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The objective of this study was to examine whether dissolved inorganic phosphate (DIP) is removed from the Eastern Mediterranean Sea by adhering to atmospherically deposited loess particles sinking through the water column. In a series of radiolable experiments, loess from the Negev Desert, treated in various ways, was added to surface (SSW) and deep (DSW) seawater spiked with 32PO4−3. It was shown that when fresh loess reaches the Mediterranean SSW approximately 1.3 μmol P/g are released (11% of the total P concentration). Biological activity and inorganic particles removed similar amounts of the tracer (30–40%) from SSW. It was estimated that about 0.2 μmol P/g of ‘aged loess' (proxy of particles sinking into DSW), were removed from poisoned SSW and DSW, while there was minor adsorption when either nothing or quartz powder was added. The adsorbed DIP accounts for approximately 15% of the released P and is equivalent to about 2% of the remaining P (11.17 μmol P/g loess). Therefore, the process of DIP removal by atmospherically derived particles exists, but due to the higher release of P, the result is a net addition of dissolved atmospheric phosphorus in seawater. It is postulated that in actual SSW where dust concentrations are much lower, biological uptake out-competes inorganic adsorption, although it was demonstrated that the decrease in loess particle concentrations tends to increase their adsorption capacity. As the loess descends into the DSW it continues to remove DIP and thus transports phosphate from the water column to the sediments. A preliminary quantitative estimate suggests that the process of DIP removal by loess particles cannot explain the phosphate ‘deficit' in the Eastern Mediterranean DSW characterized by unusually high DIN/DIP ratios (27) reported by others. 相似文献
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Keith A. Horton Glyn Williams-Jones Harold Garbeil Tamar Elias A. Jeff Sutton Peter Mouginis-Mark John N. Porter Steven Clegg 《Bulletin of Volcanology》2006,68(4):323-327
A miniaturized, lightweight and low-cost UV correlation spectrometer, the FLYSPEC, has been developed as an alternative for
the COSPEC, which has long been the mainstay for monitoring volcanic sulfur dioxide fluxes. Field experiments have been conducted
with the FLYSPEC at diverse volcanic systems, including Masaya (Nicaragua), Poás (Costa Rica), Stromboli, Etna and Vulcano
(Italy), Villarica (Chile) and Kilauea (USA). We present here those validation measurements that were made simultaneously
with COSPEC at Kilauea between March 2002 and February 2003. These experiments, with source emission rates that ranged from
95 to 1,560 t d−1, showed statistically identical results from both instruments. SO2 path-concentrations ranged from 0 to >1,000 ppm-m with average correlation coefficients greater than r
2=0.946. The small size and low cost create the opportunity for FLYSPEC to be used in novel deployment modes that have the
potential to revolutionize the manner in which volcanic and industrial monitoring is performed. 相似文献
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Controlling bioaccumulation of toxic monomethylmercury (MMHg) in aquatic food chains requires differentiation between biotic and abiotic pathways that lead to its production and degradation. Recent mercury (Hg) stable isotope measurements of natural samples suggest that Hg isotope ratios can be a powerful proxy for tracing dominant Hg transforming pathways in aquatic ecosystems. Specifically, it has been shown that photo-degradation of MMHg causes both mass dependent (MDF) and mass independent fractionation (MIF) of Hg isotopes. Because the extent of MDF and MIF observed in natural samples (e.g., fish, soil and sediments) can potentially be used to determine the relative importance of pathways leading to MMHg accumulation, it is important to determine the potential role of microbial pathways in contributing to the fractionation, especially MIF, observed in these samples. This study reports the extent of fractionation of Hg stable isotopes during degradation of MMHg to volatile elemental Hg and methane via the microbial Hg resistance (mer) pathway in Escherichia coli carrying a mercury resistance (mer) genetic system on a multi-copy plasmid. During experimental microbial degradation of MMHg, MMHg remaining in reactors became progressively heavier (increasing δ202Hg) with time and underwent mass dependent Rayleigh fractionation with a fractionation factor α202/198 = 1.0004 ± 0.0002 (2SD). However, MIF was not observed in any of the microbial MMHg degradation experiments indicating that the isotopic signature left by mer mediated MMHg degradation is significantly different from fractionation observed during DOC mediated photo-degradation of MMHg. Additionally, a clear suppression of Hg isotope fractionation, both during reduction of Hg(II) and degradation of MMHg, was observed when the cell densities increased, possibly due to a reduction in substrate bioavailability. We propose a multi-step framework for understanding the extent of fractionation seen in our MMHg degradation experiments and, based on estimates of the rates of the various steps involved in this mer mediated pathway, suggest which steps in the process could contribute towards the observed extent of fractionation. This framework suggests that at lower cell densities catalysis by MerB was the rate limiting step while at higher cell densities transport into the cell, which does not cause fractionation, became the rate limiting step. In addition to presenting evidence for absence of MIF during mer mediated Hg transformations, based on the nature of Hg compounds and microbe-Hg interactions, we suggest that the nuclear spin dependent MIF (i.e., the magnetic isotope effect) is also unlikely to occur during other non mer mediated ‘dark’ microbial Hg transformations (e.g., formation of MMHg and oxidative degradation of MMHg). Because of the important implications of the absence of MIF during biological processes on Hg isotope systematics, we discuss theoretical considerations and experimental strategies that could be used to confirm this suggestion. 相似文献
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Tamar Mayer 《The Professional geographer》1989,41(4):397-409
Neither the accomplishments of feminist scholarship, nor recent geographic research on women, seems to have had much effect on the representation of women in human geography textbooks. Relying on a set of traditional models, these texts reproduce the gender blind fictions of consensus, neutrality, and objectivity that the models and the textbooks themselves construct. Because the texts that initiate students into the discipline lag so seriously behind current consciousness and scholarship, women's invisibility not only continues in the human geography curriculum and classroom but is actually intensified by our own pedagogy. 相似文献
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Glyn Williams-Jones Keith A. Horton Tamar Elias Harold Garbeil Peter J. Mouginis-Mark A. Jeff Sutton Andrew J. L. Harris 《Bulletin of Volcanology》2006,68(4):328-332
A fundamental problem with all ground-based remotely sensed measurements of volcanic gas flux is the difficulty in accurately
measuring the velocity of the gas plume. Since a representative wind speed and direction are used as proxies for the actual
plume velocity, there can be considerable uncertainty in reported gas flux values. Here we present a method that uses at least
two time-synchronized simultaneously recording UV spectrometers (FLYSPECs) placed a known distance apart. By analyzing the
time varying structure of SO2 concentration signals at each instrument, the plume velocity can accurately be determined. Experiments were conducted on
Kīlauea (USA) and Masaya (Nicaragua) volcanoes in March and August 2003 at plume velocities between 1 and 10 m s−1. Concurrent ground-based anemometer measurements differed from FLYSPEC-measured plume speeds by up to 320%. This multi-spectrometer
method allows for the accurate remote measurement of plume velocity and can therefore greatly improve the precision of volcanic
or industrial gas flux measurements.
Editorial responsibility: A. Woods 相似文献
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This article targets the role of intermediaries, such as refugee resettlement programs, in altering the geography of the foreign‐born. It argues that, under such intermediaries, destination choice within the United States is largely determined not by economic mechanisms but instead by information‐related factors such as friction of distance, migration chains, labor procurement, and resettlement intermediaries. Metropolitan statistical area (MSA) destinations are grouped into four profiles based on their mix of foreign‐born. The result is sets of MSAs differentiated by the era of immigration, immigrant origins, geographic pattern, and place characteristics that draw migrants. To evaluate intermediary impacts, monies allocated to states by the Office of Refugee Resettlement, refugee resettlement by state, and refugee movements to MSAs are expressed as a Refugee Resettlement Index and linked to MSA profiles. We conclude that although refugees constitute only a portion of total immigration, their effects are disproportionately large in terms of changing the foreign‐born profiles of MSAs and other communities, changing the fabric of society, and changing the geography of the foreign‐born in all its ramifications. 相似文献
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Naomi Porat Li Ping Zhou Michael Chazan Tamar Noy Liora Kolska Horwitz 《Quaternary Research》1999,51(3):328
The open-air Acheulian site in Holon, Israel, was dated by the luminescence methods and by electron spin resonance (ESR). Situated in the coastal plain Quaternary Kurkar Group, the Holon site was first excavated in the late 1960s, when typical lower Paleolithic lithics and middle Pleistocene fauna were found. In order to date the site, new test pits were dug adjacent to the earlier excavations and the archaeological bed was exposed in a section comprising a series of paleosols and aeolianites. Alkali feldspars separated from the sediments were dated using the infrared stimulated luminescence and thermoluminescence signals, and quartz was dated using the optically stimulated luminescence signal. The age of the archaeological bed is constrained by two samples to 198,000 ± 22,000–201,000 ± 17,000 yr. The age of the base of the section is 240,000 ± 29,000 yr, and the age of the top is 81,000 ± 8000 yr. Two teeth from the archaeological bed, recovered from the original excavation collection, yielded an average ESR age of 204,000 ± 16,000 yr, calculated using the linear uptake model, which is in a very good agreement with the luminescence ages. These dates place Holon within the range of other late Acheulian and Acheulo-Yabrudian sites in this region such as Tabun E (younger chronology), Yabrud I (archaeological level 18), and Berekhat Ram. 相似文献