The composition and crystallinity of the near-surface regions of weathered alkali feldspars     

Martin R. Lee  Mark E. Hodson  Maureen MacKenzie  Caroline L. Smith 《Geochimica et cosmochimica acta》2008,72(20):4962-4975

Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction.  相似文献   

Baltic cod recruitment - the impact of climate variability on key processes   总被引：3，自引：0，他引：3  

Koster  Friedrich W.; Mollmann  Christian; Hinrichsen  Hans-Harald; Wieland  Kai; Tomkiewicz  Jonna; Kraus  Gerd; Voss  Rudiger; Makarchouk  Andrei; MacKenzie  Brian R.; St. John  Michael A.; Schnack  Dietrich; Rohlf  Norbert; Linkowski  Tomasz; Beyer  Jan E. 《ICES Journal of Marine Science》2005,62(7):1408-1425

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Absolute spectrophotomery of comets 1973XII and 1975IX: II. Profiles of the Swan bands     

Lucy L. Danylewych  Ralph W. Nicholls  John S. Neff  Jeremy B. Tatum 《Icarus》1978,35(1):112-120

Absolute spectrophotometric measurements of the Swan bands of two comets have been compared with computed synthetic spectra using modern Franck-Condon and Hönl-London factors, and varying rotational, vibrational, and electronic excitation temperatures. Rotational and vibrational temperatures were obtained for the comets. Although the electronic excitation temperature and the molecular column density cannot be separated, a relationship is found between these two quantities. A review is made of recent determinations of column densities for CN in comets.  相似文献   

Structural controls on Tertiary orogenic gold mineralization during initiation of a mountain belt, New Zealand   总被引：3，自引：2，他引：3  

D. Craw  M. Begbie  D. MacKenzie 《Mineralium Deposita》2006,41(7):645-659

Two types of structurally controlled hydrothermal mineralization have occurred during folding of fissile schist in southern New Zealand: fold-related mineralization and normal fault-related mineralization. Both types have the same mineralogy and textures, and are dominated by quartz–ankerite veins and silicified breccias with ankeritic alteration. Most mineralized zones are thin (centimetre scale), although host schist is commonly impregnated with ankerite up to 20 m away. Thick (up to 5 m wide) mineralized zones are generally gold-bearing and contain pyrite and arsenopyrite with stibnite pods locally. Some of these auriferous zones have been extensively mined historically despite rugged topography and difficult access. Mineralization occurred during regional tectonic compression in the initial stages of development of the Southern Alps mountain belt at the Pacific–Australian plate boundary in the Miocene. Most of the gold-bearing deposits occur in east to south-east, striking normal faults that cut across mesoscopic folds in a belt that coincides with the southern termination of a regional-scale north trending antiform. Mineralized zones have similar structural control and relative timing to a nearby swarm of Miocene lamprophyre dykes and carbonatites. Limited stable isotopic data (C and O) and trace element geochemistry suggest that there was probably no genetic link between the igneous activity and gold mineralization. However, these two types of fluid flow have been controlled by the same tectonically created crustal plumbing system. This Miocene hydrothermal activity and gold deposition demonstrates that orogenic (mesothermal) mineralization can occur during the inception of an orogenic belt, not just in the latter stages as is commonly believed. These Miocene structures have been preserved in the orogen because the locus of uplift has moved northwards, so the early-formed gold deposits have not yet been structurally overprinted or eroded.  相似文献   

Stormflow concentration–discharge dynamics of suspended sediment and dissolved phosphorus in an agricultural watershed     

Lucy A. Rose  Diana L. Karwan 《水文研究》2021,35(12):e14455

Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.  相似文献   

Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy          下载免费PDF全文

Luke Daly  Phil A. Bland  Svetlana Tessalina  David W. Saxey  Steven M. Reddy  Denis Fougerouse  William D.A. Rickard  Lucy V. Forman  Alexandre La Fontaine  Julie M. Cairney  Simon P. Ringer  Bruce F. Schaefer  Daniel Schwander 《Geostandards and Geoanalytical Research》2018,42(3):279-299

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.  相似文献   

Geomorphic constraints on the active tectonics of southern Taiwan     

Lucy A. Ramsey  Richard T. Walker  James Jackson 《Geophysical Journal International》2007,170(3):1357-1372

Taiwan is a region of rapid active tectonics, yet the study of the tectonic processes that shape the interior of the island is difficult due to the high rates of erosion and dense vegetation. We use digital topography to look for indications of active deformation preserved in the local geomorphology. In particular, anomalies in the regional pattern of drainage are used to infer zones of enhanced tectonic activity. The apparent anticlockwise rotation of major river systems in plan view indicates the presence of a diffuse zone of left-lateral shear running down the southeastern side of Taiwan. Asymmetries in the catchments of individual drainage basins show the influence of varying rates of uplift across southern Taiwan, with the most rapid uplift close to Taitung at the indentation point of the Luzon arc with the Chinese continental margin. Our interpretations, though based predominantly on remote-sensing observations, are consistent with the available field evidence. This study demonstrates the usefulness of drainage basins as tectonic markers in the quantification of regional strain and uplift, which may have wider applicability in other deforming parts of the world.  相似文献   

Electrical resistivity structure of the Valu Fa Ridge, Lau Basin, from marine controlled‐source electromagnetic sounding     

Lucy MacGregor  Martin Sinha  Steven Constable 《Geophysical Journal International》2001,146(1):217-236

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Tracer Test Evaluation of a Drainage Ditch Capture Zone   总被引：1，自引：0，他引：1  

Lucy W. Chambers  Jean M. Bahr 《Ground water》1992,30(5):667-675

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Experimental test of the wind-shear theory. A reply—rocket-borne magnetometers do measure B     

S.H. Hall  E.C. MacKenzie 《Planetary and Space Science》1973,21(10):1817-1819

The apparent inconsistencies noted by Whitehead ⁽¹⁾ in the ionization, electron density, wind and magnetic field data of the rocket flights SL 130 and 131 (Hall et al. ⁽²⁾) are resolved by the presentation of further experimental detail. Observational accuracy and in particular the heading correction procedure for the magnetic field values are discussed. It is also pointed out that the interaction of the steady EW wind component with the E _g ionization profile provides an additional contribution to the E _g magnetic field. It is concluded that within the experimental limitations the experiment remains a fair test of the wind-shear theory.  相似文献