Solubility of FeO in (Mg,Fe)SiO₃ perovskite and the post-perovskite phase transition     

Shigehiko Tateno  Kei Hirose  Nagayoshi Sata  Yasuo Ohishi 《Physics of the Earth and Planetary Interiors》2007,160(3-4):319-325

Phase relations in Mg_0.5Fe_0.5SiO₃ and Mg_0.25Fe_0.75SiO₃ were investigated in a pressure range from 72 to 123 GPa on the basis of synchrotron X-ray diffraction measurements in situ at high-pressure and -temperature in a laser-heated diamond-anvil cell (LHDAC). Results demonstrate that Mg_0.5Fe_0.5SiO₃ perovskite is formed as a single phase at 85–108 GPa and 1800–2330 K, indicating a high solubility of FeO in (Mg,Fe)SiO₃ perovskite at high pressures. Post-perovskite appears coexisting with perovskite in Mg_0.5Fe_0.5SiO₃ above 106 GPa at 1410 K, the condition very close to the post-perovskite phase transition boundary in pure MgSiO₃. The coexistence of perovskite and post-perovskite was observed to 123 GPa. In addition, post-perovskite was formed coexisting with perovskite also in Mg_0.25Fe_0.75SiO₃ bulk composition at 106–123 GPa. In contrast to earlier experimental and theoretical studies, these results show that incorporation of FeO stabilizes perovskite at higher pressures. This could be due to a larger ionic radius of Fe²⁺ ion, which is incompatible with a small Mg²⁺ site in the post-perovskite phase.  相似文献   

Observational signature of planet formation: The ALMA view     

Nagayoshi Ohashi 《Astrophysics and Space Science》2008,313(1-3):101-107

Protoplanetary disks are the most probable sites where planet formation takes place. According to theory, planet formation in protoplanetary disks should show remarkable signatures, such as a gap/hole or a spiral structure. In fact, recent high-angular and high-sensitivity observations in millimeter and submillimeter wavelengths, as well as optical/near-IR wavelengths, have shown such structures in protoplanetary disks. Two particular examples of such disks around AB Aurigae and HD 142527 are discussed here, with an emphasis on results obtained using the Submillimeter Array. These disks—and their probable planet formation—will be very important future targets for ALMA to study the physical process of planet formation in detail.  相似文献   

Phase relations of iron and iron–nickel alloys up to 300 GPa: Implications for composition and structure of the Earth's inner core     

Yasuhiro Kuwayama  Kei Hirose  Nagayoshi Sata  Yasuo Ohishi 《Earth and Planetary Science Letters》2008,273(3-4):379-385

We have investigated the phase relations of iron and iron–nickel alloys with 18 to 50 wt.% Ni up to over 300 GPa using a laser-heated diamond-anvil cell. The synchrotron X-ray diffraction measurements show the wide stability of hcp-iron up to 301 GPa and 2000 K and 319 GPa and 300 K without phase transition to dhcp, orthorhombic, or bcc phases. On the other hand, the incorporation of nickel has a remarkable effect on expanding the stability field of fcc phase. The geometry of the temperature–composition phase diagram of iron–nickel alloys suggests that the hcp–fcc–liquid triple point is located at 10 to 20 wt.% Ni at the pressure of the inner core boundary. The fcc phase could crystallize depending on the nickel and silicon contents in the Earth's core, both of which are fcc stabilizer.  相似文献   

Observations of disks around protostellar sources with nobeyama millimeter array     

Nagayoshi Ohashi  Masahiko Hayashi 《Astrophysics and Space Science》1995,224(1-2):13-16

We present results from a survey observation of circumstellar disks around protostellar sources associated with the Taurus molecular cloud. Our result shows that the 98 GHz continuum emission tends to be weaker for embedded sources than for visible T Tauri stars, which is consistent with our previous interpretation of disk formation. Direct observations of the formation of a centrifugally supported viscous accretion disk around HL Tau is discussed.  相似文献   

The development of Fe-nodules surrounding biological material mediated by microorganisms     

Hidekazu Yoshida  Koshi Yamamoto  Yuki Murakami  Nagayoshi Katsuta  Toru Hayashi  Takeshi Naganuma 《Environmental Geology》2008,55(6):1363-1374

Takashikozo is a phenomenon of Quaternary sediments in Japan. They are cylindrical Fe-oxyhydroxide nodules that form as plaques round plant roots, where Fe is preferentially concentrated to develop a solid wall. Structural features suggest that after the roots have decayed, the central space where the roots were situated acts as a flow path for oxidized water. Analysis of microbial 16S rDNA extracted from the nodules identified iron-oxidizing bacteria encrusted round the roots where they are the likely initiators of nodule formation. Direct microscopic observation revealed an accumulation of Fe-oxyhydroxides that fill the pore spaces and is also likely to be linked with the encrusting microbial colonies. Geological history and nanofossil evidence suggest that these Fe-nodules may have been buried at a depth of up to several tens of meters for at least 10⁵ years in reducing Quaternary sediments. Thus Fe-oxyhydroxide nodules that have formed in a geological environment at the interfaces between water and rock by microbial mediation can persist under reducing conditions. If this is the case, the phenomenon is significant as an analogue of post-closure conditions in radioactive waste repositories, since it could influence nuclide migration.  相似文献   

Phase transition in CaSiO₃ perovskite     

Tetsuya Komabayashi  Kei Hirose  Nagayoshi Sata  Yasuo Ohishi  Leonid S. Dubrovinsky 《Earth and Planetary Science Letters》2007,260(3-4):564-569

A phase transition in pure CaSiO₃ perovskite was investigated at 27 to 72 GPa and 300 to 819 K by in-situ X-ray diffraction experiments in an externally-heated diamond-anvil cell. The results show that CaSiO₃ perovskite takes a tetragonal form at 300 K and undergoes phase transition to a cubic structure above 490–580 K in a pressure range studied here. The transition boundary is strongly temperature-dependent with a slightly positive dT / dP slope of 1.1 (± 1.3) K/GPa. It is known that the transition temperature depends on Al₂O₃ content dissolved in CaSiO₃ perovskite [Kurashina et al., Phys. Earth Planet. Inter. 145 (2004) 67–74]. The phase transition in CaSiO₃(+ 3 wt.% Al₂O₃) perovskite therefore could occur in a cold subducted mid-oceanic ridge basalt (MORB) crust at about 1200 K in the upper- to mid-lower mantle. This phase transition is possibly ferroelastic-type and may cause large seismic anomalies in a wide depth range.  相似文献   

High-pressure behavior of MnGeO3 and CdGeO3 perovskites and the post-perovskite phase transition     

Shigehiko Tateno  Kei Hirose  Nagayoshi Sata  Yasuo Ohishi 《Physics and Chemistry of Minerals》2006,32(10):721-725

The stability and high-pressure behavior of perovskite structure in MnGeO₃ and CdGeO₃ were examined on the basis of in situ synchrotron X-ray diffraction measurements at high pressure and temperature in a laser-heated diamond-anvil cell. Results demonstrate that the structural distortion of orthorhombic MnGeO₃ perovskite is enhanced with increasing pressure and it undergoes phase transition to a CaIrO₃-type post-perovskite structure above 60 GPa at 1,800 K. A molar volume of the post-perovskite phase is smaller by 1.6% than that of perovskite at equivalent pressure. In contrast, the structure of CdGeO₃ perovskite becomes less distorted from the ideal cubic perovskite structure with increasing pressure, and it is stable even at 110 GPa and 2,000 K. These results suggest that the phase transition to post-perovskite is induced by a large distortion of perovskite structure with increasing pressure.  相似文献   

Episyenite formation in the Toki granite,central Japan     

Shoji?NishimotoEmail author  Hidekazu?Yoshida  Yoshihiro?Asahara  Tadahiko?Tsuruta  Masayuki?Ishibashi  Nagayoshi?Katsuta 《Contributions to Mineralogy and Petrology》2014,167(1):960

Episyenite is a quartz-depleted vuggy rock resulting from hydrothermal alteration of granitic rocks. This is the first report of its existence in an island arc, which is identified in a deep drill core of the Toki Cretaceous granite distributed in central Japan. In order to understand the petrographical features of the episyenite, neutron porosity measurement, geochemical analysis, microscopic observation, and X-ray computed tomography scanning were carried out. The results show remarkably high porosity (35.4 %) due to interconnecting vugs and the removal of quartz, plagioclase, and biotite. The Rb–Sr isotopic results and the paragenetic sequence of secondary minerals in the vugs suggest that the hydrothermal alteration process can be divided into an episyenitization stage and a later hydrothermal stage. At the episyenitization stage (70.6 ± 3.1 Ma) ca. 6 million years after the emplacement of the unaltered granite (76.3 ± 1.5 Ma), dissolution of quartz, biotite, and plagioclase occurred and was followed by the precipitation of albite, vermicular chlorite, and platy calcite. The episyenitization is considered as a local alteration of the Toki granite in an isotopically closed system. At the later hydrothermal stage, illite and secondary quartz precipitated from circulating meteoric-derived water in the dissolution vugs. Superimposing alteration at the later hydrothermal stage is limited, which results in the preservation of the episyenite in an almost primitive condition.  相似文献   

Pressure-induced structural evolution of pyrite-type SiO<Subscript>2</Subscript>     

Yasuhiro Kuwayama  Kei Hirose  Nagayoshi Sata  Yasuo Ohishi 《Physics and Chemistry of Minerals》2011,38(8):591-597

The equation of state and pressure-induced structural evolution of pyrite-type SiO₂ have been investigated based on synchrotron X-ray diffraction measurements in a diamond-anvil cell. The Rietveld refinement revealed that the oxygen coordinate x of pyrite-type SiO₂ increases with increasing pressure. The SiO₆ coordination polyhedra of pyrite-type SiO₂ is less compressible than the unit cell, and the increase in x induces a rotation of the SiO₆ coordination polyhedra to fill the blank space in the unit cell. Thus, the volume reduction in pyrite-type SiO₂ is achieved mainly by the rotation of the SiO₆ polyhedra, rather than by the compression of the SiO₆ polyhedra. In addition, the increase in x with increasing pressure enhances a distortion of the coordination polyhedra of pyrite-type SiO₂, implying that pyrite-type SiO₂ is not likely to transform into a fluorite-type structure at higher pressures.  相似文献   

Advanced Micro-XRF Method to Separate Sedimentary Rhythms and Event Layers in Sediments: Its Application to Lacustrine Sediment from Lake Suigetsu,Japan     

Nagayoshi Katsuta  Masao Takano  Shin-ichi Kawakami  Shoji Togami  Hitoshi Fukusawa  Mineo Kumazawa  Yoshinori Yasuda 《Journal of Paleolimnology》2007,37(2):259-271

Event-related sedimentary layers, which are deposited occasionally due to volcanic eruptions, earthquakes or heavy rains, are often contained in the rhythmical sequences of lacustrine and marine sediments. We have developed an analytical method for separating the sedimentary rhythms and the event layers identified using the scanning X-ray analytical microscope (SXAM) and obtained sequential profiles of seven elements Al, Si, K, Ca, Ti, Mn, and Fe in the lacustrine sediment from Lake Suigetsu, Japan. Two types of event layers could be detected from the elemental composition of 33 layers of sediment: three known volcanic ash layers and 30 clay layers containing 12 turbidites. The recurrence interval of the latter, which may potentially be initiated and archived by locally important earthquakes, is estimated to be an average of 640 ± 160 years by using Sompi event analysis (SEA) based on an autoregressive (AR) model. After removing those portions that represented event layers from the elemental profiles, we obtained event-removed (ER) temporal profiles based on the tephrochronology of the three volcanic ash layers. The ER temporal profiles of manganese and iron, probably representing the siderite content, showed a millennial-scale variation in the Holocene that corresponded well with ice-rafting events in the North Atlantic.  相似文献