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1.
Tellurium,selenium and cobalt enrichment in Neoproterozoic black shales,Gwna Group,UK: Deep marine trace element enrichment during the Second Great Oxygenation Event 
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下载免费PDF全文 Joseph G. T. Armstrong John Parnell Liam A. Bullock Magali Perez Adrian J. Boyce Jorg Feldmann 《地学学报》2018,30(3):244-253
Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O2 concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period. 相似文献
2.
Vertical eddy diffusivity estimations in Swan river estuary 总被引：1，自引：0，他引：1
A field experiment is described in which diapycnal diffusivity is estimated by direct and indirect methods in Swan river estuary, Perth, Western Australia. The microstructure profiles were collected in a narrow and straight part of this estuary using a portable flux profiler (PFP). The profiles were segmented into stationary parts and the rate of vertical eddy diffusivity was estimated for the segments within the pycnocline. The direct measurement showed that instantaneous flux could be positive or negative with a low net rate of vertical eddy diffusivity for mass of about 6.5 × 10−8 m2 s−1. All the indirect methods overestimated this rate. However, within the indirect methods, the method of Osborn yielded the poorest estimate while the method of Osborn and Cox gave the closest estimate. 相似文献
3.
I report on a group of orca (Orcinus orca (Linnaeus, 1758)) near the Bay of Islands, New Zealand, which were a lighter coloration than orca usually seen in these waters. Differences in pigmentation included a light grey caudal peduncle area and a dorsal cape, which has previously only been described for Antarctic orca. The size and shape of the eye patches were not consistent with orca photo‐identified in New Zealand. I suggest that this group of orca, although observed in New Zealand waters, were of Antarctic origin. 相似文献
4.
This investigation had the purpose of evaluating the reliability of a sequential extraction procedure according to Zeien and Brümmer (1989) which is performed routinely to analyse the distribution of heavy metals to different soil phases. Reliability was tested by two hypotheses. According to the first hypothesis an error propagation increased during a morefold extraction of heavy metals from a single soil sample to such an extend that it does not allow a statistical comparison of different analyses. This assumption was confirmed in an interlaboratory study of five participants applying the sequential extraction scheme on two different soils. The heavy metal amounts extracted by the different partners were of the same magnitude, but from the results no statistical correspondence at the 95% confidence level could be observed. The second hypothesis stated that also weak extraction agents were able to release metals from the more immobile soil fractions, especially if the amount of easily soluble metals was comparatively small. To answer this question the sequential extraction was modified by carrying out selected weak extraction steps several times. As expected the intensified extraction conditions caused a decrease of the element content within the more resistant phases. However, the additional release in the first four extraction steps of Pb, Mn, Fe, and Zn was only in the range of 5 to 10%. Furthermore, it was observed that a single EDTA extraction (step four within the sequential extraction scheme) was capable to extract the same amount of metals as the first four extraction steps of the original scheme at a variation of about 15%. From these results it was concluded that the EDTA step alone already represents a reliable pool of mobilisable metals. Thus it can be maintained that such a simple single EDTA extraction can be used to assess the environmental risk from heavy metal contaminated soils or to predict the potential heavy metal release of soil remediation processes. 相似文献
5.
G.W. Wake G.N. Ivey J. Imberger N.R. McDonald 《Dynamics of Atmospheres and Oceans》2005,39(3-4):189-210
A laboratory study in a rotating stratified basin examines the instability and long time evolution of the geostrophic double gyre introduced by the baroclinic adjustment to an initial basin-scale step height discontinuity in the density interface of a two-layer fluid. The dimensionless parameters that are important in determining the observed response are the Burger number S=R/R0 (where R is the baroclinic Rossby radius of deformation and R0 is the basin radius) and the initial forcing amplitude (H1 is the upper layer depth). Experimental observations and a numerical approach, using contour dynamics, are used to identify the mechanisms that result in the dominance of nonlinear behaviour in the long time evolution, τ>2−1 (where τ is time scaled by the inertial period TI=2π/f). When the influence of rotation is moderate (0.25≤S≤1), the instability mechanism is associated with the finite amplitude potential vorticity (PV) perturbation introduced when the double gyre is established. On the other hand, when the influence of rotation is strong (S≤0.1), baroclinic instability contributes to the nonlinear behaviour. Regardless of the mechanism, nonlinearity acts to transfer energy from the geostrophic double gyre to smaller scales associated with an eddy field. In the lower layer, Ekman damping is pronounced, resulting in the dissipation of the eddy field after only 40TI. In the upper layer, where dissipative effects are weak, the eddy field evolves until it reaches a symmetric distribution of potential vorticity within the domain consisting of cyclonic and anticyclonic eddy pairs, after approximately 100TI. The functional dependence of the characteristic eddy lengthscale LE on S is consistent with previous laboratory studies on continuously forced geostrophic turbulence. The cyclonic and anticyclonic eddy pairs are maintained until viscous effects eventually dissipate all motion in the upper layer after approximately 800TI. The outcomes of this study are considered in terms of their contribution to the understanding of the energy pathways and transport processes associated with basin-scale motions in large stratified lakes. 相似文献
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对全球寒武系与奥陶系界线层型剖面和点位(GSSP)——西纽芬兰绿岬(Green Point)剖面和我国吉林白山(原浑江)大阳岔小洋桥原全球寒武系与奥陶系界线候选剖面的对比研究表明,绿岬"金钉子"剖面所指定的界线生物标志——波动古大西洋牙形石(Iapetognathus fluctivagus)并不存在于所指定的界线生物层和点位上,而且在分布和分类上是均存在争议的物种,更遗憾的是,所展示的大部分牙形石和笔石标本图片以及碳氧同位素异常数据也并非来自该"金钉子"剖面,因而完全违背了选择金钉子剖面的原则和要求,有必要进行重新的评估。小洋桥寒武系与奥陶系界线剖面交通方便、环境优美,寒武系与奥陶系界线地层系由一套深水且未变质的黑色、黄绿色页岩与灰色薄层瘤状灰岩所构成的韵律沉积组成,并保存了完整的具有广泛代表性牙形石和笔石序列,在详细研究的34 m界线间隔中,自下而上保存了完整的Cambrostodus、Codylodus proavus、C.intermedius、C.lindstromi和C.angulatus等5牙形石生物带,在C.intermedius带上部至C.angulatus带之间,还依次出现3层笔石,归属于重新厘定的Rhabdinopora parabola和Anisograptus matanensis等2个笔石带,此外还有大量三叶虫和介形类化石共生,结合高精度同位素地球化学的研究,笔者等建议,以全球广泛分布的牙形石C.intermedius的首现,取代Iapetognathus fluctivagus,作为寒武系与奥陶系界线划分对比的标志,其层位与原来所指定的界线层几乎一致或接近,界线之上所记录的最大碳同位素异常和首次出现的最早的浮游正笔石——R.parabola(含R.praeparabola),可作为该界线划分的辅助标志。 相似文献
7.
Barbamarco Lagoon (area = 7 km2) is in the Po River Delta, adjoining the Northern Adriatic Sea, and supports a commercially valuable clam (Tapes philippinarum) fishery. This study investigated interactions of the lagoon with adjacent coastal waters and inland riverine inputs by modelling both the lagoon and the Northern Adriatic Sea, using a coupled three-dimensional (3D) hydrodynamic-ecological model (ELCOM-CAEDYM) adapted to include the clam population. The clam model accounted for carbon (C), nitrogen (N) and phosphorus (P) biomass in the benthos through parameterisations for filtration, excretion, egestion, respiration, mortality, and harvesting. Multiple clam size classes were included in a new population dynamics sub-model. Output from the coupled model was validated against hydrodynamic and water quality data from intensive field sampling and routine monitoring. Time scales of tidal flushing, primary production and clam grazing were investigated with the model to demonstrate that food supply to clam populations is dominated by phytoplankton inputs from the Northern Adriatic Sea. Effects of clam cultivation on nutrient concentrations and phytoplankton biomass in Barbamarco Lagoon were primarily localised, with strong tidal flushing minimising impacts of clam filtration on lagoon-wide nutrient concentrations at current clam stocking levels. Clam populations were found to alter the cycling of nutrients in the system, causing the lagoon to become a net sink for particulate organic matter and to export dissolved organic matter to the adjacent sea via tidal flushing. Ecosystem health and sensitivity of nutrient cycles to clam cultivation are important considerations for the long term sustainable management and potential expansion of the fishery. 相似文献
8.
Active turbulence in lakes is confined to the surface mixed layer, to boundary layers on the lake sides and bottom, and to turbulent patches in the interior. The density stratification present in most lakes fundamentally alters the pathways connecting external mechanical energy inputs, for example by wind, with its ultimate fate as dissipation to heat; the density stratification supports internal waves and intrusions that distribute the input energy throughout the lake. Intrusions may be viewed as internal waves with zero horizontal wavenumber and are formed each time localised mixing occurs in a stratified fluid. Intrusions are also formed in the epilimnion by differential heating or cooling and by differential deepening. The fraction of lake volume below the diurnal mixed layer that is subject to active turbulence is very small, probably of the order of 1% or less in small to medium‐sized lakes. By contrast, in the surface mixed layer, turbulence is less intermittent and maintains phytoplankton in suspension and controls their exposure to the underwater solar flux. Nutrient transport to individual cells depends not only on the cell Reynolds number but also on the Peclet number, which, if large, implies enhanced mass transfer above purely diffusive values. 相似文献
9.
Spatial patterns are generated as a result of the coupling between biogeochemical and physical processes and the ability to capture and reproduce patchiness is crucial for the better comprehension of an ecosystem and its response to external perturbations. A 1D reaction–diffusion–advection equation is used to investigate the formation of patterns and relevant time and spatial scales and thus define an approach for the determination of a critical domain size that allows differentiation of the role of local and internal cycling from advective fluxes across the open boundaries in a shallow coastal ecosystem. By using a 3D numerical model, in conjunction with an extensive field data set, it is shown that domain sizes must be larger than this critical value in order to capture the patterns generated within the system. For smaller domains, the evolution of the system is controlled by transport processes across the boundaries misleading the interpretation of the internal ecological dynamics. The study of the influence of boundary fluxes on ecological patchiness was motivated by the need to define the size of the domain necessary for the assessment of the impact of a sewage outflow on a coastal regime. 相似文献
10.
The presence and extent of small scale vertical structure in dissolved oxygen were investigated in a tropical Australian lake. At a 9 m deep site an extremely high oxygen patch appeared near the bottom boundary. Light levels reaching the bottom boundary during the life of the patch exceeded 10 µEinst m–2 s–1. The patch remained for 1.5 h before gradually reaching ambient oxygen levels. The patch's disappearance coincided with decreasing light levels during the late afternoon. Differences in the extent of oxygen vertical patchiness between deep (16 m) and shallow (9 m) sites were also observed. At the deep site, the distribution of oxygen steps over the water column coincided largely with the distribution of temperature steps. This indicates the dominance of physical processes at that site. At the shallow site, marked vertical patchiness in oxygen was observed with no similar patchiness in temperature. This indicates the prevalence of biological and chemical processes. 相似文献