Geochemical and mineralogical evidence of tectonic and sedimentary factors controlling the origin of ferromanganese crusts associated to stratigraphic discontinuities (Betic Cordilleras, SE of Spain)     

Juan Jiménez-Millán  Luis M. Nieto 《Chemie der Erde / Geochemistry》2008,68(3):323-336

Ferromanganese crusts were found in carbonates of tectonostratigraphic units located in the northern and southern areas of the eastern External Subbetic of the Betic Cordilleras (SE Spain). The crusts are associated with four stratigraphic discontinuities of the Jurassic pelagic swells sequences: D1 (Late Carixian-Early Domerian), D2 (Middle Toarcian-Early Bajocian), D3 (Middle Bathonian-Middle Oxfordian), D4 (Early Tithonian-Late Albian). Two main textural types of crusts are distinguished. Type I crusts are thin and characterized by the presence of goethite, quartz, albite and phyllosilicates. Moreover, they show Si, Al, Mg, Na, Ti and K contents close to the European Shale Composite contents and Fe/Mn ratios (>350) higher than type II crusts. Type II crusts occur as thicker banded laminae and/or macrooncoids. They consist mainly of goethite and Mn-oxyhydroxides, which are enriched in REE, Co, Ni and Cu and show a strong Ce positive anomaly. After stratigraphical, mineralogical and geochemical data, the crust formation would be produced by the exposition of bottom sediments during long periods to a thin layer of oxidizing sea and porewater enriched in metallic elements. The textural and compositional variations between crusts can be explained by taking into account the bathymetric conditions. In shallower swells, the precipitation of a thick layer of banded type II crusts and in deeper areas, thin type I crusts were formed. Organic influence was only important in crusts from D3 of the northern area where textural evidence indicates the existence of seasonal periodically alternation between organism accretion and fine sedimentation. These were preceded and followed by phases in which the inorganic precipitation of oxides prevailed together with the fine sedimentation.  相似文献   

Regional retrograde alteration of sub-greenschist facies chlorite to smectite     

Fernando Nieto  Nicolás Velilla  Donald R. Peacor  Miguel Ortega Huertas 《Contributions to Mineralogy and Petrology》1994,115(3):243-252

Dioctahedral smectite is present as a retrograde alteration product of chlorite in Permian-Triassic red slates of the Malaguide Complex in Sierra de Espuña (Betic Cordillera). Mineral assemblages and textures, illite crystallinity indices, and fluid inclusion data indicate sub-greenschist facies conditions that reached at least 180°C in the higher-grade tectonic unit of the Malaguide Complex, preceding formation of smectite. Smectite, having K as the dominant interlayer cation, occurs ubiquitously intercalated with trioctahedral chlorite as thin packets of layers and as individual layers that commonly change to chlorite along layers. Although some chlorite is typically homogeneous and trioctahedral, much chlorite shows signs of alteration and has compositions corresponding to different degrees of smectite contaimination. The incompatibility of metamorphic grade with the occurrence of smectite, the general association of chlorite and smectite, and the textural relations collectively show that dioctahedral smectite is derived through replacement of trioctahedral chlorite. Such replacement occurs on a regional basis and demonstrates that caution must be used in interpreting the occurrence of smectite in pelites as being due to prograde processes. Alteration of trioctahedral chlorite under oxidizing conditions due to introduction of phreatic water after uplift of the Betic Cordillera is proposed as the cause of formation of smectite.  相似文献   

The behavior of trace elements during schwertmannite precipitation and subsequent transformation into goethite and jarosite   总被引：5，自引：0，他引：5  

Patricia Acero  Carlos Ayora  José-Miguel Nieto 《Geochimica et cosmochimica acta》2006,70(16):4130-4139

Schwertmannite is a ubiquitous mineral formed from acid rock drainage (ARD), and plays a major role in controlling the water chemistry of many acid streams. The formation of schwertmannite was investigated in the acid discharge of the Monte Romero abandoned mine (Iberian Pyrite Belt, SW, Spain). Schwertmannite precipitated from supersaturated solutions mainly owing to the oxidation of Fe(II) to Fe(III) and transformed with time into goethite and jarosite. In a few hours, schwertmannite precipitation removed more than half of the arsenic load from solution, whereas the concentration of divalent trace metals (Zn, Cu, Pb, Cd, Ni, and Co) remained almost unchanged. In the laboratory, natural schwertmannite was kept in contact with its coexisting acid water in a flask with a solid-liquid mass ratio of 1:5 for 353 days. During this time, the pH of the solution dropped from 3.07 to 1.74 and the concentrations of sulfate and Fe increased. During the first 164 days, schwertmannite transformed into goethite plus H₃O-jarosite but, subsequently, goethite was the only mineral to form. Some of the trace elements, such as Al, Cu, Pb, and As were depleted in solution during the first stage as schwertmannite transformed into goethite plus H₃O-jarosite. On the contrary, the transformation of schwertmannite to goethite (with no jarosite) during the second stage released Al, Cu, and As to the solution. Despite the variation in their concentrations in solution, approximately 80% of the total Al and Cu inventories and more than 99% As and Pb remained in the solid phase throughout the entire aging process.  相似文献   

The Westerly Index as complementary indicator of the North Atlantic oscillation in explaining drought variability across Europe   总被引：1，自引：0，他引：1  

Sergio M. Vicente-Serrano  Ricardo García-Herrera  David Barriopedro  Cesar Azorin-Molina  Juan I. López-Moreno  Natalia Martín-Hernández  Miquel Tomás-Burguera  Luis Gimeno  Raquel Nieto 《Climate Dynamics》2016,47(3-4):845-863

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Analysis of swarms of high-frequency seismic events at Nevado del Ruiz volcano, Colombia (January 1986–August 1987): Development of a procedure     

Fernando C. Muoz  Alvaro E. Nieto  Hansjürgen Meyer 《Journal of Volcanology and Geothermal Research》1990,41(1-4)

The determination of signal properties like frequency, amplitude, “signature” of the sequence of arrivals of P- and S-phases and the subsequent computation of hypocenter parameters, are the steps of a procedure in the analysis of swarms of high-frequency seismic events from Nevado del Ruiz volcano, which could be useful in other volcanic areas. The use of this procedure on Ruiz data led to the determination of various seismic source volumes, which together with hypocenters of non-swarmed events and the identification of geological features such as faults which cross the area, alignment of domes and volcanic edifices, and the record of low-frequency seismic events not centered in the area of the active vent, suggest the existence of a magma chamber of a rather complex geometry. This hypothesis would suggest that magma, emplaced in zones of weakness (faults) that affect the area, may act as the source of seismic activity. This demands a revision of the methodology used in the deformation measurements, and in the analysis of released energy and event occurrence too. The relations between hypocenters (sources), location and relative energy of the swarms, as well as the general volcanic activity (tremor, ash and gas emission, deformation) could turn out to be a possible means to assist in the identification of premonitory activity and thus be relevant to the process of monitoring and forecasting.  相似文献   

Mercury in the Tinto-Odiel Estuarine System (Gulf of Cádiz, Spain): Sources and Dispersion   总被引：1，自引：0，他引：1  

D. Cossa  F. Elbaz-Poulichet  J. M. Nieto 《Aquatic Geochemistry》2001,7(1):1-12

The Tinto and Odiel are small rivers draining one of the largest sulphide deposits in the world. As a result of these deposits and a large industrial complex, the adjacent marine area receives a high amount of metal input. Mercury distribution in the Tinto-Odiel estuary, the Huelva Ría and the Gulf of Cádiz was assessed in water and suspended particulatematter (SPM) and sediments. In the rivers and estuaries, dissolved (HgD)and particulate (HgP) mercury showed wide variations (13 to 200 pM and0.3 to 330 nmol g^-1 respectively) depending on the presence or notof sulphidic waters, phosphogypsum deposits, detrital pyrite and oxyhydroxides.In the Ría, concentrations were lower than 10 pM and 4.5 nmol g^-1 for HgD and HgP respectively. In surface waters of the Gulf of Cádiz, the average HgD concentration (pm standard deviation) was 2.9 pm 0.9 pM, which is similar to that of North Atlantic Central Waters. The surface sediments collected in the rivers, the Ría and the Gulf showed systematically enriched mercury compared to pre-industrial levels. Vertical mercury profiles in dated sediment cores were typical of anthropogenically influenced environments starting in the early Roman age. These distribution features suggest that most of the Hg discharged by the Huelva Ría is trapped in the sediments of the Gulf of Cádiz.  相似文献   

Contents to Volume 7     

D. Cossa  F. Elbaz-Poulichet  J.M. Nieto 《Aquatic Geochemistry》2001,7(4):295-297

Volume Contents

Contents to Volume 7  相似文献   

Analysis of the precipitation and cloudiness associated with COLs occurrence in the Iberian Peninsula     

R. Nieto  L. Gimeno  J. A. Añel  L. De la Torre  D. Gallego  D. Barriopedro  M. Gallego  A. Gordillo  A. Redaño  G. Delgado 《Meteorology and Atmospheric Physics》2007,96(1-2):103-119

Summary The Iberian Peninsula is one of the regions in the world with higher occurrence of cut-off low systems (COL). The aim of this paper is to analyse the weather events (rainfall and cloudiness layer) associated to COLs in the Iberian Peninsula with tools not previously used: (a) the use of the new multidecadal COLs database developed by Nieto et al (2005) that permit us to study a 41 years period (1958–1998), (b) the checking of the expected weather events (rainfall and cloudiness layer) associated with COLs in a conceptual model (Winkler et al, 2005) and (c) the extensive use of radiosoundings to analyse convective instability in areas inside and close to the COL. Two points of view are used to make the analysis: (1) a source oriented method, when a particular COL is followed and its associated precipitation and cloudiness is analysed over four quadrants in which Iberia was divided and (2) a receptor oriented method, when the precipitation associated to COLs is analysed in given areas, defined by patterns of precipitation. Results reveal that the precipitation and cloudiness patterns associated to COLs in the conceptual model reproduce quite well the main characteristics found over the Iberian Peninsula. The generalized idea that most of the COLs produce intense convective rainfall is show to be misleading. Convective phenomena are important usually when the centre of the COL is located on the Mediterranean region. Most of the rainfall associated with COLs comes from the baroclinic shield; specially in cases located over the west half of the Iberian Peninsula. It is shown that nearly 30% of COLs do not induce any rainfall; most of them located in the southern half of the Peninsula, and mainly during autumn. Only 30% of COLs produce generalized rainfall over the whole analysed territory, being most of them (about 90%) located over the western half of the Iberian Peninsula.  相似文献   

Eratosthenes Seamount: collisional processes in the easternmost Mediterranean in relation to the Plio-Quaternary uplift of southern Cyprus     

A.H.F. Robertson  R.B. Kidd  M.K. Ivanov  A.F. Limonov  J. M. Woodside  J. Galindo-Zaldivar  L. Nieto 《地学学报》1995,7(2):254-264

Important new light is shed on subduction and incipient collisional processes in the Easternmost Mediterranean, notably the Plio-Quaternary uplift of the Troodos ophiolite, from new geophysical information collected during a cruise of the R.V. Gelendzhik in July 1993, as part of the Training-through-Research' programme. The data collected over the Eratosthenes Seamount formed part of the site-survey work for Leg 160 of the Ocean Drilling Program scheduled for spring 1995. The main results are that the Eratosthenes Seamount is in the process of actively subsiding, breaking-up and being thrust, beneath both Cyprus to the north and the Levantine Basin to the south. Northwards thrusting appears to post-date the Messinian, when evaporites accumulated around the lower flanks of a pre-existing seamount feature. Comparison with the geology of southern Cyprus and offshore areas suggests a causative link between northward underthrusting of the Eratosthenes Seamount and late Pliocene-mid Quaternary uplift of southern Cyprus, focused on the centre of the Troodos ophiolite.  相似文献   

Magnitude of lateral displacement on the Crevillente Fault Zone (Betic Cordillera,SE Spain): stratigraphical and sedimentological considerations     

L. M. Nieto  J. Rey 《Geological Journal》2004,39(1):95-110

The Crevillente Fault Zone (CFZ) comprises a system of northeast to southwest oriented dextral faults that extend for some 600 km in the External Zones of the Betic Cordillera (SE Spain). The magnitude of lateral displacement related to this fault zone is not well constrained, and it is considered to be between 20 and 400 km. The stratigraphical and sedimentological criteria used in this work have proven effective in quantifying the magnitude of the displacement along this structure. We have analysed an oolitic turbidite facies in the Middle Jurassic of the Sierra de Ricote (Median Subbetic of Murcia Province). A detailed revision of ooidal limestone outcrops has revealed that the source area of these deposits was to the Internal Subbetic zone, north of Vélez Rubio (Almería Province). These two tectonic units, the Median and Internal Subbetic, are currently 75 km from each other and separated by the CFZ. The conclusions arising from our stratigraphical, petrological and sedimentological studies favour interpretation of a 75–100 km lateral displacement. After restoring the Late Jurassic–Cretaceous anticlockwise rotation of Iberia, the CFZ appears to belong to the E–W palaeofault system that is related to the extension of the South Iberian Continental Margin (SICM). Copyright © 2004 John Wiley & Sons, Ltd.  相似文献