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Rachelle B. Turnier Yaron Katzir Kouki Kitajima Ian J. Orland Michael J. Spicuzza John W. Valley 《Journal of Metamorphic Geology》2020,38(1):53-70
Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ18O) measured at mm-scale and the uncertain calibration of Δ18O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ18O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 106/T2 (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ18O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ18O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas. 相似文献
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Lake St Lucia in South Africa is part of a UNESCO World Heritage site and a Ramsar wetland of international importance. Like many coastal wetlands worldwide, anthropogenic activities including catchment land-use changes, water diversions/abstractions, and manipulation of the mouth state have significantly affected its functioning over the past century. Questions concerning its sustainability have motivated a re-evaluation of management decisions made in the past and of options for the future. A model for the water and salt budgets has therefore been used to investigate “what if” scenarios in terms of past anthropogenic interventions. In particular, simulations allow us to evaluate the effects of diverting the Mfolozi river from St Lucia on the functioning of the system and on the occurrence of various water level/salinity states that drive the biological functioning of the ecosystem. In the past, when the St Lucia estuary and the Mfolozi river had a combined inlet, the mouth was predominantly open. The lake had relatively stable water levels but variable salinities that increased during dry conditions due to evaporative losses and saltwater inflows from the sea. If the mouth closed, the Mfolozi flow was diverted into the lake which reduced salinities and maintained or increased water levels. Simulations indicate that without a link to the Mfolozi the lake system would naturally have a mainly closed inlet with lower average salinities but more variable water levels. During dry conditions water levels would reduce and result in desiccation of large areas of the lake as has recently occurred. We conclude that the artificial separation of the St Lucia and Mfolozi inlets underpins the most significant impacts on the water & salt budget of the lake and that its reversal is key to the sustainability of the system. 相似文献
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Wastewater discharges affect the functioning of small temporarily open/closed estuaries (TOCEs) through two main mechanisms: (1) they can significantly change the water balance by altering the quantity of water inflows, and (2) they can significantly change the nutrient balance and hence the water quality. This study investigated the bio-physical responses of a typical, small TOCE on the east coast of South Africa, the Mhlanga Estuary. This estuary receives significant inflows of treated effluent from upstream wastewater treatment works. Water and nutrient budgets were used together with biological sampling to investigate changes in the functioning of the system. The increase in inflows due to the effluent discharges has significantly increased the mouth breaching frequency. Furthermore, when the mouth closes, the accumulation of nutrients leads to eutrophication and algal blooms. A grey water index, namely the proportion of effluent in the estuary and an indicator of the additional nutrient inputs into the estuary, reached high values (?50%) during low flow regimes and when the mouth was closed. In these hyper-eutrophic conditions (DIN and DIP concentrations up to 457 μM and 100 μM respectively), field measurements showed that algal blooms occurred within about 14 days following closure of the mouth (chlorophyll-a concentrations up to 375 mg chl-a m−3). Water and nutrient balance simulations for alternative scenarios suggest that further increases in wastewater discharges would result in more frequent breaching events and longer open mouth conditions, but the occurrence of hyper-eutrophic conditions would initially intensify despite more frequent openings. The study indicates how water and nutrient balance simulations can be used in the planning and impact assessment of wastewater treatment facilities. 相似文献
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Neil C. Mitchell Rachelle Stretch Clive Oppenheimer Daniel Kay Christoph Beier 《Bulletin of Volcanology》2012,74(10):2289-2301
Eruptions in shallow water typically produce cones of volcaniclastic material. In order to identify any systematic effects of water depth and other environmental parameters on cone morphology, we have measured the heights and widths of cones in multibeam echo-sounder data from a submarine ridge extending southeast from Pico Island, Azores. XRF analyses of dredged samples show that lavas here vary compositionally from alkali basalt to trachybasalt and trachyandesite. Cones in deeper water are generally steep-sided with upper flanks close to 30°, the dip of talus at the angle of repose. However, height/width ratios of cones vary more in shallow water (200?C400-m summit depth) with extreme values below 0.1; while some shallow-water cones are steep-sided as in deep water, others are much flatter. Three such cones lie on a bench at 300-m depth immediately east of Pico Island and have flank slopes of only 10?C20°. We speculate that exceptionally shallow cone slopes here were produced by forced spreading of the erupting columns on reaching the water?Cair density barrier. 相似文献
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Alexandria B. Boehm Kevan M. Yamahara Sarah P. Walters Blythe A. Layton Daniel P. Keymer Rachelle S. Thompson Karen L. Knee Matt Rosener 《Estuaries and Coasts》2011,34(5):925-936
This study quantifies dissolved inorganic nitrogen (DIN), soluble reactive phosphorous (SRP), and microbial pollutant inputs
to a tropical embayment, Hanalei Bay, Kaua'i, Hawai'i from rural watersheds during two field excursions during non-storm conditions.
We employ land cover analysis and a suite of nucleic acid fecal source tracking markers (host-specific Bacteroidales and human enterovirus) to identify sources of pollutants to the bay. The highest concentrations of DIN and SRP are in streams
draining watersheds with large areas of cultivated land, suggesting fertilizer is a source of these nutrients to the streams
and coastal waters. Pollutant areal loading correlates with the fractions of urban and cultivated land cover. Microbial source
tracking indicates the presence of human, pig, and ruminant feces in the streams. This work provides preliminary evidence
that human development affects loading of DIN, SRP, and microbial pollutants to tropical coastal waters; further study is
needed to confirm this. Additionally, results point to a mix of microbial pollutant sources. 相似文献
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A. McR. Holm I.W. Watson E.J. Speijers R.J. Allen G.J. Eliot K.R. Shackleton J.K. Stretch 《Journal of Arid Environments》2005,61(4):631-649
General models of degradation suggest soil and nutrients are lost and conversion of rainfall into primary productivity is diminished when rangeland is degraded. These models are supported by studies on non-resilient landscapes, where loss of primary productivity also translated into loss of secondary productivity, but have not been tested on resilient landscapes. Elsewhere we showed that loss of chenopod shrubs from a landscape characterized as resilient was associated with declines in plant productivity and efficiency of conversion of rainfall into plant mass. To explore whether these differences in primary productivity translated into differences in secondary productivity, we grazed sheep at five rates of stocking for 10 years on 2000 ha of this landscape. The experiment was necessarily replicated in time not space (i.e. pseudo-replicated), which limits confident extrapolation of results to other landscapes.Productivity of sheep at all except highest rates of stocking varied little between sites where shrubs were abundant or scarce. From an animal production point of view, greater rates of stocking were unsustainable through dry years on the degraded site, but animal performance was generally unaffected on the non-degraded site, where shrubs were abundant. While these results provide evidence of economic penalties associated with degrading a resilient landscape, important ecological penalties were only partially explored. 相似文献
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Akash Anandraj Renzo Perissinotto Christian Nozais Derek Stretch 《Estuarine, Coastal and Shelf Science》2008,79(4):599-606
Mouth breaching is a recurrent event in temporarily open/closed estuaries (TOCEs). Such disturbances result in flushing and sediment scouring, reducing the microalgal biomass stock. The depletion of these microalgae may have negative repercussions in the form of depleted stocks of commercial fish, game fish, crustaceans and mollusks. The aim of this investigation was therefore: (1) to monitor the recovery of microalgal biomass and production following a breaching event; and (2) to determine the key environmental parameters influencing primary production during the open and recovery phases. Phytoplankton and benthic microalgal production was measured (14C-uptake method) successively during the closed, open and recovery phases of the Mdloti TOCE (South Africa). Upon breaching, 94–99% of microalgal biomass was washed out to sea through flushing and sediment scouring. A temporary recovery of phytoplankton and benthic microalgal biomass was observed during the open phase, but this was not sustained because of continual flushing and scouring of the sediment. During the re-closure (recovery phase), microalgal biomass immediately increased, reaching pre-breaching levels 35–40 days following the breaching event. In contrast to biomass, autochthonous pelagic primary production reached a maximum level (341 mg C m−2 h−1) during the open phase. Pelagic primary production normalized to biomass (PB) significantly increased during the open phase. This is attributed to a favorable combination of optimum light conditions, high influx of macronutrients and high water temperatures (33 °C). Similarly, benthic primary production normalized to biomass (PB) peaked during the open phase (35 mg C mg chl-a−1 h−1). Multivariate analysis showed that major variations in primary production were mainly controlled by temperature, dissolved inorganic nitrogen (DIN) to phosphorus (DIP) molar ratios (water-column and pore-water) and light extinction (Kd), all of which were regulated by the state of the mouth. 相似文献
8.
The St Lucia estuarine lake in South Africa forms part of a World Heritage Site and is an important local source of biodiversity. Like many estuarine systems worldwide, St Lucia has experienced significant anthropogenic impacts over the past century. Abstractions have decreased fresh water inflows from the lake catchments by about 20%. Furthermore the Mfolozi river, which previously shared a common inlet with St Lucia and contributed additional fresh water during droughts, was diverted from the system in 1952 because of its high silt loads. The separated St Lucia mouth was subsequently kept artificially open until the onset of a dry period in 2002 when the mouth was left to close naturally. These changes and the current drought have placed the system under severe stress with unprecedented hypersaline conditions coupled with desiccation of large portions of the lake. Long-term simulations of the water and salt balance were used to estimate the occurrence and persistence of water levels and salinities for different management scenarios. The risks of desiccation and hyper-salinity were assessed for each case. The results show that the configuration of the Mfolozi/St Lucia inlets plays a key role in the physicochemical environment of the system. Without the Mfolozi link desiccation (of about 50% of the lake area) would occur for 32% of the time for an average duration of 15 months. Artificially maintaining an open mouth would decrease the chance of desiccation but salinities would exceed 65 about 17% of the time. Restoring the Mfolozi link would reduce the occurrence of both desiccation and hypersaline conditions and a mostly open mouth state would occur naturally. Integrating these modeled scenarios with observed biological responses due to changes in salinity and water depth suggests that large long-term changes in the biological structure can be expected in the different management scenarios. 相似文献
9.
Derek D. Stretch James W. Rottman S.Karan Venayagamoorthy Keiko K. Nomura Chris R. Rehmann 《Dynamics of Atmospheres and Oceans》2010
Mixing efficiency in stratified flows is a measure of the proportion of turbulent kinetic energy that goes into increasing the potential energy of the fluid by irreversible mixing. In this research direct numerical simulations (DNS) and rapid distortion theory (RDT) calculations of transient turbulent mixing events are carried out in order to study this aspect of mixing. In particular, DNS and RDT of decaying, homogeneous, stably-stratified turbulence are used to determine the mixing efficiency as a function of the initial turbulence Richardson number Rit0=(NL0/u0)2, where N is the buoyancy frequency and L0 and u0 are initial length and velocity scales of the turbulence. The results show that the mixing efficiency increases with increasing Rit0 for small Rit0, but for larger Rit0 the mixing efficiency becomes approximately constant. These results are compared with data from towed grid experiments. There is qualitative agreement between the DNS results and the available experimental data, but significant quantitative discrepancies. The grid turbulence experiments suggest a maximum mixing efficiency (at large Rit0) of about 6%, while the DNS and RDT results give about 30%. We consider two possible reasons for this discrepancy: Prandtl number effects and non-matching initial conditions. We conclude that the main source of the disagreement probably is due to inaccuracy in determining the initial turbulence energy input in the case of the grid turbulence experiments. 相似文献
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