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The BanskáŠtiavnica ore district: relationship between metallogenetic processes and the geological evolution of a stratovolcano 总被引：1，自引：0，他引：1
The Banská?tiavnica ore district is in the central zone of the largest stratovolcano in the Central Slovakia Neogene Volcanic Field, which is situated at the inner side of the Carpathian arc over the Hercynian basement with the Late Paleozoic and Mesozoic sedimentary cover. Volcanic rocks of the High-K orogenic suite are of the Badenian through Pannonian age (16.5–8.5?Ma). Their petrogenesis is closely related to subduction of flysch belt oceanic basement underneath the advancing Carpathian arc and to back-arc extension processes. The stratovolcano includes a large caldera 20?km in diameter and a late-stage resurgent horst in its centre, exposing a basement and extensive subvolcanic intrusive complex. The following stages have been recognized in the evolution of the stratovolcano: (1)?formation of a large pyroxene/hornblende-pyroxene andesite stratovolcano; (2)?denudation, emplacement of a diorite intrusion; (3) emplacement of a large granodiorite bell-jar pluton within the basement; (4) emplacement of granodiorite/quartz-diorite porphyry stocks and dyke clusters around the pluton; (5) caldera subsidence and its filling by biotite-hornblende andesite volcanics, emplacement of quartz-diorite porphyry sills and dykes at the subvolcanic level; (6)?renewed activity of andesites from dispersed centres on slopes of the volcano; (7) uplift of a resurgent horst accompanied by rhyolite volcanics and granite porphyry dykes. The following types of ore deposits (mineralizations) have been identified in the Banská?tiavnica ore district: 1. Quartz-pyrophyllite-pyrite high-sulphidation system at ?obov, related to the diorite intrusion. 2. Magnetite skarn deposits and occurrences?at contacts of the granodiorite pluton with Mesozoic carbonate rocks. Magnetite ores occur as lenses in the calcic skarns. 3.?Stockwork/disseminated base metal deposit along an irregular network of fractures in apical parts of the granodiorite pluton and in remnants of basement rocks. Mineral paragenesis is simple, with leading sphalerite and galena and minor chalcopyrite and pyrite. In overlying andesites the mineralization is accompanied by metasomatic quartzites and argillites with pyrophyllite, kaolinite, illite and pyrite. 4. Porphyry/skarn copper deposits and occurrences related to granodiorite/quartz-diorite porphyry dyke clusters and stocks around the granodiorite intrusion. The mineralized zone is represented by accumulations of chalcopyrite in exo- and endo-skarns, usually of the magnesian type affected by serpentinization. Besides chalcopyrite, pyrhotite, minor bornite, chalcosite, tennantite and magnetite, rare molybdenite and gold are present. The alteration pattern around productive intrusions includes an external zone of propylitization, a zone of argillitic alteration (kaolinite – illite – pyrite) and an internal zone of phyllic alteration (quartz – sericite – pyrite). Biotitization is rare and limited to porphyry intrusions. 5. Intrusion related “mesothermal” gold deposit in an andesitic environment just above the granodiorite intrusion. Gold of high fineness with base metal mineralization is contained in brecciated and/or banded quartz veins of subhorizontal orientation, parallel to the surface of granodiorite pluton. At least the first phase of mineralization is older than quartz-diorite porphyry sills, which separate granodiorite and blocks of mineralized andesite. 6. Hot spring type advanced argillic systems in the caldera filling. Silicites and opalites accompanied by kaolinite, alunite and pyrite grade downward into smectite dominated argillites. 7. Vein type epithermal precious/base metal deposits and occurrences as a result of the long lasting interaction among structural evolution of the resurgent horst and evolving hydrothermal system, extensive intrusive complex and deep seated siliceous magma chamber serving as heat and magmatic fluid source. Three types of epithermal veins occur in a zonal arrangement: (a) base metal veins ± Au with transition to Cu?±?Bi mineralization at depth in the east/central part of the horst, (b)?Ag – Au veins with minor base metal mineralization and (c) Au – Ag veins located at marginal faults of the horst. Isotopic composition of oxygen and hydrogen in hydrothermal fluids indicate mixing of magmatic and meteoric component (with generally increasing proportion of meteoric component towards younger mineralization periods?). Veins are accompanied by zones of silicification, adularization and sericitization, indicating a low sulphidation environment. 8.?Replacement base metal mineralization of a limited extent in the Mesozoic carbonate rocks next to sulphide rich epithermal base metal veins. 相似文献
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Kamil Vrana Stanislav Rapant Dušan Bodiš Karol Marsina Blanka Maňkovská Ján ?urlík Peter Šef?ík Jozef Daniel Ladislav Lu?ivjanský Jaroslav Lexa Silvester Pramuka 《Journal of Geochemical Exploration》1997,60(1):7-37
The Geochemical Atlas of Slovak Republic (49,036 km2) at a scale of 1 : 1,000,000 was compiled during 1991–1995 together with maps of associated geochemical and ecological features at a scale of 1 :200,000. Investigations were aimed at the evaluation of concentrations and distributions of Al, As, Ba, Be, Ca, Ce, Co, Cd, Cs, Cr, Cu, Fe, Ga, Hg, K, La, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Rb, Sb, Se, Sn, Sr, Th, U, V, W, Y, Zn, Zr in groundwater (16,359 samples), stream sediments (24,422 samples), rocks (3839 samples), soils (9892 samples from 4946 profiles; A and C horizons of each profile were sampled) and forest biomass (the foliage of the forest tree species from 3063 plots was sampled). In groundwater field measurements of temperature, pH, conductivity, dissolved O2, acidity, alkalinity were done. The evaluation was oriented to the natural radioactivity of the Slovak territory as follows: rocks (K, U, Th, Utot and dose rate, 15,573 reference spectrometric points), radon risk and water (Unat, 226Ra, 222Rn; 5271 samples). The main objective of the Geochemical Atlas was to construct single-component maps showing concentrations of chemical elements, compounds and measured parameters in the researched media of Slovakia at a scale of 1 : 1,000.000 and to create interactive databases of chemical composition and/or measured parameters of groundwater, biomass, rocks, soils, stream sediments and natural radioactivity, for the entire territory of the Slovak Republic. The single-component maps are not constructed in the part ‘Rocks’, where all the main rocks types of Slovakia are presented in the ‘Map of lithogeochemical rock types of Slovakia at a scale of 1: 500,000’. The edition of six atlases has been planned. In 1997 the first three atlases will appear (Groundwater, Biomass, Natural Radioactivity). Publishing of last three atlases (Rocks, Soils, Stream Sediments) is planned for 1998. Since the analytical works on stream sediments were finished during 1997, it was not possible to present here the results of that part of the Geochemical Atlas. 相似文献
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Ondrej Ledvinka Anna Lamacova 《Stochastic Environmental Research and Risk Assessment (SERRA)》2015,29(5):1463-1484
Trend analysis is a frequently used tool in hydrology and climatology for the identification of long-term changes. However, studies are usually only oriented on local trends. This paper rather focuses on the spatial application of trend analysis in groundwater data. For this purpose, a modification of the Mann-Kendall test was developed, based on the trend-free pre-whitening approach. This method was successfully tested on 157 series of yields from headwater springs collected in Czechia during the 1971–2007 period. The analysis was done separately for year, each season and each month. Field significant trends in spring yields were identified in hydrogeological regions. The results showed that the field significant trends are outnumbered when cross-correlation is not taken into account. In the case of annual series, 4 of 18 hydrogeological regions investigated showed a significant decreasing trend after corrections for cross-correlation, compared to 12 regions with field significant trend when not considering cross-correlation. 相似文献
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Metamorphic inheritance of Rheic passive margin evolution and its early‐Variscan overprint in the Teplá‐Barrandian Unit,Bohemian Massif 
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下载免费PDF全文 V. Peřestý O. Lexa R. Holder P. Jeřábek M. Racek P. Štípská K. Schulmann B. Hacker 《Journal of Metamorphic Geology》2017,35(3):327-355
Rift‐related regional metamorphism of passive margins is usually difficult to observe on the surface, mainly due to its strong metamorphic overprint during the subsequent orogenic processes that cause its exposure. However, recognition of such a pre‐orogenic evolution is achievable by careful characterization of the polyphase tectono‐metamorphic record of the orogenic upper plate. A multidisciplinary approach, involving metamorphic petrology, P–T modelling, structural geology and in situ U‐Pb monazite geochronology using laser‐ablation split‐stream inductively coupled plasma mass spectrometry, was applied to unravel the polyphase tectono‐metamorphic record of metapelites at the western margin of the Teplá‐Barrandian domain in the Bohemian Massif. The study resulted in discovery of three tectono‐metamorphic events. The oldest event M1 is LP–HT regional metamorphism with a geothermal gradient between 30 and 50 °C km?1, peak temperatures up to 650 °C and of Cambro‐Ordovician age (c. 485 Ma). The M1 event was followed by M2‐D2, which is characterized by a Barrovian sequence of minerals from biotite to kyanite and a geothermal gradient of 20–25 °C km?1. D2‐M2 is associated with a vertical fabric S2 and was dated as Devonian (c. 375 Ma). Finally, the vertical fabric S2 was overprinted by a D3‐M3 event that formed sillimanite to chlorite bearing gently inclined fabric S3 also of Devonian age. The high geothermal gradient of the M1 event can be explained as the result of an extensional, rift‐related tectonic setting. In addition, restoration of the deep architecture and polarity of the extended domain before the Devonian history – together with the supracrustal sedimentary and magmatic record – lead us to propose a model for formation of an Ordovician passive continental margin. The subsequent Devonian evolution is interpreted as horizontal shortening of the passive margin at the beginning of Variscan convergence, followed by detachment‐accommodated exhumation of lower‐crustal rocks. Both Devonian shortening and detachment occurred in the upper plate of a Devonian subduction zone. The tectonic evolution presented in this article modifies previous models of the tectonic history of the western margin of the Teplá‐Barrandian domain, and also put constraints on the evolution of the southern margin of the Rheic ocean from the passive margin formation to the early phases of Variscan orogeny. 相似文献
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Alexandre V. Andronikov Martin Novak Pavel Kram Ondrej Sebek Irina E. Andronikova Marketa Stepanova Hyacinta Vitkova Elena Antalova Arnost Komarek 《水文研究》2021,35(12):e14434
One pre-requisite for the construction of a global chromium isotope mass balance is detailed understanding of Cr isotope systematics in the critical zone where redox-processes can modify the isotope signature of geogenic Cr input into the hydrosphere. A Cr isotope inventory of bedrock, soil, and runoff was performed in a Central European headwater catchment underlain by amphibolite, situated in the vicinity of two previously studied catchments underlain by different bedrock types (serpentinite and leucogranite). Fresh bedrock in the amphibolite catchment NAZ contained ~300 mg/kg Cr, serpentinite at PLB contained ~800 mg/kg Cr, and leucogranite at LYS contained ~2 mg/kg Cr. Monthly hydrochemical monitoring at all three sites revealed higher Cr(VI) export fluxes in winter than in summer. NAZ was characterized by a distinct seasonality in the δ53Cr values, with minima during winter/spring snowmelts (−0.35‰) and maxima during dry summers (0.40‰). Similar seasonality in δ53Cr values had been reported from PLB and LYS. Bedrock at all three sites had similar Cr isotope composition close to −0.10‰, a value indistinguishable from the δ53Cr value of bulk silicate Earth (BSE). Positive mean δ53Cr value of NAZ runoff indicated Cr-isotope fractionations during weathering of geogenic Cr(III), combined with adsorption of the resulting Cr(VI) on soil particles during pedogenesis. However, the mass-weighted mean δ53Cr of NAZ runoff was lower (−0.08‰), indistinguishable from the Cr isotope signature of bedrock. The same pattern of lower mass-weighted mean δ53Cr values of runoff, compared to arithmetic mean δ53Cr values of runoff, were observed also at PLB and LYS. We suggest that elevated Cr runoff fluxes in winter remove some of the residual isotopically light Cr that accumulated in the soil during summer. Seasonality in runoff δ53Cr values appears to be a relatively widespread phenomenon, de-coupled from Cr availability for chemical weathering. 相似文献
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Understanding the role of forests on snowmelt processes enables better estimates of snow storages at a catchment scale and contributes to a higher accuracy of spring flood forecasting. A coniferous forest modifies the snowpack energy balance by reducing the total amount of solar shortwave radiation (SWR) and enhancing the role of longwave radiation (LWR) emitted by trees. This study focuses on changes in SWR and LWR at three sites with different canopy structure (Bohemian Forest, Czechia), including one site affected by the bark beetle (Ips typographus). Measurements of incoming and outgoing SWR and LWR were performed at all sites equipped with CNR4 Net Radiometers for three cold seasons. In addition to SWR and LWR, sensible and latent heat, and ground heat and energy supplied by liquid precipitation were calculated. The results showed that net SWR at the healthy forest site represented only 7% of the amount at the open site due to the shading effect of trees. In contrast, net LWR represented a positive component of the snowpack energy balance at the healthy forest site and thus contributed the most to snowmelt. However, the modelled snowmelt rates were significantly lower in the forest than in the open area since the higher LWR in the forest did not compensated for the lower SWR. The progressive decay of disturbed forest caused the decrease in mean net LWR from −3.1 W/m2 to −12.9 W/m2 and the increase in mean net SWR from 31.6 W/m2 to 96.2 W/m2 during the study period. These changes caused an increase in modelled snowmelt rates by 50% in the disturbed forest, compared to the healthy forest site, during the study period. Our findings have important implications for runoff from areas affected by land cover changes due to either human activity or climate change. 相似文献
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Norma Tombesi Karla Pozo Andrés Arias Mónica Alvarez Petra Pribylova Ondrej Audy Jana Klánová 《Environmental Earth Sciences》2018,77(11):403
The present study fills a gap in the knowledge in regards to the occurrence of banned pesticides at both coastal and inland locations at the Southwest Buenos Aires region, Argentina. Superficial sediment and soil samples were collected from different sites along the Bahia Blanca Estuary and surrounding sites to assess the concentration levels and spatial distribution of 12 selected organochlorine pesticides (OCs); 13 spatial locations including inland and shore-coast were sampled to evaluate occurrence and concentration levels of hexachlorocyclohexanes α-HCH, β-HCH, δ-HCH, γ-HCH, dichlorodiphenyltrichloroethane and its degradation products (DDXs: p,p′-DDT, o,p′-DDT, p,p′-DDE, o,p′-DDE, p,p′-DDD, o,p′-DDD) and the polychlorobenzenes PeCB (pentachlorobenzene) and HCB (hexachlorobenzene). After cleaning and extractions steps, samples were analyzed by means of gas chromatography/mass spectrometry. ∑OCs (sum of all studied compounds) ranged between 0.206 and 1040 ng g?1 dw (mean?=?82.4 and SD?=?277 ng g?1 dw). Total HCHs (sum of α-HCH, β-HCH, γ-HCH and δ-HCH) ranged from 0.0858 to 0.876 ng g?1 dw (mean?=?0.43 and SD?=?0.23 ng g?1 dw), DDXs (sum of p,p′and o,p′ isomers) from 0.080 to 1040 ng g?1 dw (mean?=?81.3 and SD?=?277 ng g?1 dw). Lower concentrations were found for PeCB (mean?=?0.095 and SD 0.17 ng g?1 dw) and HCB (mean?=?0.56 and SD 1.7 ng g?1 dw). Principal component analysis (PCA) permitted the extraction of underlying information about common factors, providing an overview of the distribution of pesticides and allowing the characterization of sites in regards to the major pesticide signature. 相似文献
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V. Hurai J.-L. Paquette O. Lexa P. Konečný I. Dianiška 《Mineralogy and Petrology》2015,109(5):519-530
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P–T–t–D record of crustal‐scale horizontal flow and magma‐assisted doming in the SW Mongolian Altai 下载免费PDF全文
下载免费PDF全文 A. Broussolle P. Štípská J. Lehmann K. Schulmann B. R. Hacker R. Holder A. R. C. Kylander‐Clark P. Hanžl M. Racek P. Hasalová O. Lexa K. Hrdličková D. Buriánek 《Journal of Metamorphic Geology》2015,33(4):359-383
The Chandman massif, a typical structure of the Mongolian Altai, consists of a migmatite–magmatite core rimmed by a lower grade metamorphic envelope of andalusite and cordierite‐bearing schists. The oldest structure in the migmatite–magmatite core is a subhorizontal migmatitic foliation S1 parallel to rare granitoid sills. This fabric is folded by upright folds F2 and transposed into a vertical migmatitic foliation S2 that is syn‐tectonic, with up to several tens of metres thick granitoid sills. Sillimanite–ilmenite–magnetite S1 inclusion trails in garnet constrain the depth of equilibration during the S1 fabric to 6–7 kbar at 710–780 °C. Reorientation of sillimanite into the S2 fabric indicates that the S1–S2 fabric transition occurred in the sillimanite stability field. The presence of cordierite, and garnet rim chemistry point to decompression to 3–4 kbar and 680–750 °C during development of the S2 steep fabric, and post‐tectonic andalusite indicates further decompression to 2–3 kbar and 600–650 °C. Widespread crystallization of post‐tectonic muscovite is explained by the release of H2O from crystallizing partial melt. In the metamorphic envelope the subhorizontal metamorphic schistosity S1 is heterogeneously affected by upright F2 folds and axial planar subvertical cleavage S2. In the north, the inclusion trails in garnet are parallel to the S1 foliation, and the garnet zoning indicates nearly isobaric heating from 2.5 to 3 kbar and 500–530 °C. Cordierite contains crenulated S1 inclusion trails and has pressure shadows related to the formation of the S2 fabric. The switch from the S1 to the S2 foliation occurred near 2.5–3 kbar and 530–570 °C; replacement of cordierite by fine‐grained muscovite and chlorite indicates further retrogression and cooling. In the south, andalusite containing crenulated inclusion trails of ilmenite and magnetite indicates heating during the D2 deformation at 3–4 kbar and 540–620 °C. Monazite from a migmatite analysed by LASS yielded elevated HREE concentrations. The grain with the best‐developed oscillatory zoning is 356 ± 1.0 [±7] Ma (207Pb‐corrected 238U/206Pb), considered to date the crystallization from melt in the cordierite stability ~680 °C and 3.5 kbar, whereas the patchy BSE‐dark domains give a date of 347 ± 4.2 [±7] Ma interpreted as recrystallization at subsolidus conditions. The earliest sub‐horizontal fabric is associated with the onset of magmatism and peak of P–T conditions in the deep crust, indicating important heat input associated with lower crustal horizontal flow. The paroxysmal metamorphic conditions are connected with collapse of the metamorphic structure, an extrusion of the hot lower crustal rocks associated with vertical magma transfer and a juxtaposition of the hot magmatite–migmatite core with supracrustal rocks. This study provides information about tectono‐thermal history and time‐scales of horizontal flow and vertical mass and heat transfer in the Altai orogen. It is shown that, similar to collisional orogens, doming of partially molten rocks assisted by syn‐orogenic magmatism can be responsible for the exhumation of orogenic lower crust in accretionary orogenic systems. 相似文献