Spectroradiometer (MODIS) data were used to compare estimates of ET specifically at 3 native vegetation restoration sites during 2014 planned flow events, and MODIS data were used to evaluate long‐term (2002–2016) ET responses to restoration efforts at these sites. Overall, ET was generally 0–10 mm d?1 across sites, and although daily ET values from groundwater data were highly variable, weekly averaged estimates were highly correlated with MODIS‐derived estimates at most sites. The influence of the 2014 flow events was not immediately apparent in the results, although the process of clearing vegetation and planting native vegetation at the restoration sites was clearly visible in the results.  相似文献   
8.
The central and southern Perth Basin in southwestern Australia has a geological history involving multiple regional unconformity‐forming events from the Permian to Recent. This study uses sonic transit time analysis to quantify the magnitudes of net and gross exhumation for four stratigraphic periods from 43 wells. Most importantly, we quantify gross exhumation of the Permian–Triassic, Triassic–Jurassic, Valanginian break‐up and post‐Early Cretaceous events. Post‐Early Cretaceous gross exhumation averages 900‐m offshore and 600‐m onshore. Up to 200 m of this exhumation may be attributed to localized fault block rotation during extension in the Late Cretaceous and/or reverse fault re‐activation due to the compressive stresses in Australia in the last 50 Ma. The remainder is attributed to regional exhumation caused by epeirogenic processes either during the Cenozoic or at the Aptian–Albian boundary. Maximum burial depths prior to the Valanginian unconformity‐forming event were less than those reached subsequently, so that the magnitude of Valanginian break‐up exhumation cannot be accurately quantified. Gross exhumation prior to the break‐up of Gondwana was defined by large magnitude differences (up to 2500 m) between adjoining sub‐basins. At the end of Triassic, exhumation is primarily attributed to reverse re‐activation of faults that were driven by short‐wavelength inversion and exhumation at the end Permian is likely caused by uplift of rotated fault blocks during extension. The evidence from quantitative exhumation analysis indicates a switch in regime, from locally heterogeneous before break‐up to more regionally homogeneous after break‐up.  相似文献   
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Geotechnical and Geological Engineering - Dispersive soils are susceptible to phenomena of internal and external erosion when in contact with relatively pure water due to its particle’s...  相似文献   
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