A deep Chandra survey of the Groth Strip – I. The X-ray data     

K. Nandra  E. S. Laird  K. Adelberger  Jonathan P. Gardner  R. F. Mushotzky  J. Rhodes  C. C. Steidel  H. I. Teplitz  K. A. Arnaud 《Monthly notices of the Royal Astronomical Society》2005,356(2):568-586

  相似文献   

Tidal fluxes of nutrients and suspended sediments at the North Inlet–Winyah Bay National Estuarine Research Reserve     

L.R. Gardner  B. Kjerfve   《Estuarine, Coastal and Shelf Science》2006,70(4):682

Beginning June of 1993 suites of 13 water samples have been collected at Oyster Landing, North Inlet (SC), every 20 days covering two consecutive tidal cycles at 2.07 h intervals. In order to ascertain whether this large (and still growing) water chemistry data set can be used to determine tidal fluxes of nutrients and sediments, we coupled measured concentrations to estimates of instantaneous tidal discharge based on a basin water storage curve and hindcast tides. The mean advective fluxes of all constituents, including salt, showed statistically significant exports. This result, however, is largely due to an ebb bias in the sampling protocol, which resulted in 52% of the samples being collected on ebb tide versus a theoretical percentage of 48%. When this bias was corrected by reducing the mean discharge (−610 l s⁻¹) to a value (−125 l s⁻¹) that produced a balance between the mean advective and dispersive salt fluxes, the advective fluxes of the other constituents were reduced to values that are not significantly different from zero. In addition to a statistically significant dispersive influx of salt, significant dispersive exports were found for DON, NH₄, DOP, PO₄ and DOC. All particulate constituents (PN, PP, ISS and OSS) yielded dispersive fluxes that were not significantly different from zero. Annual material budgets for the Oyster Landing basin based on the dispersive fluxes of all constituents (except salt) are generally similar in magnitude and direction to those measured by [Dame, R.F., Spurrier, J.D., Williams, T.M., Kjerfve, B., Zingmark, R.G., Wolaver, T.G., Chrzanowski, T.H., McKeller, H.N., Vernberg, F.J., 1991. Annual material processing by a salt marsh-estuarine basin in South Carolina, USA. Marine Ecology Progress Series 72, 153–166.] in the nearby and ecologically similar Bly Creek basin, indicating that the dispersive fluxes determined in this study are realistic. We offer suggestions for improving the reliability and usefulness of future Oyster Landing water quality data.  相似文献   

High-resolution measurements of chromophoric dissolved organic matter in the Mississippi and Atchafalaya River plume regions   总被引：4，自引：0，他引：4  

Robert F. Chen  G. Bernard Gardner 《Marine Chemistry》2004,89(1-4):103

Chromophoric dissolved organic matter (CDOM) was measured in the spring and summer in the northern Gulf of Mexico with the ECOShuttle, a towed, instrumented, undulating vehicle. A submersible pump mounted on the vehicle supplied continuously flowing, uncontaminated seawater to online instruments in the shipboard laboratory and allowed discrete samples to be taken for further analysis. CDOM in the northern Gulf of Mexico was dominated by freshwater inputs from the Mississippi River through the Birdfoot region and to the west by discharge from the Atchafalaya River. CDOM was more extensively dispersed in the high-flow period in the spring but in both time periods was limited by stratification to the upper 12 m or so. Thin, subsurface CDOM maxima were observed below the plume during the highly stratified summer period but were absent in the spring. However, there was evidence of significant in situ biological production of CDOM in both seasons.The Mississippi River freshwater end member was similar in spring and summer, while the Atchafalaya end member was significantly higher in the spring. In both time periods, the Atchafalaya was significantly higher in CDOM and dissolved organic carbon (DOC) than the Mississippi presumably due to local production and exchange within the coastal wetlands along the lower Atchafalaya which are absent along the lower Mississippi. Nearshore waters may also have higher CDOM due to outwelling from coastal wetlands. High-resolution measurements allow the differentiation of various water masses and are indicative of rapidly varying (days to weeks) source waters. Highly dynamic but conservative mixing between various freshwater and marine end members apparently dominates CDOM distributions in the area with significant in situ biological inputs (bacterial degradation of phytoplankton detritus), evidence of flocculation, and minor photobleaching effects also observed. It is clear that high-resolution measurements and adaptive sampling strategies allow a more detailed examination of the processes that control CDOM distributions in river-dominated systems.  相似文献   

Swimming endurance of haddock (Melanogrammus aeglefinus L.) at prolonged and sustained swimming speeds, and its role in their capture by towed fishing gears     

Breen  Mike; Dyson  Jamie; O'Neill  Finbarr G.; Jones  Emma; Haigh  Michael 《ICES Journal of Marine Science》2004,61(7):1071-1079

  相似文献   

Stability and composition of terrestrially derived dissolved organic nitrogen in continental shelf surface waters     

Wayne S. Gardner  John A. Stephens 《Marine Chemistry》1978,6(4):335-342

A linear decrease in dissolved organic carbon and nitrogen with increasing salinity offshore from the Georgia coast suggests that organic nitrogen compounds contributed to coastal waters by rivers are stable during the period (2–3 months) of their transfer over the continental shelf. While the C/N ratio decreased with distance from shore, total dissolved organic nitrogen (DON), total amino nitrogen, and primary amino nitrogen showed similar relative decreases, suggesting that nitrogen is associated with refractory organic compounds. Measured amino nitrogen accounted for about 20% of the total DON, leaving about 80% of the organic nitrogen undefined.  相似文献   

Remote sensing and surface POC concentration in the South Atlantic   总被引：1，自引：0，他引：1  

Alexey V. Mishonov  Wilford D. Gardner  Mary Jo Richardson 《Deep Sea Research Part II: Topical Studies in Oceanography》2003,50(22-26):2997

Several SeaWiFS products have been compared with shipboard data to assess the possibility of using remote sensing to estimate particulate organic carbon (POC) concentration in surface waters. Transmissometer data were collected during six South Atlantic Ventilation Experiment (SAVE) hydrographic expeditions conducted between November 1987 and March 1989 from R/V Knorr, and Melville. A total of 361 beam attenuation profiles were made with a SeaTech transmissometer interfaced with a CTD/rosette. In order to calculate the POC concentration from transmissometer profiles, a regression between beam attenuation and POC for open Atlantic Ocean waters derived from our research in the North Atlantic (North Atlantic Bloom Experiment, NABE) and enhanced by data from the Bermuda Atlantic Time Series Station (BATS) was applied. The profiles were processed and examined as vertical sections of the surface 250 m. The data were collected in two successive years, during the same season, which allowed us to compile a combined data set over the austral summer for examination. Beam attenuation/POC concentrations were integrated down to one attenuation depth with the intent of making comparisons with satellite optical data. No satellite optical data were available for 1987–1989, so the only option was to compare our integrated data with SeaWiFS-derived variables from later years averaged over the same season as SAVE data. Analysis of four SeaWiFS products acquired from 1997 to 2002 demonstrated very low variations from year to year for seasonally averaged data, suggesting that making comparisons of the beam attenuation/POC fields with averaged satellite optical products from later years is a valid (though not optimal) approach for this area. The highest correlation between beam attenuation/POC concentration and remotely derived products was found with normalized water-leaving radiance at 555 nm. Other SeaWiFS-derived variables—chlorophyll concentration, diffuse attenuation coefficient at 490 nm and integral chlorophyll (integrated over one attenuation depth)—were also compared but showed a slightly less satisfactory correlation.  相似文献   

Surface water–groundwater interaction and chemistry in a mineral-armored hydrothermal outflow channel, Yellowstone National Park, USA     

M. V. Vitale  P. Gardner  N. W. Hinman 《Hydrogeology Journal》2008,16(7):1381-1393

Small quantities of groundwater interact with hydrothermal surface water to drive in-stream geochemical processes in a silica-armored hot-spring outflow channel in Yellowstone National Park, USA. The objective of this study was to characterize the hydrology and geochemistry of this unique system in order to (1) learn more about the Yellowstone Plateau’s subsurface water mixing between meteoric and hydrothermal waters and (2) learn more about the chemical and physical processes that lead to accumulation of streambed cements, i.e., streambed armor. A combination of hydrological, geochemical, mineralogical, microscopic, and petrographic techniques were used to identify groundwater and surface-water exchange. Interaction could be identified in winter because of differences in surface water and groundwater composition but interaction at other times of the year cannot be ruled out. Dissolved constituents originating from groundwater (e.g., Fe(II) and Mg) were traced downstream until oxidation and/or subsequent precipitation with silica removed them, particularly where high affinity substrates like cyanobacterial surfaces were present. Because the stream lies in a relatively flat drainage basin and is fed mainly by a seasonally relatively stable hot spring, this system allowed study of the chemical processes along a stream without the obscuring effects of sedimentation.  相似文献   

Porites corals as recorders of mining and environmental impacts: Misima Island, Papua New Guinea   总被引：1，自引：0，他引：1  

Stewart J. Fallon  Jamie C. White†Malcolm T. McCulloch 《Geochimica et cosmochimica acta》2002,66(1):45-62

In 1989 open-cut gold mining commenced on Misima Island in Papua New Guinea (PNG). Open-cut mining by its nature causes a significant increase in sedimentation via the exposure of soils to the erosive forces of rain and runoff. This increased sedimentation affected the nearby fringing coral reef to varying degrees, ranging from coral mortality (smothering) to relatively minor short-term impacts. The sediment associated with the mining operation consists of weathered quartz feldspar, greenstone, and schist. These rocks have distinct chemical characteristics (rare earth element patterns and high abundances of manganese, zinc, and lead) and are entering the near-shore environment in considerably higher than normal concentrations. Using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), we analyzed eight colonies (two from high sedimentation, two transitional, two minor, and two unaffected control sites) for Y, La, Ce, Mn, Zn, and Pb. All sites show low steady background levels prior to the commencement of mining in 1988. Subsequently, all sites apart from the control show dramatic increases of Y, La, and Ce associated with the increased sedimentation as well as rapid decreases following the cessation of mining. The elements Zn and Pb exhibit a different behavior, increasing in concentration after 1989 when ore processing began and one year after initial mining operations. Elevated levels of Zn and Pb in corals has continued well after the cessation of mining, indicating ongoing transport into the reef of these metals via sulfate-rich waters. Rare earth element (REE) abundance patterns measured in two corals show significant differences compared to Coral Sea seawater. The corals display enrichments in the light and middle REEs while the heavy REEs are depleted relative to the seawater pattern. This suggests that the nearshore seawater REE pattern is dominated by island sedimentation. Trace element abundances of Misima Island corals clearly record the dramatic changes in the environmental conditions at this site and provide a basis for identifying anthropogenic influences on corals reefs.  相似文献   

Aspects of the loss-on-ignition (LOI) technique in the context of clay-rich, glaciolacustrine sediments     

Jamie G. Smith 《Geografiska Annaler: Series A, Physical Geography》2003,85(1):91-97

The loss‐on‐ignition (LOI) technique for organic matter determination is evaluated with reference to clay‐rich, glaciolacustrine sediments. Examples of the use of LOI in glaciolacustrine literature are inconsistent in their methodology, and standardisation is called for. Problems with application of the technique to glaciolacustrine sediments stem mainly from the effects of additional weight loss due to release of structurally bound water and exposure time to ignition temperatures. Exposure time should be increased from 1 hour to 2.5 hours in the light of significant additional weight loss occurring between 2 and 2.5 hours in clay‐rich samples. The reason for this sudden increase in LOI after 2 hours (up to 86% of total LOI in some cases) appears to be the build‐up of a distinct surface crust during heating that insulates the core of the sample from ignition temperatures. Some time between 2 and 2.5 hours, the crust breaks down and exposes the sample core to ignition temperatures, increasing weight loss significantly. Overestimation of LOI due to loss of structural water is thought to be insignificant. Replicates of LOI at 550 and 1000°C in non‐calcareous, clay‐rich (>40%) sediments, show differences of <0.25%, which, for the purpose of inferring broad changes in glacier extent in lake catchments, is an acceptable error.  相似文献   

Alkylation of polycyclic aromatic hydrocarbons in carbonaceous chondrites     

Jamie E. Elsila  Peter R. Buseck 《Geochimica et cosmochimica acta》2005,69(5):1349-1357

Using microprobe laser-desorption, laser-ionization mass spectrometry (μL²MS), we measured the distributions of alkylated and unalkylated polycyclic aromatic hydrocarbons (PAHs) in the free organic material of 20 carbonaceous chondrites. These meteorites represent a variety of meteorite classes and alteration histories, including CI, CK, CM, CO, CR, CV, and Tagish Lake. This work provides information on free organic compounds that is complementary to studies of the structure and composition of meteoritic macromolecular content.For the nine CM2 meteorites analyzed, we observe that higher relative abundances of alkylated PAHs correlate with more intense aqueous activity. We attribute this correlation to the differences in solubility and volatility between unalkylated and alkylated PAHs. Naphthalene and its alkylation series are more susceptible to the effects of aqueous exposure than the less-soluble PAH phenanthrene and its alkylated derivatives. These observations are consistent with the possibility of chromatographic separations on the meteorite parent bodies. We identify six CM2 meteorites with similar PAH distributions that may represent the original, unaltered organic composition of the parent body.Increased metamorphic intensity reduces the abundance of all PAHs. The thermally metamorphosed CK chondrites had no detectable levels of typical meteoritic PAHs. This observation might be explained either by a loss of PAHs caused by volatilization or by a significantly different organic content of the CK parent body.  相似文献