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1.
This paper is a continuation of previous research, which obtained a convenient solution for arbitrary surface fluxes before ponding. By means of Fourier Transformation this has been extended to derive analytical solutions of a linearized Richards' equation for arbitrary input fluxes after surface saturation. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
2.
Three coins of the Khotan horse, or Sino‐Kharosthi, style from Xinjiang province of China were recently obtained from a coin dealer. Because the archaeological context of these coins remains unknown, we conducted chemical and stylistic analyses to help determine their authenticity. Energy dispersive X‐ray (EDX) and wavelength dispersive X‐ray (WDX or microprobe) measurements indicate that they are red (pure) copper and bronze coins, with one coin containing 4.2% Ag. Metal content and the presence of secondary minerals formed through weathering indicate that these are authentic ancient coins that were buried in a dry environment. All three coins bear Chinese characters; one shows Kharosthi, and two display Brahmi, a popular language in Khotan from A.D. 260 to 282. This indicates that the Sino‐Brahmi coins were made slightly later than the Sino‐Kharosthi coins, which were made before A.D. 260. These specimens represent the first Sino‐Brahmi coin and 20‐zhu coin ever reported in the literature. © 2011 Wiley Periodicals, Inc.  相似文献   
3.
Vertical profiles of dissolved and particulate Mn, Fe, Ni, Cu, Zn, Cd, Pb, and (234)Th were determined in the Hung-Tsai Trough off southwestern Taiwan during 19-23 November, 2004. Except in the case of Cd, the distribution coefficient (K(d)) of the trace elements showed a negative correlation with the suspended particle concentration. Based on the average K(d) values, the general sequence of particle affinities for the eight trace elements is, from highest to lowest, Fe>Mn≈Pb>Zn≈Th>Cd≈Cu≈Ni. The trace metal data was coupled with the particle removal flux estimated from (234)Th/(238)U disequilibrium to investigate metal removal by particle sinking from the euphotic layer. The residence time of trace elements with respect to particle removal from the euphotic layer was estimated. A negative correlation between the residence time and the distribution coefficient for the trace metals was found.  相似文献   
4.
It is generally assumed that estuarine mixing is continuous for metals from terrestrial sources, gradually decreasing towards the open ocean endmember. Here we show that, chemical reactivity, determined by ion exchange method, and molecular weight distributions, obtained using cross-flow ultrafiltration, of dissolved Cd, Cu, and Ni in the surface waters of the Gulf of Mexico varied systematically across the estuarine mixing zone of the Mississippi River. Most size or chemical affinity fractions of dissolved metals (<0.4 μm) were linearly related to salinity (10.8–36.6), suggesting that the distribution of these elements was mainly controlled by continuous mixing processes. Dissolved concentrations across the salinity gradient ranged for Cd: 87–187 pM; Cu: 1.4–18.3 nM; and Ni: 2.6–18.8 nM, with highest values near the Mississippi river mouth, and lowest concentrations in a warm core ring in the Gulf of Mexico. Dissolved Cd was mostly present as a truly dissolved (<10 kDa, 97 ± 1%) and cationic fraction (Chelex-100 extractable, 94 ± 4%). A novel observation across the estuarine mixing zone was that colloidal metal concentrations were identical to either inert (for Cu, Ni) or AMPG-labile anionic (Cu, Cd) fractions. The difference in behavior between Cu and the other two metals might indicate differences in the biopolymeric nature of the metal–organic chelates. In particular, the anionic-organic Cd fractions accounted for just 3 ± 1%, on average. However, for Cu, it was 24 ± 4%, and for Ni, it was 9 ± 6%. The fractions of the total dissolved metal fractions that were “inert” averaged 31 ± 10% for Cu and 29 ± 12% for Ni. Small but noticeable amounts (6 ± 3%) of dissolved inert Cd fractions were also present. Apparent non-local transport processes, likely associated with cross-shelf sediment resuspension processes, could have been responsible for the relatively high concentrations of ‘inert’ and ‘anionic’ metal fractions in high salinity coastal waters, and accounting for the persistence of metals bound to humic substances in the Gulf of Mexico.  相似文献   
5.
Jiann‐Mou Chen 《水文研究》2008,22(26):5037-5047
Most methods developed to represent water flow phenomena in an unconfined aquifer with a fully penetrated pumping well are either numerical, such as the well‐known FEMWTER model, or experimental; analytical models of a partially penetrated pumping well are rare. This study employs the linearized Richards equation as the governing equation, with the aid of Fourier Integral Transformation, to obtain an analytical solution of the water content distribution in an unconfined aquifer with a partially penetrated pumping well. The results from this study could serve to substantiate in some sense results from numerical models. In addition, the theory developed herein can be modified to simulate a vacuum‐pressured pumping well since it is derived by considering, among others, the location and length of a well screen with fluxes. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
6.
湖北铜绿山矿床石英闪长岩的矿物学及Sr-Nd-Pb同位素特征   总被引:11,自引:8,他引:3  
铜绿山是长江中下游鄂东南矿集区最重要的、大型夕卡岩型Cu-Fe(Au)矿床。本文对该矿区中与成矿密切的石英闪长岩进行了详细的矿物成分、地球化学及Sr-Nd-Pb同位素研究。结果表明:岩石中斜长石主要为更长石(An=21~31);角闪石贫Ti(0.2),高Mg/(Mg+Fe)(0.5),属于富镁角闪石;而黑云母为镁质黑云母。岩石的地球化学具有高硅(58.86%~67.71%),富碱(Na2O+K2O=5.67%~9.63%),富集轻稀土元素(LREE)和大离子亲石元素(LILE),并强亏损元素Nb、Ta、Ti等特征。岩石的(87Sr/86Sr)i为0.7055~0.7069,εNd(t)为-7.65~-3.44;(206Pb/204Pb)i=17.66~18.00,(207Pb/204Pb)i=15.49~15.56,(208Pb/204Pb)i=37.73~38.19。矿物成分、地球化学和同位素特征说明,铜绿山岩体与阳新岩体为同源岩浆的产物,源区为深度大于40km的富集地幔,经下地壳的混染及分离结晶作用形成。岩浆熔体形成的温度应大于889℃。角闪石和黑云母的温度计估算岩浆结晶温度分别为650~800℃和500~630℃,黑云母开始结晶温度略低于角闪石结晶结束温度,压力为1.49kbar,对应侵位深度约4.9km。岩浆具有利于Cu、Fe、Au等成矿元素进入熔体的条件,可能与板块俯冲作用相关。  相似文献   
7.
Dissolved and particulate Mn and Fe in the nearshore waters were determined at 27 stations along the west coast of Taiwan during 19-23 November 2004. The latitudinal distributions of Mn and Fe were very similar; however, the concentration in the dissolved phase was lower, whereas that in the particulate phase was higher in the northern regime. The higher percentage of Fe than Mn that was associated with particles resulted in a two-order of magnitude higher particle-water partition coefficient for Fe, Kd(Fe), than that for Mn, Kd(Mn). The removal fluxes of Mn and Fe could be estimated by multiplying the particulate 234Th removal flux with the Mn/234Th and Fe/234Th ratios in suspended particles, which ranged from 0.1 to 3.8 mmol m−2 d−1 for Mn, and from 3.4 to 194.5 mmol m−2 d−1 for Fe. Residence times ranged from 1 to 20 days for Mn and Fe were estimated in the nearshore.  相似文献   
8.
This paper reports the results of cyclic loading tests performed on four specimens consisting of reinforced concrete frames with brick infill walls. The brick infill is pre‐laid, followed by the cast in‐place RC columns and beams. Test parameters include the height‐to‐length ratio of the brick infill wall and the mortar compressive strength. Test results reveal that the in‐plane lateral strength of brick infill wall is related to the fracture path. The fracture path for brick infill walls with large height‐to‐length ratios includes bed joints, cross joints, and vertical splitting of bricks. As a result, the lateral strength of this type of brick infill wall is larger. In comparison, the fracture path for brick infill walls with small height‐to‐length ratios only passes through joints, which is the reason why they have lower lateral strength. Mortar with higher strength improves the lateral strength of brick infill wall. In addition to presenting experimental observations in detail, this paper compares the test results with those obtained from existing methods for assessment of seismic resistance. Comments and recommendations are offered with respect to the capabilities of the assessment methods in predicting stiffness, strength, and ultimate deformation capacity of brick infill walls. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
9.
Reconstruction of modern climate and environmental changes in east Asia using inland natural climate archives can provide valuable insights on decadal–multidecadal climate and environmental patterns that are probably related to both natural and anthropogenic forcing. Here we investigated an 89‐cm‐long sediment core (TH1) from Tian Lake, southeastern China, for sedimentological, physical and geochemical parameters in order to understand climate and environmental changes for the latest two centuries. 137Cs‐ and 210Pb‐based age models show that the fine sand–coarse silt‐dominated core contains ~170 years (c. AD 1842–2011) of continuous sedimentation. Sediments with fine sands, low MS values, high water content, high TOC content and a high C:N ratio from c. AD 1842 to 1897 suggest intense hydrological conditions and strong runoff in the catchment, probably because of a humid climate. From AD 1897 to 1990, sediments with very fine sand and coarse silt, high MS values, low water content and unchanged TOC and C:N ratios indicate normal hydrological conditions and in‐lake algae‐derived organic matter. During this interval, the chemical weathering indicators show stronger weathering conditions compared with sediments deposited during AD 1842–1897, supporting the dominance of weathered surface soil input in the earlier interval and physical erosion dominance in the later period, respectively. Since AD 1990, the continuous decrease of geochemical proxies suggests human‐interacted Earth surface processes in the catchment of Tian Lake. A PCA revealed four dominant geochemical controlling factors – detrital input, trophic status, grain size and early diagenesis –, accounting for 26, 20, 18 and 16% of total variance, respectively. This study for the first time provides lacustrine geochemical evidence for the most recent two centuries of climate and environmental changes in coastal southeastern China, a region that is currently undergoing an inversion of critical zone, i.e. an overturning of its soil profile, owing to swift modernization.  相似文献   
10.
The analysis of infiltration of 2D trickle irrigation under multiple‐line sources, governed by the celebrated Richards equation, is performed, aiming at determining the efficiency of trickle irrigation so as to reduce the water demand. A closed‐form solution is explicitly obtained by utilizing the Fourier integral transformation, and this serves as a means to compute the distribution of volumetric water content during trickle irrigation. Results for the infiltration of 2D trickle irrigation under single line and multiple‐line sources are presented, which illustrate the distribution of infiltration water that diffuses into the soil, and make it possible to calculate the period of time required for trickle irrigation for different plants. The results can be applied to verify complicated solutions from other numerical models. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
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