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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff 
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下载免费PDF全文 We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
利用不同形状冰晶的散射特性,获得了非球形冰晶云的94/220 GHz测云雷达双波长比,探讨了非球形冰晶云的双波长比与云内微物理参数的关系,分析了衰减前后的星载雷达反射率因子及双波长比的垂直廓线。结果表明:（1）双波长比可以反映小到0.1 mm中值尺度的冰粒子,对粒子总数、谱的形状参数不敏感,对粒子大小、形状、云衰减较敏感。（2）雷达灵敏度一定时,星载雷达可测云厚与雷达波长、冰含水量（IWC）的垂直分布、云厚及衰减有关;没有进行衰减订正时,双波长比和衰减有关,冰含水量越大,波长越短,衰减越大,双波长比最大值与可探测云厚有关。两部雷达可探测冰含水量为0.001—0.1 g/m3、厚2 km的冰云;当云厚5 km、冰含水量垂直分布在0.001—0.2 g/m3时,云厚的94%基本可以被220 GHz云雷达探测到。（3）如果两部雷达气象方程中用水的介电因子,测量回波强度应进行介电因子的订正后再计算双波长比。 相似文献
3.
Belowground carbon balance and carbon accumulation rate in the successional series of monsoon evergreen broad-leaved forest 总被引：4，自引：0，他引：4
ZHOU Guoyi ZHOU Cunyu LIU Shuguang TANG Xuli OUYANG Xuejun ZHANG Deqiang LIU Shizhong LIU Juxiu YAN Junhua ZHOU Chuanyan LUO Yan GUAN Lili LIU Yan 《中国科学D辑(英文版)》2006,49(3):311-321
The belowground part of terrestrial ecosystem is a huge carbon pool. It is believed that of the total 2500Gt carbon stored in global terrestrial ecosystem, soil carbon storage within the 1 m surface layer ac- counts for 2000Gt, which is 4-fold of vegetation car- bon storage[1,2]. Compared with the carbon in the vegetation, carbon in the deep soil layers is much more stable, and it will stay in soil profile permanentlyunless geological vicissitude occurs. Essentially, forest restoration is the… 相似文献
4.
利用毫米波测云雷达反演层状云中过冷水 总被引：1，自引：0，他引：1
毫米波测云雷达已成为研究云内微物理参数的有效工具,利用其从混合相云中识别出过冷水,对人工影响天气及预防飞机积冰具有重要意义,对我国毫米波雷达的数据处理也具有借鉴作用。本文利用英国的35 GHz、94 GHz测云雷达,结合激光雷达和探空资料,采用阈值法,反演分析了层状云中的过冷水。结果表明:(1)毫米波雷达联合激光雷达可以识别层状云中的过冷水,其结果与微波辐射计测量的液态水路径或毫米波雷达的双峰谱相符合;(2)利用多普勒速度的双峰谱可以反演混合相云中的过冷水含量、冰晶含水量。混合相云的雷达反射率因子主要取决于冰晶,根据雷达反射率因子反演会低估云内液态水含量;(3)本次层状云降水的亮带以上含有较多过冷水,此处35 GHz的雷达回波强度随冰晶的增大而减弱,且冰晶的含水量主导了总液态水含量。 相似文献
5.
Chaoqun Tan Juxiu Tong Yang Liu Bill X. Hu Jinzhong Yang Hong Zhou 《Stochastic Environmental Research and Risk Assessment (SERRA)》2016,30(5):1347-1361
With the development of modern agriculture, large amount of fertilizer and pesticide outflow from farming land causes great waste and serious pollution to surface water and groundwater, and threatens ecological environment and even human life. In this paper, laboratory experiments are conducted to simulate adsorbed Cr(VI) transfer from soil into runoff. A two-layer in-mixing analytical model is applied to analyze laboratory experimental results. A data assimilation (DA) method via the ensemble Kalman filter (EnKF) is used to update parameters and improve modeling results. In comparison with the experimental data, DA updated modeling results are much better than those without the updating. To make predictions better, the inflation method with a constant inflation factor via DA method was used to compensate the fast decrease of ensemble spread partially related to filter inbreeding. Based on the used rainfall and relevant physical principles, the updated value of the incomplete mixing coefficient γ is about 14.0 times of the value of the incomplete mixing coefficient α in experiment 1 and about 7.4 times in experiment 2, while the difference between the flow rate of runoff and infiltration is not so large even after reaching stable infiltration condition. The results indicate the loss of Cr(VI) in soil solute is mainly due to infiltration, rather than surface runoff. With the increase of mixing layer depth, soil adsorption capacity will increase and the loss of soil solute will decrease. The study results provide information for reducing and even preventing the agricultural nonpoint source pollution. 相似文献
6.
利用我国自己研制的W波段云雷达地基探测资料,分析了合肥一次小雨云系的微物理过程,然后利用两个不同地区的地基及机载探测资料,初步反演了水云及卷云的微物理参数。结果表明:(1)回波强度增大,多普勒速度、线性退极化比(LDR)、谱宽激增的地方为融化层顶,根据LDR亮带可初步判定融化层的厚度;(2)利用经验关系法,对卷云冰水含量和水云的液态水含量进行了反演,利用推导的公式反演得到冰晶云云粒子的有效半径;(3)利用逐库订正法对水云的回波强度进行订正,得到了衰减订正后的液态水含量,减小了反演误差。 相似文献
7.
An ensemble Kalman filter (EnKF) is developed to identify a hydraulic conductivity distribution in a heterogeneous medium by assimilating solute concentration measurements of solute transport in the field with a steady‐state flow. A synthetic case with the mixed Neumann/Dirichlet boundary conditions is designed to investigate the capacity of the data assimilation methods to identify a conductivity distribution. The developed method is demonstrated in 2‐D transient solute transport with two different initial instant solute injection areas. The influences of the observation error and model error on the updated results are considered in this study. The study results indicate that the EnKF method will significantly improve the estimation of the hydraulic conductivity field by assimilating solute concentration measurements. The larger area of the initial distribution and the more observed data obtained, the better the calculation results. When the standard deviation of the observation error varies from 1% to 30% of the solute concentration measurements, the simulated results by the data assimilation method do not change much, which indicates that assimilation results are not very sensitive to the standard deviation of the observation error in this study. When the inflation factor is more than 1.0 to enlarge the model error by increasing the forecast error covariance matrix, the updated results of the hydraulic conductivity by the data assimilation method are not good at all. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
8.
Assimilating transient groundwater flow data via a localized ensemble Kalman filter to calibrate a heterogeneous conductivity field 总被引：2，自引：2，他引：0
Juxiu Tong Bill X. Hu Jinzhong Yang 《Stochastic Environmental Research and Risk Assessment (SERRA)》2012,26(3):467-478
A localized ensemble Kalman filter (EnKF) method is developed to assimilate transient flow data to calibrate a heterogeneous
conductivity field. To update conductivity value at a point in a study domain, instead of assimilating all the measurements
in the study domain, only limited measurement data in an area around the point are used for the conductivity updating in the
localized EnKF method. The localized EnKF is proposed to solve the problems of the filter divergence usually existing in a
data assimilation method without localization. The developed method is applied, in a synthetical two dimensional case, to
calibrate a heterogeneous conductivity field by assimilating transient hydraulic head data. The simulations by the data assimilation
with and without localized EnKF are compared. The study results indicate that the hydraulic conductivity field can be updated
efficiently by the localized EnKF, while it cannot be by the EnKF. The covariance inflation and localization are found to
solve the problem of the filter divergence efficiently. In comparison with the EnKF method without localization, the localized
EnKF method needs smaller ensemble size to achieve stabilized results. The simulation results by the localized EnKF method
are much more sensitive to conductivity correlation length than to the localization radius. The developed localized EnKF method
provides an approach to improve EnKF method in conductivity calibration. 相似文献
9.
Using data assimilation method to calibrate a heterogeneous conductivity field conditioning on transient flow test data 总被引：1，自引：1，他引：0
Juxiu Tong Bill X. Hu Jinzhong Yang 《Stochastic Environmental Research and Risk Assessment (SERRA)》2010,24(8):1211-1223
A data assimilation method is developed to calibrate a heterogeneous hydraulic conductivity field conditioning on transient
pumping test data. The ensemble Kalman filter (EnKF) approach is used to update model parameters such as hydraulic conductivity
and model variables such as hydraulic head using available data. A synthetical two-dimensional flow case is used to assess
the capability of the EnKF method to calibrate a heterogeneous conductivity field by assimilating transient flow data from
observation wells under different hydraulic boundary conditions. The study results indicate that the EnKF method will significantly
improve the estimation of the hydraulic conductivity field by assimilating continuous hydraulic head measurements and the
hydraulic boundary condition will significantly affect the simulation results. For our cases, after a few data assimilation
steps, the assimilated conductivity field with four Neumann boundaries matches the real field well while the assimilated conductivity
field with mixed Dirichlet and Neumann boundaries does not. We found in our cases that the ensemble size should be 300 or
larger for the numerical simulation. The number and the locations of the observation wells will significantly affect the hydraulic
conductivity field calibration. 相似文献
10.
对非球形冰晶94 GHz云雷达后向散射和衰减的研究 总被引：1，自引：0，他引：1
针对94 GHz毫米波云雷达的数据处理,基于离散偶极子近似法(DDA)计算了几种非球形冰晶的后向散射及衰减效率,探讨了不同冰云模型下冰云的雷达反射率因子(Z_e)和衰减系数(k)及冰水含量(IWC,记作W)的关系。结果表明:(1)形状对冰晶的散射及衰减效率与粒子大小有关。(2)在实际的冰云中,将六角形冰晶和椭圆冰晶看做同体积的球形粒子将低估其衰减和后向散射。将聚合物冰晶看做等体积球形,将高估其后向散射及衰减,子弹花冰晶的后向散射与同体积的球形相比有减小也有增大,但是衰减比同体积球形的小。(3)冰云模型对Z_e-k、Z_e-W关系具有较大影响,假设滴谱相同的条件下,得到了具体冰云模型下对应Z_e-k、Z_e-W关系的系数。这些探讨为我国W波段云雷达的数据处理提供了参考。 相似文献