Diffuse radiation,twilight, and photochemistry — I     

D. J. Lary  J. A. Pyle 《Journal of Atmospheric Chemistry》1991,13(4):373-392

A photochemical scheme which includes a detailed treatment of multiple scattering up to solar zenith angles of 96° (developed for use in a GCM) has been used to study partitioning within chemical families. Attention is drawn to the different zenith angle dependence of diffuse radiation for the two spectral regions <310 nm and >310 nm. The effect that this has on the so-called 40 km ozone problem is discussed. The importance of correctly including multiple scattering for polar ozone studies is emphasised.  相似文献   

Sulfur isotope measurement of sulfate and sulfide by high-resolution MC-ICP-MS   总被引：4，自引：0，他引：4  

Paul R. Craddock  Olivier J. Rouxel  Lary A. Ball  Wolfgang Bach   《Chemical Geology》2008,253(3-4):102-113

We have developed a technique for the accurate and precise determination of ³⁴S/³²S isotope ratios (δ³⁴S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O₂⁺. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (< 0.2‰, within analytical error), and are mathematically removed by on-peak zero subtraction and by bracketing of samples with standards determined at the same signal intensity (within 20%). Matrix effects are significant (up to 0.7‰) for matrix compositions relevant to many natural sulfur-bearing minerals. For solution analysis, sulfur isotope compositions are best determined using purified (matrix-clean) sulfur standards and sample solutions using the chemical purification protocol we present. For in situ analysis, where the complex matrix cannot be removed prior to analysis, appropriately matrix-matching standards and samples removes matrix artifacts and yields sulfur isotope ratios consistent with conventional techniques using matrix-clean analytes. Our method enables solid samples to be calibrated against aqueous standards; a consideration that is important when certified, isotopically-homogeneous and appropriately matrix-matched solid standards do not exist. Further, bulk and in situ analyses can be performed interchangeably in a single analytical session because the instrumental setup is identical for both. We validated the robustness of our analytical method through multiple isotope analyses of a range of reference materials and have compared these with isotope ratios determined using independent techniques. Long-term reproducibility of S isotope compositions is typically 0.20‰ and 0.45‰ (2σ) for solution and laser analysis, respectively. Our method affords the opportunity to make accurate and relatively precise S isotope measurement for a wide range of sulfur-bearing materials, and is particularly appropriate for geologic samples with complex matrix and for which high-resolution in situ analysis is critical.  相似文献   

Field and petrological evidence for a Late Palaeozoic (Upper Carboniferous–Permian) age of the Erfaulet orthogneiss (Gran Paradiso,western Alps)     

Benjamin Le Bayon  Michel Ballèvre 《Comptes Rendus Geoscience》2004,336(12):1079-1089

In the Gran Paradiso massif (western Alps), the boundary between the Erfaulet orthogneiss and the overlying metasediments (Money Complex) is interpreted as a Late Palaeozoic intrusive contact. Major arguments in favour of this hypothesis are: (i) the obliquity of the sedimentary layering with respect to the contact; (ii) the presence of aplitic dykes within the Money Complex; (iii) the lack of a mylonitic zone; and (iv) rare relics of an early generation of garnet in the Money metasediments, interpreted as evidence of the contact metamorphism of the Erfaulet granite. To cite this article: B. Le Bayon, M. Ballèvre, C. R. Geoscience 336 (2004).  相似文献   

A comparison of frameworks for separating the impacts of human activities and climate change on river flow in existing records and different near-future scenarios     

Soghra Andaryani  Vahid Nourani  James Ball  Saeed Jahanbakhsh Asl  Hamidreza Keshtkar  Dennis Trolle 《水文研究》2021,35(7):e14301

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Petrogenesis of the Bosworgey granitic cusp in the SW England tin province and its implications for ore mineral genesis     

T. K. Ball  I. R. Basham 《Mineralium Deposita》1984,19(1):70-77

The Bosworgey granite cusp forms an apical portion of the concealed northern extension of the Tregonning-Godolphin granite ridge. It is characterised by unusually high values of B, P, Mn, Fe, As, Cu, Nb, Ta, Bi, Sn, W, U and S which are present largely as tourmaline, apatite, pyrite, arsenopyrite, chalcopyrite, bismuth, columbite, cassiterite, wolframite and uraninite; and low levels of Zr, Hf, Ti and REE present in zircon, ilmenite and monazite. The granite is classified as Sn and W specialised (Tischendorf, 1974) and it belongs to the ilmenite series of Japanese workers. The classification of Chappell and White (1974) (S and I type granites) is shown to be inapplicable to Cornubian rocks although the Bosworgey samples show characteristics of S type granites. The accessory mineral assemblages are typical of high temperature lodes (cassiterite, wolframite, arsenopyrite, chalcopyrite) and the assamblage is concluded to be the cusp analogue of hypothermal lodes produced by extreme differentiation and concentration of volatiles. It is speculated that such granites could provide the parent material for the mesothermal crosscourse mineralisation (pitchblende, bismuth, pyrite, galena, sphalerite).  相似文献   

¹⁴C content of ten meteorites measured by tandem accelerator mass spectrometry     

R.M. Brown  H.R. Andrews  G.C. Ball  N. Burn  Y. Imahori  J.C.D. Milton  E.L. Fireman 《Earth and Planetary Science Letters》1984,67(1):1-8

¹⁴C has been measured in three North American and seven Antarctic meteorites with the Chalk River MP tandem accelerator. In most cases cosmogenic¹⁴C, which is tightly bound, was separated from absorbed atmospheric radiocarbon by stepwise heating extractions. Terrestrial ages obtained by comparing cosmogenic¹⁴C in the meteorite to that in Bruderheim are (7.2 ± 0.6) × 10³ years for Yamato 7304, (11.6 ± 0.4) × 10³ years for Estacado, and range from (32.7 ± 0.5) × 10³ to (41.0 ± 0.8) × 10³ years for six meteorites recovered at Allan Hills and its vicinity. The present upper limit to age determination by the accelerator method varies from 50 × 10³ to 70 × 10³ years depending upon mass and carbon content of the sample. The natural limit caused by cosmic ray production of¹⁴C in silicate rocks at 2000 m elevation is estimated to be (55 ± 5) × 10³ years. “Weathering ages” were estimated for the Antarctic meteorites from the specific activity of loosely-bound CO₂ considered to be absorbed from the terrestrial atmosphere on weathering. The accelerator measurements are in accordance with previous low-level counting measurements but have higher precision and sensitivity.  相似文献   

Instrumental temperature records at two sites in Central Canada: 1768 to 1910     

Timothy F. Ball  Roger A. Kingsley 《Climatic change》1984,6(1):39-56

As a result of affiliation between the Hudson's Bay Company and the Royal Society a relatively large number of instrumental temperature records are available from York Factory and Churchill Factory on the southwest of Hudson Bay beginning in 1768. The nature of these records, details of the instruments and information about the observers are presented. The major difficulty with the records is that the number of observations and the time of observation varied considerably. Adjustment factors were calculated for all of the combinations using a modern record maintained at the Churchill airport. By combining the Hudson's Bay Company record with data recorded by members of the Royal Canadian Mounted Police after 1852, and up to 1910, a long and relatively continuous record of daily and monthly average temperatures has been created for Central Canada.  相似文献   

Specific-lon electrode determinations of sulfide preconcentrated from San Francisco Bay waters     

Davison V. Vivit  James W. Ball  Everett A. Jenne 《Environmental Geology》1984,6(2):79-90

Measurements of low-level dissolved-sulfide concentrations in estuarine water from San Francisco Bay have been made using the sulfide-specific electrode after preservation, separation, and preconcentration of the sulfide species. The separation and preconcentration were acheived by coprecipitation of ZnS with Zn(OH)₂ followed by collection and dissolution of the precipitate, giving concentration factors up to 160-fold Preconcentration provided sulfide solutions that were adequately measurable within the practical working range of the specific-ion electrode The sulfide detection limit with the preconcentration step is 0 02 μg/l Spike recoveries in the range of 81 to 10 1% have been achieved for laboratory-prepared samples having S²⁻ concentrations as low as 0 6 μg/l and 84 to 100% for an estuarine sample spiked in the field with 2 μg/l (S(−II) Positive correlations have been found between dissolved S(−II) concentrations and concentrations of dissolved Cd, Cu, and Ni, negative correlations have been found between bisulfide (HS⁻) activity and activities of Cd²⁺, Cu²⁺, and Ag⁺ species  相似文献   

Estimation of heterogeneous reaction rates for stratospheric trace gases with particular reference to the diffusional uptake of HCl and ClONO2 by polar stratospheric clouds     

S. Ghosh  D. Lary  J. A. Pyle 《Annales Geophysicae》1995,13(4):406-412

The stratosphere holds a variety of particulates like polar stratospheric clouds (PSCs) and sulphate aerosols which catalyse chemical reactions. These reactions cause changes in the composition of the stratosphere, including the redistribution of active chlorine which might lead to ozone destruction. As a result during recent years a lot of effort has been directed towards the quantification of the uptake of trace gases like ClONO₂, HCl, etc. into these particulates. However, it has been observed that many of the two and three dimensional models used in such studies are constrained by the lack of adequate rate constant data. This paper describes a theoretical approach to estimate the reaction rate constants for 23 gases on both types of polar stratospheric clouds (type I and II). It is found that for gases like N₂O₅, ClONO₂ and HCl, diffusional uptake is important and contributes significantly to the heterogeneous reaction rate. A complete Lennard-Jones calculation is used to accurately compute the trace gas diffusion coefficients.  相似文献   

Ground Water Modeling for Risk Assessment Purposes: Use of a Gaussian-Distributed Transport Model and a Batch Flush Model     

David J. Cushman  Stephen D. Ball 《Ground Water Monitoring & Remediation》1993,13(4):162-172

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