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1.
火山活动与海侵影响下的典型湖相页岩有机质保存差异分析 总被引：1，自引：0，他引：1
黑色富有机质页岩是页岩油气生成和赋存的主要母体,是强还原环境水体的沉积产物,在其形成过程中,细菌硫酸盐还原作用(BSR)对水体环境影响明显,但BSR强度如何影响有机质的保存尚未得到关注。我国陆相湖盆富有机质泥页岩广泛发育,形成过程中常常伴随有火山活动或者海侵等事件,大量硫酸盐进入湖盆,改变水体的沉积环境,不同环境下BSR对黑色页岩有机质保存的影响明显不同。本次研究选取鄂尔多斯盆地延长组长7段页岩、松辽盆地青山口组和嫩江组页岩作为对象,同时与现代沉积物进行对比。研究表明,TOC与TS之间关系复杂,但细菌硫酸盐还原强度指数(SRI)与TOC呈现幂指数变化,且表现出两阶段变化的特征。当SRI大于1.375时,TOC整体偏低,指示了强硫酸盐还原作用消耗大量有机质;当SRI小于1.375时,TOC明显较高,指示了弱硫酸盐还原作用对有机质消耗相对较少,更有利于有机质保存。火山活动和海侵作用均向水体提供了大量硫酸盐,但对陆相湖盆页岩中有机质的保存影响不同。火山活动影响的长7段页岩SRI普遍小于1.375,BSR对有机质消耗相对弱,页岩TOC高。而受海侵影响的青山口组一段底部和嫩江组一段底部页岩SRI大于1.375,BSR过度消耗了大量有机质,使得页岩TOC偏低。嫩江组一段下部SRI指数更高,海侵强度更大,BSR反应更强,更不利于有机质保存。 相似文献
2.
MENG Qingqiang PANG Qian HU Guang JIN Zhijun ZHU Dongy LIU Jiayi ZHANG Chuanwen 《《地质学报》英文版》2022,96(4):1342-1352
Heat carried by deep fluid might greatly affect hydrocarbon generation and pore space in shale. Dyke intrusion carrying high levels of heat may be a means by which to explore the influence of deep fluid on shale reservoirs. This study evaluates hydrocarbon generation and analyzed the evolution of shale storage space in the third member of the Xiamaling Formation in the Zhaojiashan section, Hebei Province, based on experimental data such as TOC, SEM, VRo, low-temperature N2 adsorption and high-pressure mercury injection. The results show that the dyke intrusion reduced the shale TOC content drastically―by up to 77%―and also induced instantaneous hydrocarbon generation over a range about 1.4 times the thickness of the intrusion. Furthermore, the dyke intrusion might transform organic pores in surrounding shales into inorganic pores. There were two shale porosity peaks: one appeared when VRo = 2.0%, caused by the increase of organic pores as thermal maturity increased, the other occurred when the VRo value was between 3% and 4%, caused by the increase of inorganic mineral pores. It can be concluded that dyke intrusion can be an effective tool with which to study how deep fluid affects instantaneous hydrocarbon generation and pore space in shale. 相似文献
3.
Peng Weilong Liu Quanyou Zhang Ying Jia Huichong Zhu Dongya Meng Qingqiang Wu Xiaoqi Deng Shang Ma Yongsheng 《中国科学:地球科学(英文版)》2022,65(5):874-881
Science China Earth Sciences - Helium gas is a scarce but important strategic resource, which is usually associated with natural gas. Presently, only one extra-large helium-rich gas field has been... 相似文献
4.
青藏高原主要生态系统净初级生产力的估算 总被引：37，自引：2，他引：35
利用青藏高原贡嘎山、海北、五道梁、拉萨等4个野外台站2000~2002年的观测数据、陆地生态系统模型与2001年MODIS遥感数据相结合的方法来估算青藏高原区域的净初级生产力。结果表明:青藏高原区域的净初级生产力空间分布趋势表现出由东南向西北逐渐递减的梯度,该趋势也与水热梯度表现基本一致;整个青藏高原的净初级生产力为302.44×1012 gC yr-1,其中森林的净初级生产力最高,120.11×1012 gC yr-1,占整个高原净初级生产力的39.7%;全年中夏季(6~8月) 的净初级生产力最高,246.7×1012 gC yr-1,约占全年总净初级生产力的80%。用实测数据验证模拟结果表明,二者非常相符。 相似文献
5.
Late Quaternary palaeosols in the Yangtze Delta, China, and their palaeoenvironmental implications 总被引：1，自引：0，他引：1
The stiff clays beneath Holocene strata in the Yangtze Delta are interpreted as palaeosols, based on pedogenic features including illuvial argillans, voids, cracks, iron–manganese concretions and nodules, and carbonate materials. Variations in clay content with depth, the occurrence of foraminifera, and the environmental magnetism characteristics of the palaeosols suggest that their parent materials are floodplain deposits. Anisotropy of magnetic susceptibility (AMS) parameters of the sediments correlate well both with sedimentary dynamics and depositional processes in different sedimentary environments, and AMS analysis may be a useful tool for inferring sedimentary environments. Based on their considerable thickness (> 3.0 m), vertical changes of palaeosol maturity, and occurrence of ageing argillans throughout the palaeosols, the palaeosols are inferred to be compound ones (pedocomplexes) resulting from alternating deposition and pedogenesis on the palaeointerfluve of the Yangtze River. Phytoliths in the palaeosols indicate that climates turned generally from warm and wet to cold and dry with marked fluctuations during development of the palaeosols. This suggests that the palaeosols developed mainly during the marine regression prior to the last glacial maximum. The vertical distribution of manganese materials (e.g., concretions, nodules, speckles and mottles) in the palaeosols suggests that the groundwater tables were about 2.0–3.0 m beneath the upper boundary of the palaeosols during their development. Yellow–brown streaks and speckles are abundant from the middle to lower parts of the palaeosols, and layers with high CaCO3 content occur in the strata just beneath the palaeosols, but which lack caliche, suggesting that the groundwater table fluctuated markedly during their development. Voids and cracks filled with clays, and carbonate nodules (less than 0.1 mm in diameter) with thin iron–manganese rims are abundant in the palaeosols, indicating that wet and dry seasons were marked during the palaeosol development. It is suggested that the monsoonal influence was marked in the Yangtze Delta, with both winter and summer monsoons strongly developed during the development of the late Quaternary palaeosols. 相似文献
6.
Deep fluids in a petroliferous basin generally come from the deep crust or mantle beneath the basin basement, and they transport deep substances(gases and aqueous solutions) as well as heat to sedimentary strata through deep faults. These deep fluids not only lead to large-scale accumulations of CO_2, CH_4, H_2, He and other gases, but also significantly impact hydrocarbon generation and accumulation through organic-inorganic interactions. With the development of deep faults and magmatic-volcanic activities in different periods, most Chinese petroliferous basins have experienced strong impacts associated with deep fluid activity. In the Songliao, Bohai Bay, Northern Jiangsu, Sanshui, Yinggehai and Pearl Mouth Basins in China, a series of CO_2 reservoirs have been discovered. The CO_2 content is up to 99%, with δ~(13)C_(CO2) values ranging from-4.1‰ to-0.37‰ and ~3He/~4He ratios of up to 5.5 Ra. The abiogenic hydrocarbon gas reservoirs with commercial reserves, such as the Changde, Wanjinta, Zhaozhou, and Chaoyanggou reservoirs, are mainly distributed in the Xujiaweizi faulted depression of the Songliao Basin. The δ~(13)CCH4 values of the abiogenic alkane gases are generally -30‰ and exhibit an inverse carbon isotope sequence of δ~(13)C_(CH4)δ~(13)C_(C2H6)δ~(13)C_(C3H8)δ~(13)C_(C4H10). According to laboratory experiments, introducing external H_2 can improve the rate of hydrocarbon generation by up to 147% through the kerogen hydrogenation process. During the migration from deep to shallow depth, CO_2 can significantly alter reservoir rocks. In clastic reservoirs, feldspar is easily altered by CO_2-rich fluids, leading to the formation of dawsonite, a typical mineral in high CO_2 partial pressure environments, as well as the creation of secondary porosity. In carbonate reservoirs, CO_2-rich fluids predominately cause dissolution or precipitation of carbonate minerals. The minerals, e.g., calcite and dolomite, show some typical features, such as higher homogenization temperatures than the burial temperature, relatively high concentrations of Fe and Mn, positive Eu anomalies, depletion of 18 O and enrichment of radiogenic ~(87)Sr. Due to CO_2-rich fluids, the development of high-quality carbonate reservoirs is extended to deep strata. For example, the Well TS1 in the northern Tarim Basin revealed a high-quality Cambrian dolomite reservoir with a porosity of 9.1% at 8408 m, and the Well ZS1 C in the central Tarim Basin revealed a large petroleum reserve in a Cambrian dolomite reservoir at ~6900 m. During the upward migration from deep to shallow basin strata, large volumes of supercritical CO_2 may extract petroleum components from hydrocarbon source rocks or deep reservoirs and facilitate their migration to shallow reservoirs, where the petroleum accumulates with the CO_2. Many reservoirs containing both supercritical CO_2 and petroleum have been discovered in the Songliao, Bohaiwan, Northern Jiangsu, Pearl River Mouth and Yinggehai Basins. The components of the petroleum trapped with CO_2 are dominated by low molecular weight saturated hydrocarbons. 相似文献
7.
在遥感解译、野外调查的基础上,采用高密度电法和电阻率测深法,并结合钻探对川西岷江河谷发育的尕米寺滑坡、俄寨村滑坡、格机寨滑坡等典型大型—巨型古滑坡的空间结构进行了勘探分析,有效确定了古滑坡的空间结构和滑带特征,并认为古滑坡的滑动面多具有高低阻相间的不稳定电性层,且滑坡前缘多位于不稳定电性层变薄收敛的地方。其中,俄寨村滑坡高低阻相间的不稳定电性层厚约0~45 m,为滑坡堆积层,古滑动面紧贴基岩面,滑动面平均埋深约30 m,弱风化基岩面埋深约5.6~61 m,强风化层厚约为3~12 m;尕米寺滑坡高低阻相间的不稳定电性层厚约2.5~43 m,为滑坡堆积层,沿剖面古滑动面平均埋深约35 m,在滑坡中部存在一圈闭的低阻异常体,推测为古河道,并与钻探结果相吻合,其埋深约56~96 m,弱风化基岩面埋深13.3~100 m,强风化及岩溶综合层厚一般约为5~20 m。基于古滑坡的地球物理勘探数据和解译结果,统计分析了川西岷江河谷地区大型—巨型古滑坡空间岩土体的地球物理物性参数,对指导该区滑坡调查分析具有重要的指导意义。 相似文献
8.
塔里木盆地深层寒武系地表岩溶型白云岩储层及后期流体改造作用 总被引：3，自引：0，他引：3
对塔里木盆地钻遇寒武系白云岩的塔深1等井的岩芯观察发现埋深超过8000m的深层寒武系白云岩中仍发育有丰富的几毫米至几厘米大小的地表岩溶作用形成的溶蚀孔洞。塔深1井测井曲线的突变反映出了多个寒武系沉积间断(暴露)面的存在;但塔深1井附近寒武系地震剖面同相轴连续性较好,没有明显的角度不整合接触。测井和地震特征表明了寒武系白云岩岩溶作用发生在同生或准同生期,是由于相对海平面下降造成的暴露作用,而没有发生强烈的构造抬升。塔深1等井寒武系白云岩溶蚀孔洞中常见有白云石、石英等矿物的充填。充填白云石具有弯曲晶面和波状消光的特征。白云石中流体包裹体均一温度主峰区间110～130℃,没有随深度增加而增加的特点。与基质白云岩相比,充填白云石具有相对较低的Na、K和Sr的含量以及相对较高的Fe、Mn和Ba含量。在同位素组成上,充填白云石具有相对较轻的氧同位素组成和较高的n(87Sr)/n(86Sr)比值;其氧同位素δ18OPDB的变化范围为-11.62‰～-5.13‰,平均为-8.00‰,锶同位素n(87Sr)/n(86Sr)比值变化范围为0.709361～0.709978,平均为0.709590。上述特征表明了白云石等的充填作用与深部热液活动有关。受深部热液作用强度的限制,寒武系白云岩中已有的岩溶型孔隙并没有被完全充填破坏,仍有较多的储集空间得以保存下来。 相似文献
9.
HU Guang MENG Qingqiang WANG Jie Tengger XIE Xiaomin LU Longfei LUO Houyong LIU Wenhui 《《地质学报》英文版》2022,96(6):2158-2158
The above article from Acta Geologica Sinica (English Edition), published online on 27 December 2018 in Wiley Online Library (wileyonlinelibrary.com) and in Volume 92, Issue 6, pp. 2297–2309, has been retracted by agreement between the authors, the journal Editor in Chief, Professor Zengqian Hou and John Wiley & Sons Ltd. The retraction has been agreed due to major overlap with a previously published article from the same group of authors published in Chinese. 相似文献
10.
XU Huiyuan LIU Quanyou JIN Zhijun ZHU Dongy MENG Qingqiang LI Pengpeng ZHU Biqing 《《地质学报》英文版》2023,97(1):327-336
Continental epithermal ore deposits are commonly associated with sedimentary organic matter, oils or solid bitumen. These organics embedded in mineral deposits can convey valuable information of the ore genesis. However, the extent to which the formation of ore minerals was recorded by organic compounds remains largely unknown, as also is how metal-rich ores interfere with the molecular proxies in the temperature regime envisaged for hydrothermal activity. The molecular compositional changes of ... 相似文献