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1.
The 26 December 2004-tsunami has deposited sediments in the Pichavaram mangrove ecosystem, east coast of India. Ten surface and three core sediment samples were collected within 30 days of the event and analyzed for nutrients. Water samples were also analyzed to see the impact of tsunami on the geochemical behavior of nutrients. An increase in the concentration of various nutrients namely nitrate and phosphate was observed. The geochemistry of the mangrove forest was observed to be influenced by a number of factors like rapid increase of aquaculture farms, agricultural practices and the anthropogenic discharge from the nearby-inhabited areas. Further the sediment column was disturbed due to energetic tsunami waves, which has caused a sheer increase in the dissolved oxygen in water. As a result, the change in the redox potential has resulted in change in the nutrients absorbed/associated with the sediments. In addition, role of retreating water after tsunami on the nutrient geochemistry was also evaluated.  相似文献   
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The vorticity analysis technique was applied to measure the different lithological units,such as schist,metagranite and metavolcano-sedimentary rocks,which are present in the Halaban region.This work aims to interpret the relationship between the different lithologies and the tectonic setting,in order to elucidate the nature of kinematic analysis in the Halaban region.The kinematic analyses were applied to feldspar porphyroclasts,quartz and hornblende for twentysix samples.The kinematic vorticity number (W_m) for deformed rocks in the study area ranged from~0.6 to 0.9.The direction of the long axes for finite strain data (X axes) revealed a WNW trend with shallow dipping.The direction of the short axes for finite strain data (Z axes) were represented by vertical with associated horizontal foliation.The results of the kinematic vorticity and strain analyses are characterized by simple shear with different degrees of deformation in the Halaban region.Furthermore,our finite strain data shows no significant volume change during deformation.The subhorizontal foliation was synchronized with thrusting and deformation.Furthermore,throughout the overlying nappes,the same attitudes of tectonic contacts are observable,the nappes in the orogens being formed from simple shear deformation.  相似文献   
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Abstract— –Sayh al Uhaymir (SaU) 169 is a composite lunar meteorite from Oman that consists of polymict regolith breccia (8.44 ppm Th), adhering to impact‐melt breccia (IMB; 32.7 ppm Th). In this contribution we consider the regolith breccia portion of SaU 169, and demonstrate that it is composed of two generations representing two formation stages, labeled II and III. The regolith breccia also contains the following clasts: Ti‐poor to Ti‐rich basalts, gabbros to granulites, and incorporated regolith breccias. The average SaU 169 regolith breccia bulk composition lies within the range of Apollo 12 and 14 soil and regolith breccias, with the closest correspondence being with that of Apollo 14, but Sc contents indicate a higher portion of mare basalts. This is supported by relations between Sm‐Al2O3, FeO‐Cr2O3‐TiO2, Sm/Eu and Th‐K2O. The composition can best be modeled as a mixture of high‐K KREEP, mare basalt and norite/troctolite, consistent with the rareness of anorthositic rocks. The largest KREEP breccia clast in the regolith is identical in its chemical composition and total REE content to the incompatible trace‐element (ITE)‐ rich high‐K KREEP rocks of the Apollo 14 landing site, pointing to a similar source. In contrast to Apollo 14 soil, SaU 169 IMB and SaU 169 KREEP breccia clast, the SaU 169 regolith is not depleted in K/Th, indicating a low contribution of high‐Th IMB such as the SaU 169 main lithology in the regolith. The data presented here indicate the SaU 169 regolith breccia is from the lunar front side, and has a strong Procellarum KREEP Terrane signature.  相似文献   
5.
The end of the Palaeozoic is marked by two mass‐extinction events during the Middle Permian (Capitanian) and the Late Permian (Changhsingian). Given similarities between the two events in geochemical signatures, such as large magnitude negative δ13C anomalies, sedimentological signatures such as claystone breccias, and the approximate contemporaneous emplacement of large igneous provinces, many authors have sought a common causal mechanism. Here, a new high‐resolution continental record of the Capitanian event from Portal Mountain, Antarctica, is compared with previously published Changhsingian records of geochemical signatures of weathering intensity and palaeoclimatic change. Geochemical means of discriminating sedimentary provenance (Ti/Al, U/Th and La/Ce ratios) all indicate a common provenance for the Portal Mountain sediments and associated palaeosols, so changes spanning the Capitanian extinction represent changes in weathering intensity rather than sediment source. Proxies for weathering intensity chemical index of alteration, ?W and rare earth element accumulation all decline across the Capitanian extinction event at Portal Mountain, which is in contrast to the increased weathering recorded globally at the Late Permian extinction. Furthermore, palaeoclimatic proxies are consistent with unchanging or cooler climatic conditions throughout the Capitanian event, which contrasts with Changhsingian records that all indicate a significant syn‐extinction and post‐extinction series of greenhouse warming events. Although both the Capitanian and Changhsingian event records indicate significant redox shifts, palaeosol geochemistry of the Changhsingian event indicates more reducing conditions, whereas the new Capitanian record of reduced trace metal abundances (Cr, Cu, Ni and Ce) indicates more oxidizing conditions. Taken together, the differences in weathering intensity, redox and the lack of evidence for significant climatic change in the new record suggest that the Capitanian mass extinction was not triggered by dyke injection of coal‐beds, as in the Changhsingian extinction, and may instead have been triggered directly by the Emeishan large igneous province or by the interaction of Emeishan basalts with platform carbonates.  相似文献   
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New observations of energetic helium ion fluxes in the Earth’s radiation belts have been obtained with the CAMMICE/HIT instrument on the ISTP/GGS POLAR spacecraft during the extended geomagnetically low activity period April through October 1996. POLAR executes a high inclination trajectory that crosses over both polar cap regions and passes over the geomagnetic equator in the heart of the radiation belts. The latter attribute makes possible direct observations of nearly the full equatorial helium ion pitch angle distributions in the heart of the Earth’s radiation belt region. Additionally, the spacecraft often re-encounters the same geomagnetic flux tube at a substantially off-equatorial location within a few tens of minutes prior to or after the equatorial crossing. This makes both the equatorial pitch angle distribution and an expanded view of the local off-equatorial pitch angle distribution observable. The orbit of POLAR also permitted observations to be made in conjugate magnetic local time sectors over the course of the same day, and this afforded direct comparison of observations on diametrically opposite locations in the Earth’s radiation belt region at closely spaced times. Results from four helium ion data channels covering ion kinetic energies from 520 to 8200 KeV show that the distributions display trapped particle characteristics with angular flux peaks for equatorially mirroring particles as one might reasonably expect. However, the helium ion pitch angle distributions generally flattened out for equatorial pitch angles below about 45°. Significant and systematic helium ion anisotropy difference at conjugate magnetic local time were also observed, and we report quiet time azimuthal variations of the anisotropy index.  相似文献   
7.
Contaminated groundwater in fractured bedrock can expose ecosystems to undesired levels of risk for extended periods due to prolonged back-diffusion from rock matrix to permeable fractures. Therefore, it is key to characterize the diffusive mass loading (intrusion) of contaminants into the rock matrix for successful management of contaminated bedrock sites. Even the most detailed site characterization techniques often fail to delineate contamination in rock matrix. This study presents a set of analytical solutions to estimate diffusive mass intrusion into matrix blocks, it is recovered by pumping and concentration rebound when pumping ceases. The analytical models were validated by comparing the results with (1) numerical model results using the same model parameters and (2) observed chloride mass recovery, rebound concentration, and concentration in pumped groundwater at a highly fractured bedrock site in Alberta, Canada. It is also demonstrated that the analytical solutions can be used to estimate the total mass stored in the fractured bedrock prior to any remediation thereby providing insights into site contamination history. The predictive results of the analytical models clearly show that successful remediation by pumping depends largely on diffusive intrusion period. The results of initial mass from the analytical model was used to successfully calibrate a three-dimensional discrete fracture network numerical model further highlighting the utility of the simple analytical solutions in supplementing the more detailed site numerical modeling. Overall, the study shows the utility of simple analytical methods to support long-term management of a contaminated fractured bedrock site including site investigations and complex numerical modeling.  相似文献   
8.
The chemical compositions of various ions in meltwater of the Chhota Shigri glacier were analysed during the observation period from May to October 2010. Total 164 samples of meltwater were collected in two times a day at 8.0 a.m and 6.0 p.m. Bicarbonate and calcium were the dominant anion and cation in meltwater of the investigation area. High ratios of (Ca + Mg) versus TZ+ and (Ca + Mg) versus (Na + K) demonstrate that hydrogeochemistry of the study area was mainly governed by carbonate type weathering. The average sulphate mass fraction of meltwater was computed to be 0.31 ± 0.12, showing dominancy of bicarbonate over sulphate. This excess bicarbonate would be generated by an alternative proton supply mechanism due to biological activities in the bed rock lithology and sulphide oxidation may be about the same as carbonation as a driver of chemical weathering at Chhota Shigri glacier. In general, major ions and total dissolved solid concentrations showed decreasing trend with increasing discharge from the study area. The average daily mean dissolved load of this glacier was much lower than that of the Gangotri glacier, which may be due to low meltwater runoff and lithology of the investigation area. The cation weathering rates of study area for early, peak and late melt seasons were computed to be 694, 1631 and 481 meq m?2 a?1, respectively. The average value of chemical denudation rates of the Chhota Shigri glacier meltwater was found lower than that of the Dokriani glacier.  相似文献   
9.
A field screening method was developed for rapid measurement of benzene and gasoline range total petroleum hydrocarbons (TPHg) concentrations in groundwater. The method is based on collecting photoionization detector (PID) measurements from vapor samples. The vapor samples are collected by bubbling air through groundwater samples (air sparging) with a constant volume, temperature and sparging rate. The level of accuracy, sensitivity, precision, and statistical significance of the estimated concentrations, derived from the screening method, are comparable to conventional laboratory analytical results at concentrations equal to or greater than 150 µg/L for benzene and greater than 50 µg/L for TPHg. The method's concentration estimations can assist in making real‐time decisions regarding location of dissolved plumes and light nonaqueous phase liquid (LNAPL) source zones at many fuel release sites. The screening method was tested in the laboratory and in the field with 208 and 107 samples, respectively. The study concludes that the screening method can be used as a tool to aid in completing a site conceptual model as well as analyzing groundwater from monitoring wells.  相似文献   
10.
Present study is an effort to distinguish between the contributions of natural weathering and anthropogenic inputs towards high salinity and nutrient concentrations in the groundwater of National Capital Territory (NCT) Delhi, India. Apart from the source identification, the aquifer of entire territory has been characterized and mapped on the basis of salinity in space and water suitability with its depth. Major element chemistry, conventional graphical plots and specific ionic ratio of Na+/Cl, SO4 2−/Cl, Mg2+/Ca2+ and Ca2+/(HCO3  + SO4 2−) are conjointly used to distinguish different salinization sources. Results suggest that leaching from the various unlined landfill sites and drains is the prime cause of NO3 contamination while study area is highly affected with inland salinity which is geogenic in origin. The seasonal water level fluctuation and rising water level increases nutrients concentration in groundwater. Mixing with old saline sub-surface groundwater and dissolution of surface salts in the salt affected soil areas were identified as the principle processes controlling groundwater salinity through comparison of ionic ratio. Only minor increase of salinity is the result of evaporation effect and pollution inflows. The entire territory has characterized into four groups as fresh, freshening, near freshening and saline with respect to salinity in groundwater. The salinity mapping suggests that in general, for drinking needs, groundwater in the fresh, freshening and near freshening zone is suitable up to a depth of 45, 20 and 12 m, respectively, while the saline zones are unsuitable for any domestic use. In the consideration of increasing demand of drinking water in the area; present study is vital and recommends further isotopic investigations and highlights the need of immediate management action for landfill sites and unlined drains.  相似文献   
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