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1.
Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain 总被引：1，自引：0，他引：1
The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ11B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ11B are related to pollution of human origin. 相似文献
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The elevated levels of primary productivity associated with eastern boundary currents are driven by nutrient- rich waters upwelled from depth, such that these regions are typically characterised by high rates of nitrate-fuelled phytoplankton growth. Production studies from the southern Benguela upwelling system (SBUS) tend to be biased towards the summer upwelling season, yet winter data are required to compute annual budgets and understand seasonal variability. Net primary production (NPP) and nitrate and ammonium uptake were measured concurrently at six stations in the SBUS in early winter. While euphotic zone NPP was highest at the stations nearest to the coast and declined with distance from the shore, a greater proportion was potentially exportable from open-ocean surface waters, as indicated by the higher specific nitrate uptake rates and f-ratios (ratio of nitrate uptake to total nitrogen consumption) at the stations located off the continental shelf. Near the coast, phytoplankton growth was predominantly supported by ammonium despite the high ambient nitrate concentrations. Along with ammonium concentrations as high as 3.6 µmol l–1, this strongly suggests that nitrate uptake in the inshore SBUS, and by extension carbon drawdown, is inhibited by ammonium, at least in winter, although this has also been hypothesised for the summer. 相似文献
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Ana Moreno Blas L. Valero‐Garcés Montserrat Jiménez‐Sánchez María José Domínguez‐Cuesta M. Pilar Mata Ana Navas Penélope González‐Sampériz Heather Stoll Pedro Farias Mario Morellón J. Pablo Corella Mayte Rico 《第四纪科学杂志》2010,25(7):1076-1091
A sedimentological and geochemical study of the Lago Enol sequence (Cantabrian Mountains, northern Spain), together with detailed geomorphological mapping, provides a first record of glacier evolution and climate change over the last 40 ka in the Picos de Europa National Park. The Enol glacier retreated from its maximum extent prior to 40 ka BP as demonstrated by the onset of proglacial lacustrine sedimentation in two glaciated depressions: the Comella hollow to the north (before 40 ka BP) and the Lago Enol (before 38 ka BP). These results support previous evidence that the maximum extent of southern European glaciers occurred earlier than in northern Europe. Alternation of homogeneous and laminated proglacial sediments during the glacier retreat illustrate a dynamic glacial evolution during the Marine Isotope Stage (MIS) 3 (40–26 ka BP). A slight warming is detected at 26 ka ago with the change from proglacial sediments (in a lake located in contact to the glacier) to glaciolacustrine sedimentation (in a non‐contact or distal lake). Finally, the onset of organic‐rich sediments took place at 18 ka ago. This last transition occurred in two phases, similarly to the North Atlantic Last Termination, suggesting a link between North Atlantic Deep Water formation oscillations and palaeohydrological variability in the Cantabrian Mountains. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
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Juan Pablo Corella Adel El Amrani Javier Sigró Mario Morellón Eugenio Rico Blas Lorenzo Valero-Garcés 《Journal of Paleolimnology》2011,46(3):469-485
We present a high-resolution, multiproxy reconstruction of the depositional history of Lake Arreo, northern Spain, for the
last 60 years. We conducted sedimentological, geochemical and diatom analyses in short cores and made a detailed comparison
with regional instrumental climate data (1952–2007), limnological monitoring of the lake (1992–2008) and recent land use changes
that affect the lake catchment. Chronology is based on “floating” discontinuous varve counts and 137Cs and 14C dates. Four periods were identified in the Lake Arreo recent history: (1) prior to 1963, varved facies intercalated with
fine turbidite deposits, and diatom assemblages dominated by Cyclotella taxa indicate predominantly meromictic conditions, (2) from 1964 to 1978, permanent anoxia persisted in bottom waters, as shown
by similar facies and diatom assemblages as before, though detrital layers were coarser, (3) from 1979 to 1994, sediment delivery
to the lake increased and laminated, clastic facies were deposited, and (4) from 1995 to 2008, dominance of massive facies
and an increase in Fragilaria tenera and Achnanthes minutissima reflect relatively lower lake levels, less frequent bottom anoxia with more frequent water column mixing, similar to modern
conditions. The period 1952–1979 was a time of meromixis and varved facies deposition, and was characterized by higher rainfall
and less intense agricultural pressure in the watershed. There were two short humid periods (1992–1993 and 1996–1998) when
monitoring data show more anoxic weeks per year and relatively higher lake levels. Increased cultivation of small landholdings
in 1963, and particularly after 1979, caused a large increase in sediment delivery to the lake. The inferred lake evolution
is in agreement with monitoring data that suggest a transition from dominantly meromictic conditions prior to 1993–1994 to
a predominantly monomictic pattern of circulation since then, particularly after 2000. The synergistic effects of intensive
water extraction for irrigation and lower rainfall since 1979, and particularly since 1994, brought the long period of meromictic
conditions in Lake Arreo to an end. Water balance and sediment delivery to the lake are dominant factors that control the
limnological and mixing conditions in Lake Arreo and they must be considered in management and restoration plans. 相似文献
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Representative profiles of inorganic nitrogenous species dissolved in interstitial waters of coral reef sands are presented. Ammonium is the dominant nitrogenous species in these pore waters with concentrations of up to 40 μm. Nitrate is present but in lower concentrations. Nitrite is found only occasionally in trace amounts. Computations of diffusive fluxes and inferences concerning microbial activity are derived from the profile structures. Computed flux rates of nitrogenous species from the sediment to the water column range between 0.75 and 1.37 μM m−1 h−1. These inputs may represent a significant source of recycled nitrogen to the primary producers of the coral reef ecosystem. 相似文献
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内蒙古西拉沐伦成矿带碾子沟钼矿床成矿流体地球化学特征 总被引：7，自引：3，他引：4
碾子沟钼矿床是内蒙古西拉沐伦钼多金属成矿带中石英脉型钼矿床的典型代表,矿体以石英大脉形式产于燕山期中粗粒黑云母二长花岗岩内,受断裂构造控制。流体包裹体研究发现包裹体均为气液两相,按照相比不同,可进一步分为WL型(5%～20%)和WV型(20%～50%)。Ⅰ阶段流体为低温(89.3～245.2℃)、中低盐度(2.07%～17.96%NaCleqv)流体;Ⅱ阶段流体具有中低温(134.4～458.8℃,峰值170℃～240℃)、中低盐度(0.53%～19.92%NaCleqv)特征;Ⅲ阶段流体为低温(134.9～202.4℃)、中低盐度(4.96%～14.97%NaCleqv)流体。流体成分均以H2O为主(96.1mol%),含少量挥发份CO2、N2、CH4、C2H6、Ar、H2S,阳离子以Na+为主,阴离子以SO42-、Cl-为主,属NaCl-H2O体系。各阶段成矿热液氢、氧同位素特征为:δ18OH2O介于-5.75‰～-1.90‰、δD介于-128.821‰～-109.234‰,说明成矿流体是岩浆热液与古大气降水混合而成。开放的断裂体系为流体混合创造了条件,流体的混合作用是造成碾子沟辉钼矿沉淀成矿的主要原因。这与斑岩型钼矿床的高盐度流体以及以沸腾为主的矿石沉淀机制具有显著区别。 相似文献
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J Kantoussan JM Ecoutin R Laë OT Thiaw L Tito de Morais 《African Journal of Marine Science》2018,40(2):175-185
This study examines the effects of increasing salinity on fish assemblage structure in the Casamance Estuary, Senegal, using a series of indices. The study data were derived from commercial fishery surveys conducted between April and July 2005. Analysis of within-trophic-group diversity in the Casamance Estuary shows a significant drop in the diversity of apex predators in the upper, more saline reaches of the estuary. By contrast, primary consumers adapted well to salinity changes and exhibited higher taxonomic diversity in the upper reaches of the estuary than in the lower reaches. The findings also indicate decreases in average sizes of the landed species and the trophic levels among fish catches in the direction of the upper reaches. However, the catch per unit effort (CPUE) was globally higher in the upstream area of the estuary as compared with the downstream area. This increasing CPUE trend from the lower towards the upper reaches is attributed to (i) the high primary productivity in the upper Casamance Estuary; (ii) the increasing abundance of euryhaline fish species in an upstream direction; and (iii) ‘telescoping’ of the food chain through the presence of mostly herbivorous fishes in the upper reaches. Such a situation likely facilitated high fish production in the upstream area of the estuary, though multimetric indices indicated unfavourable living conditions for many fish taxa in this area. 相似文献
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T-C Livingstone JM Harris AT Lombard AJ Smit DS Schoeman 《African Journal of Marine Science》2018,40(1):51-65
Marine bioregional planning requires a meaningful classification and spatial delineation of the ocean environment using biological and physical characteristics. The relative inaccessibility of much of the ocean and the paucity of directly measured data spanning entire planning regions mean that surrogate data, such as satellite imagery, are frequently used to develop spatial classifications. However, due to a lack of appropriate biological data, these classifications often rely on abiotic variables, which act as surrogates for biodiversity. The aim of this study was to produce a fine-scale bioregional classification, using multivariate clustering, for the inshore and offshore marine environment off the east coast of South Africa, adjacent to the province of KwaZulu-Natal and out to the boundary of the exclusive economic zone (EEZ), 200 nautical miles offshore. We used remotely sensed data of sea surface temperature, chlorophyll a and turbidity, together with interpolated bathymetry and continental-slope data, as well as additional inshore data on sediments, seabed oxygen and bottom temperature. A multivariate k-means analysis was used to produce a fine-scale marine bioregionalisation, with three bioregions subdivided into 12 biozones. The offshore classification was primarily a pelagic bioregionalisation, whereas the inshore classification (on the continental shelf) was a coupled benthopelagic bioregionalisation, owing to the availability of benthic data for this area. The resulting classification was used as a base layer for a systematic conservation plan developed for the province, and provided the methods for subsequent planning conducted for the entire South African EEZ. Validation of the classification is currently being conducted in marine research programmes that are sampling benthic biota and habitats in a sampling design stratified according to the biozones delineated in this study. 相似文献