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ABSTRACT

The October 2011 sinking of the container ship MV Rena on Astrolabe Reef, New Zealand, provided a rare opportunity to examine the fate of shipwreck-derived contaminants on an offshore rocky reef and food chain. Analyses of trace metals, polycyclic aromatic hydrocarbons (PAHs) and organotins indicated significant but localised contamination of Astrolabe Reef but not of nearby Mōtītī Island. Three years after the grounding, PAH concentrations were greater in sediments at Astrolabe (up to 131?mg kg?1) than at control locations, while organotins from the ship's antifouling hull paint were found exclusively in Astrolabe Reef sediments and biota. Over 80% of Astrolabe sediment samples contained tributyltin at concentrations above guideline sediment levels (>0.07?mg kg?1). Tributyltin and its decomposition products were also recorded in sea urchins, gastropods, lobster and fishes at concentrations up to 0.2?mg kg?1. Wreck and cargo-derived metals, particularly copper, tin and zinc, were present in some Astrolabe sediment samples above Australia and New Zealand Environment and Conservation Council guideline concentrations. However, there appeared to be only limited transmission of metals through the food chain. Copper, tin and zinc were recorded at greater concentrations in Astrolabe sea urchins and gastropods compared to control specimens, while metal concentrations in other biota were comparable across impact and control sites. Despite over 3 years having passed since the Rena grounding, the data series does not show any upward or downward trends in contaminant concentrations on Astrolabe Reef. Consequently, there is uncertainty about the long-term implications of the Rena grounding for the ecology of Astrolabe Reef.  相似文献   
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ABSTRACT

To investigate the uptake and depuration of polycyclic aromatic hydrocarbons associated with the Rena oil spill we sampled the surf clam Paphies subtriangulata at two open coast locations (6?km apart) just prior to oil coming ashore (7 October 2011), then at 1–3 week intervals for the next 4 months. Total polycyclic aromatic hydrocarbons (tPAH) increased at both sites from 1 to 96–124?µg?kg?1 (wet weight) by 18 October before declining to low levels (<4?µg?kg?1) by February 2012. Ongoing sampling throughout 2012–2014 included three additional sites to the north east (up to 30?km away) and a site 5?km to the south east revealing tPAH levels generally <10?µg?kg?1 except in October 2013 where levels ranged between 39–45?µg?kg?1 at all sites. A comparison of PAH component profiles with oil-contaminated beach sediment indicated that the high levels observed in surf clams between October–December 2011 were clearly associated with the Rena spill. However, the October 2013 peak had a PAH profile inconsistent with weathered Rena oil, suggesting an alternative source of contamination. Our results highlight the potential for P. subtriangulata as a PAH monitoring tool but recognise more study is needed to better quantify baseline levels and uptake and depuration dynamics.  相似文献   
4.
Abstract

It is suggested that reverse currents seen in recent numerical reconnection experiments (Biskamp, 1986; Forbes and Priest, 1983) are caused by the choice of outflow boundary conditions. The specification of the normal velocity at the outflow boundary may result in a mismatch in velocity at the diffusion region which is manifested as a spike of reverse current.  相似文献   
5.
Monitoring Networks in Fractured Rocks: A Decision Analysis Approach   总被引:1,自引:0,他引:1  
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Understanding the interactions of climate, physical erosion, chemical weathering and pedogenic processes is essential when considering the evolution of critical zone systems. Interactions among these components are particularly important to predicting how semiarid landscapes will respond to forecasted changes in precipitation and temperature under future climate change. The primary goal of this study was to understand how climate and landscape structure interact to control chemical denudation and mineral transformation across a range of semiarid ecosystems in southern Arizona. The research was conducted along the steep environmental gradient encompassed by the Santa Catalina Mountains Critical Zone Observatory (SCM-CZO). The gradient is dominated by granitic parent materials and spans significant range in both mean annual temperature (>10 °C) and precipitation (>50 cm a?1), with concomitant shift in vegetation communities from desert scrub to mixed conifer forest. Regolith profiles were sampled from divergent and convergent landscape positions in five different ecosystems to quantify how climate-landscape position interactions control regolith development. Regolith development was quantified as depth to paralithic contact and degree of chemical weathering and mineral transformation using a combination of quantitative and semi-quantitative X-ray diffraction (XRD) analyses of bulk soils and specific particle size classes. Depth to paralithic contact was found to increase systematically with elevation for divergent positions at approximately 28 cm per 1000 m elevation, but varied inconsistently for convergent positions. The relative differences in depth between convergent and divergent landscape positions was greatest at the low and high elevation sites and is hypothesized to be a product of changes in physical erosion rates across the gradient. Quartz/Plagioclase (Q/P) ratios were used as a general proxy for bulk regolith chemical denudation. Q/P was generally higher in divergent landscape positions compared to the adjacent convergent hollows. Convergent landscape positions appear to be collecting solute-rich soil–waters from divergent positions thereby inhibiting chemical denudation. Clay mineral assemblage of the low elevation sites was dominated by smectite and partially dehydrated halloysite whereas vermiculite and kaolinite were predominant in the high elevation sites. The increased depth to paralithic contact, chemical denudation and mineral transformation are likely functions of greater water availability and increased primary productivity. Landscape position within a given ecosystem exerts strong control on chemical denudation as a result of the redistribution of water and solutes across the landscape surface. The combined data from this research demonstrates a strong interactive control of climate, landscape position and erosion on the development of soil and regolith.  相似文献   
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Sediments left by coastal flooding have been observed worldwide and have been variously ascribed to the action of storm surges and tsunami waves. To date, no study has attempted to unequivocally establish on stratigraphical, sedimentological, and palaeoecological grounds the means by which these two different processes might be distinguished in coastal sedimentary sequences. This paper examines the evidence for historical storm surges and tsunamis and shows that both high magnitude events have been documented over the past 250 years in southwest England. Sand layers of varying thickness are present within Holocene lagoonal and peat sequences of several shallow lakes of the Scilly Isles. Detailed analysis of Big Pool, St Agnes, indicates that the basal peats date from around 1000 BP. Within the basal peats are numerous thin sand layers. Above the basal peat is an extensive sand layer 15 to 40 cm thick. The base of this latter layer probably dates from the early to mid 18th century. Particle size, grain surface morphology, diatom, and mineral magnetic studies are used to try and determine the most likely mode of deposition. The results of all analyses are inconclusive, but the weight of evidence suggests that the increasing frequency of thin sand layers in the upper part of the basal peat may be related to the increasing frequency and intensity of Atlantic storms during the Little Ice Age superimposed upon a rising sea level. The thick sand layer may have been deposited by the tsunami wave generated by the Lisbon earthquake of November 1,1755. Due to the difficulties in distinguishing depositional processes in coastal environments known to have been affected by storm surges and tsunami waves, it is suggested that generally accepted sedimentological techniques are inadequate for discriminating depositional processes in coastal environments.  相似文献   
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We have produced brightness and magnetic field maps of the surfaces of CV Cha and CR Cha: two actively accreting G- and K-type T Tauri stars in the Chamaeleon I star-forming cloud with ages of 3–5 Myr. Our magnetic field maps show evidence for strong, complex multipolar fields similar to those obtained for young rapidly rotating main-sequence stars. Brightness maps indicate the presence of dark polar caps and low-latitude spots – these brightness maps are very similar to those obtained for other pre-main-sequence and rapidly rotating main-sequence stars.
Only two other classical T Tauri stars have been studied using similar techniques so far: V2129 Oph and BP Tau. CV Cha and CR Cha show magnetic field patterns that are significantly more complex than those recovered for BP Tau, a fully convective T Tauri star.
We discuss possible reasons for this difference and suggest that the complexity of the stellar magnetic field is related to the convection zone; with more complex fields being found in T Tauri stars with radiative cores (V2129 Oph, CV Cha and CR Cha). However, it is clearly necessary to conduct magnetic field studies of T Tauri star systems, exploring a wide range of stellar parameters in order to establish how they affect magnetic field generation, and thus how these magnetic fields are likely to affect the evolution of T Tauri star systems as they approach the main sequence.  相似文献   
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